Methane and sulfide fluxes in permanent anoxia: In situ studies at the Dvurechenskii mud volcano (Sorokin Trough, Black Sea)

The Dvurechenskii mud volcano (DMV) is located in permanently anoxic waters at 2060 m depth (Sorokin Trough, Black Sea). The DMV was studied during the RV Meteor expedition M72/2 as an example of an active mud volcano system, to investigate the significance of submarine mud volcanism for the methane and sulfide budget of the anoxic Black Sea hydrosphere. Our studies included benthic fluxes of methane and sulfide, as well as the factors controlling transport, consumption and production of both compounds within the sediment. The pie-shaped mud volcano showed temperature anomalies as well as solute and gas fluxes indicating high fluid flow at its summit north of the geographical center. The anaerobic oxidation of methane (AOM) coupled to sulfate reduction (SR) was repressed in this zone due to the upward flow of sulfate-depleted fluids through recently deposited subsurface muds, apparently limiting microbial methanotrophic activity. Consequently, the emission of dissolved methane into the water column was high, with an estimated rate of 0.46 mol m⁻² d⁻¹. On the wide plateau and edge of the mud volcano surrounding the summit, fluid flow and total methane flux were lower, allowing higher SR and AOM rates correlated with an increase in sulfate penetration into the sediment. Here, between 50% and 70% of the methane flux (0.07-0.1 mol m⁻² d⁻¹) was consumed within the upper 10 cm of the sediment. The overall amount of dissolved methane released from the entire mud volcano structure into the water column was significant with a discharge of 1.3 × 10⁷ mol yr⁻¹. The DMV maintains also high areal rates of methane-fueled sulfide production and emission of on average 0.05 mol m⁻² d⁻¹. This is a difference to mud volcanoes in oxic waters, which emit similar amounts of methane, but not sulfide. However, based on a comparison of this and other mud volcanoes of the Black Sea, we conclude that sulfide and methane emission into the hydrosphere from deep-water mud volcanoes does not significantly contribute to the sulfide and methane inventory of the Black Sea.     

Accounting for the solar radiation in thermal regime prediction for railway subgrade in cold regions

This paper presents a comparative analysis of simulation processes of seasonal freezing-thawing of railway subgrade and permafrost degradation, with and without accounting for solar radiation. Also, the effect of sun screens to reduce the degradation of subgrade permafrost under different climatic conditions is numerically substantiated. And finally, the temperature criterion of the origination of permafrost is illustrated.     

The effects of initial soil moisture conditions on swale flow hydrographs

The effects of soil water content (SWC) on the formation of run‐off in grass swales draining into a storm sewer system were studied in two 30‐m test swales with trapezoidal cross sections. Swale 1 was built in a loamy fine‐sand soil, on a slope of 1.5%, and Swale 2 was built in a sandy loam soil, on a slope of 0.7%. In experimental runs, the swales were irrigated with 2 flow rates reproducing run‐off from block rainfalls with intensities approximately corresponding to 2‐month and 3‐year events. Run‐off experiments were conducted for initial SWC (SWC_ini) ranging from 0.18 to 0.43 m³/m³. For low SWC_ini, the run‐off volume was greatly reduced by up to 82%, but at high SWC_ini, the volume reduction was as low as 15%. The relative swale flow volume reductions decreased with increasing SWC_ini and, for the conditions studied, indicated a transition of the dominating swale functions from run‐off dissipation to conveyance. Run‐off flow peaks were reduced proportionally to the flow volume reductions, in the range from 4% to 55%. The swale outflow hydrograph lag times varied from 5 to 15 min, with the high values corresponding to low SWC_ini. Analysis of swale inflow/outflow hydrographs for high SWC_ini allowed estimations of the saturated hydraulic conductivities as 3.27 and 4.84 cm/hr in Swales 1 and 2, respectively. Such estimates differed from averages (N = 9) of double‐ring infiltrometer measurements (9.41 and 1.78 cm/hr). Irregularities in swale bottom slopes created bottom surface depression storage of 0.35 and 0.61 m³ for Swales 1 and 2, respectively, and functioned similarly as check berms contributing to run‐off attenuation. The experimental findings offer implications for drainage swale planning and design: (a) SWC_ini strongly affect swale functioning in run‐off dissipation and conveyance during the early phase of run‐off, which is particularly important for design storms and their antecedent moisture conditions, and (b) concerning the longevity of swale operation, Swale 1 remains fully functional even after almost 60 years of operation, as judged from its attractive appearance, good infiltration rates (3.27 cm/hr), and high flow capacity.     

