The use of selected research methods to describe the pore space of dolomite from copper ore mine,Poland

Basic knowledge of the characteristics of copper-bearing rock such as dolomite is essential to locate those areas of the deposit which have different structural and textural properties. Those regions can be important in terms of the assessment of the possibilities of gas accumulating in them as well as in terms of gasogeodynamic hazard. To better understand those threats, it is necessary to locate, monitor and analyse those areas in detail. This article characterises the structural and textural parameters of dolomite from the Polkowice–Sieroszowice copper mine in Poland. The study involved five samples from various areas of the mine. A number of research methods were selected. Reflected and transmitted light microscopy (MS), computer microtomography (Micro-CT), gas adsorption porosimetry (LPNA), mercury porosimetry (MIP), helium and quasi-fluid pycnometry (Pycno. He, DryFlo). Each of the methods examined a different scope of the pore size, which enabled to achieve a full view of the porous nature of those rocks. We determined their porosity (open, closed, total), surface area as well as mean size and volume of the pores. Also, we studied the character and the pore size distribution from a few nm to a few mm. Comprehensive dolomite properties analyses showed that these rocks are characterised by high structural variability. They have mesopores and macropores but few micropores. The analyses presented in this paper are determined by a large petrographic diversity of the deposits containing dolomite. This article is an example of a comprehensive approach to the rock analysis in copper ore mines.     

Comparison of fluid geochemistry and microbiology of multiple organic-rich reservoirs in the Illinois Basin, USA: Evidence for controls on methanogenesis and microbial transport

Microbial methane in sedimentary basins comprises approximately 20% of global natural gas resources, yet little is known about the environmental requirements and metabolic rates of these subsurface microbial communities. The Illinois Basin, located in the midcontinent of the United States, is an ideal location to investigate hydrogeochemical factors controlling methanogenesis as microbial methane accumulations occur: (1) in three organic-rich reservoirs of different geologic ages and organic matter types - Upper Devonian New Albany Shale (up to 900 m depth), Pennsylvanian coals (up to 600 m depth), and Quaternary glacial sediments (shallow aquifers); (2) across steep salinity gradients; and (3) with variable concentrations of . For all three organic-rich reservoirs aqueous geochemical conditions are favorable for microbial methanogenesis, with near neutral pH, concentrations <2 mM, and Cl⁻ concentrations <3 M. Also, carbon isotopic fractionation of CH₄, CO₂, and DIC is consistent with microbial methanogenesis, and increased carbon isotopic fractionation with average reservoir depth corresponds to a decrease of groundwater flushing rates with average depth of reservoir. Plots of stable isotopes of water and Cl⁻ show mixing between a brine endmember and freshwater, suggesting that meteoric groundwater recharge has affected all microbial methanogenic systems. Additionally, similar methanogenic communities are present in all three reservoirs with comparable cell counts (8.69E3-2.58E6 cells/mL). TRFLP results show low numbers of archaea species with only two dominant groups of base pairs in coals, shale, and limestone aquifers. These results compare favorably with other methanogen-containing deep subsurface environments. Individual hydrogeochemical parameters that have a Spearman correlation coefficient greater than 0.3 to variations in methanogenic species include stable isotopes of water (δ¹⁸O and δD), type of substrate (i.e. coals versus shale), pH, and Cl⁻ concentration. The matching of variations between methanogenic TRFLP data and conservative tracers suggests that deep circulation of meteoric waters influenced archaeal communities in the Illinois Basin. In addition, coalification and burial estimates suggest that in the study area, coals and shale reservoirs were previously sterilized (>80 °C in nutrient poor environments), necessitating the re-introduction of microbes into the subsurface via groundwater transport.     

High-Nb hawaiite–mugearite and high-Mg calc-alkaline lavas from northeastern Iran: Oligo-Miocene melts from modified mantle wedge

Tertiary volcanic rocks in northwestern Firoozeh, Iran (the Meshkan triangular structural unit), constitute vast outcrops (up to 250 km²) of high-Mg basaltic andesites to dacites that are associated with high-Nb hawaiites and mugearites. Whole-rock ⁴⁰Ar/³⁹Ar ages show a restricted range of 24.1 ± 0.4–22.9 ± 0.5 Ma for the volcanic rocks. The initial ratios of ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd vary from 0.703800 to 0.704256 and 0.512681 to 0.512877, respectively, in the high-Mg basaltic andesites–dacites. High-Th contents (up to 11 ppm) and Sr/Y values (27–100) and the isotopic composition of the subalkaline high-Mg basaltic andesites–dacites indicate derivation from a mantle modified by slab and sediment partial melts. Evidence such as reverse zoning and resorbed textures and high Ni and Cr contents in the evolved samples indicate that magma mixing with mafic melts and concurrent fractional crystallization lead to the compositional evolution of this series. The high-Nb hawaiites and mugearites, by contrast, have a sodic alkaline affinity and are silica undersaturated; they are also enriched in Nb (up to 47 ppm) and a wide range of incompatible trace elements, including LILE, LREE, and HFSE. Geochemistry and Sr–Nd isotopic compositions of the high-Nb hawaiites and mugearites suggest derivation from a mantle source affected by lower degrees of slab melts. Post-orogenic slab break-off is suggested to have prompted the asthenospheric upwelling that triggered partial melting in mantle metasomatized by slab-derived melts.     

Numerical models of tectonic deformation at the Baltica–Avalonia transition zone during the Paleocene phase of inversion

Predictions from dynamic modelling of the lithospheric deformation are presented for Northern Europe, where several basins underwent inversion during the Late Cretaceous and Early Cenozoic and contemporary uplift and erosion of sediments occurred. In order to analyse the evolution of the continental lithosphere, the equations for the deformation of a continuum are solved numerically under thin sheet assumption for the lithosphere. The most important stress sources are assumed to be the Late Cretaceous Alpine tectonics; localized rheological heterogeneities can also affect local deformation and stress patterns. Present-day observations available in the studied region and coming from seismic structural interpretations and stress measurements have been used to constrain the model. Our modelling results show that lateral variation in lithospheric strength below the basin systems in Central Europe strongly controls the regional deformation and the stress regime. Furthermore, we have demonstrated that the geometry of the boundary between Baltica and Avalonia, together with different rheological characteristics of the two plates, had a crucial role on local crustal deformation and faulting regime resulting in the Baltica–Avalonia transition zone from the S–N Alpine convergence.     

Orbitolinidae and Alveolinidae (Foraminiferida) from the uppermost Albian-lower Cenomanian of Monti d'Ocre (Abruzzi, Italy)

A biostratigraphic study carried out in the Monti d'Ocre area, Abruzzi, Central Apennines, allowed us to recognize Orbitolina (Conicorbitolina) moulladei ‘Strata 5 (1985) 1’, Praealveolina iberica Reichel and Praealveolina simplex Reichel in uppermost Albian–lower Cenomanian shelf-edge deposits of the Fossato Machè succession. These foraminifers have now been found for the first time in the Apennines of central Italy; their finding is quite important from a palaeobiogeographic viewpoint, as it contributes to the improvement of our knowledge on facies distribution in the circum-Mediterranean regions during the Cretaceous Period. In the study area, the coeval Monte Rotondo and Monte Orsello sections also crop out; these are characterized by bauxite deposits and stratigraphic gaps reflecting episodes of emergence on the carbonate platform. The Monte Rotondo and Monte Orsello sections accumulated in a platform back-reef environment; consequently, in this sector of the Monti d'Ocre area, the depositional environment shifted from a back-reef westward and southward to a shelf-edge northward, during the latest Albian–early Cenomanian. Owing to synsedimentary tectonics, the area investigated underwent differential subsidence: westward and southward, wide areas were uplifted and subjected to emergence, karstification and bauxite accumulation, whereas sedimentation continued in a shelf-edge environment in the north-eastern area.     

The “suevite” conundrum,Part 1: The Ries suevite and Sudbury Onaping Formation compared

The term “suevite” has been applied to various impact melt‐bearing breccias found in different stratigraphic settings within terrestrial impact craters. Suevite was coined initially for impact glass‐bearing breccias from the Ries impact structure, Germany, which is the type locality. Various working hypotheses have been proposed to account for the formation of the Ries suevite deposits over the past several decades, with the most recent being molten‐fuel‐coolant interaction (MFCI) between an impact melt pool and water. This mechanism is also the working hypothesis for the origin of the bulk of the Onaping Formation at the Sudbury impact structure, Canada. In this study, the key characteristics of the Ries suevite, the Onaping Formation and MFCI deposits from phreatomagmatic volcanic eruptions are compared. The conclusion is that there are clear and significant lithological, stratigraphic, and petrographic observational differences between the Onaping Formation and the Ries suevite. The Onaping Formation, however, shares many key similarities with MFCI deposits, including the presence of layering, their well‐sorted and fine‐grained nature, and the predominance of vitric particles with similar shapes and lacking included mineral and lithic clasts. These differences argue against the viability of MFCI as a working hypothesis for genesis of the Ries suevite and for a required alternative mechanism for its formation.     

Carrier phase bias estimation of geometry-free linear combination of GNSS signals for ionospheric TEC modeling

The ionosphere can be modeled and studied using multi-frequency GNSS signals and their geometry-free linear combination. Therefore, a number of GNSS-derived ionospheric models have been developed and applied in a broad range of applications. However, due to the complexity of estimating the carrier phase ambiguities, most of these models are based on low-accuracy carrier phase smoothed pseudorange data. This, in turn, critically limits their accuracy and applicability. Therefore, we present a new methodology of estimating the phase bias of the scaled L1 and L2 carrier phase difference which is a function of the ambiguities, the ionospheric delay, and hardware delays. This methodology is suitable for ionospheric modeling at regional and continental scales. In addition, we present its evaluation under varying ionospheric conditions. The test results show that the carrier phase bias of geometry-free linear combination can be estimated with a very high accuracy, which consequently allows for calculating ionospheric TEC with the uncertainty lower than 1.0 TECU. This high accuracy makes the resulting ionosphere model suitable for improving GNSS positioning for high-precision applications in geosciences.     

The influence of hydrodynamic boundary conditions on characteristics,migration, and associated sand transport of sand dunes in a tidal environment

Large parts of the tidal estuary of river Elbe (Germany) are characterized by regular patterns of sand dunes. They evolve due to complex sand transport mechanisms and show multi-faceted migration patterns, which are influenced by hydrodynamic boundary conditions such as runoff and tidal forces. This study aims at increasing the understanding of the way hydrodynamic boundary conditions influence dune behavior. This is the basis of an effective sediment management as well as an important requirement for planning offshore structures. From a unique data set of up to six annual bathymetrical multibeam soundings between 1995 and 2010, bedform characteristics and migration rates were processed and analyzed with a set of automated methods. The influence of river runoff, water levels, current velocities, tidal range, and river depth on characteristics and migration were tested statistically. The results show that migration is mainly dominated by the incoming flood tide while rates and directions depend on the amount of runoff originating from the inland catchment.     

A uniform terminology on bioinvasions: a chimera or an operative tool?

A consensual set of definitions regarding bioinvasions is essential in order to facilitate discourse among the science, policy and management communities dealing with the issue. Considering both the mode of entry and the extent of the impact of an alien species into a new environment, a set of key terms is proposed as an operative tool for marine scientists.