Microtextural investigation (SEM and TEM study) of phyllosilicates in a major thrust fault zone (Monte Perdido, southern Pyrenees): impact on fault reactivation

Thrusting fault zone in foreland basins are characterized by highly foliated zones generally enriched in phyllosilicates which can play a major role on the mechanical behaviour of the fault. In this context, investigations of synkinematic clay minerals permit to determine the origin of the fluid from which they precipitated as well as the mechanisms of deformation. Our study is focused on clay mineral assemblages (illite and chlorite) in a major thrust fault located in the Monte Perdido massif (southern Pyrenees), a shallow thrust that affects upper cretaceous-paleocene platform carbonates and lower Eocene marls and turbidites. It implied 3?km of displacement of the Monte Perdido thrust unit with respect to the underlying Gavarnie unit. In this area the cleavage development by pressure-solution is linked to the Monte Perdido and Gavarnie thrust activity. The core zone of the fault, about 6?m thick, consists of an interval of intensely deformed clay-bearing rocks bounded by major shear surfaces. The deformed sediment is markedly darker than the protolith. Calcite-quartz shear veins along the shear planes are abundant. Detailed SEM and TEM observations of highly deformed fault zone samples indicate that clay mineral enrichment in the core zone of the fault is not only related to passive increase by pressure-solution mechanism but that dissolution?Crecrystallization of phyllosilicates occurs during deformation. A mineral segregation is observed in the highly deformed zone. Newly formed 2M ₁ muscovite is present along the cleavage whereas IIb chlorite crystals fill S_V2 shear veins suggesting syntectonic growth of phyllosilicates in the presence of fluids in low-grade metamorphic conditions. These mineralogical reactions act as weakening processes and would favour Monte Perdido fault creeping.     

A Plan to Push Limits? Investigating the ecologically sustainable development dimensions of Melbourne's Central Region sustainable water strategy

Drawing upon theory from the field of urban political ecology, we analyse a major strategic water plan for Melbourne, Australia—the Sustainable water strategy for the Central Region, published in 2006. We assess the extent to which the strategy identified and addressed ecological sustainability in terms of: cultural frames; ecological context; social equity; and engagement processes. We identify that the strategy's framing of water was largely separate from its social and ecological context. This framing resulted in the importance of issues such as environmental flows, social equity and cultural values being diminished, thus avoiding the inevitable confrontation with environmental limits needed to ensure long-term ecological sustainability. Our analysis shows that the discursive dominance of economics limited the response to persuasive scientific arguments for greater ecological consideration in the strategy. Our findings suggest that broadening engagement with the diverse ways in which water is valued is likely to contribute to more equitable and ecologically sustainable water futures.     

Flood-type trend analysis for alpine catchments

ABSTRACT

In many places, magnitudes and frequencies of floods are expected to increase due to climate change. To understand these changes better, trend analyses of historical data are helpful. However, traditional trend analyses do not address issues related to shifts in the relative contributions of rainfall versus snowmelt floods, or in the frequency of a particular flood type. We present a novel approach for quantifying such trends in time series of floods using a fuzzy decision tree for event classification and applied it to maximal annual and seasonal floods in 27 alpine catchments for the period 1980–2014. Trends in flood types were studied with Sen’s slope and double mass curves. Our results reveal a decreasing number of rain-on-snow and an increasing number of short rainfall events in all catchments, with flash floods increasing in smaller catchments. Overall, the results demonstrate the value of incorporating a fuzzy flood-type classification into flood trend analyses.     

A review of the impacts of pumped hydro energy storage construction on subalpine and alpine biodiversity: lessons for the Snowy Mountains pumped hydro expansion project

ABSTRACT

The Australian government’s proposal to expand the Snowy Hydro Scheme to include a second pumped hydro energy storage (PHES) system, and support for feasibility studies for PHES in Tasmania, offer an opportunity to incorporate more intermittent renewable energy generation into the National Energy Market. However, the infrastructure construction required for PHES expansion may have negative effects for biodiversity in subalpine and alpine areas. To identify the potential effects of PHES on biodiversity in Kosciuszko National Park (KNP), this systematic literature review assesses: (i) the key environmental disturbances likely to arise from PHES construction; and (ii) the specific impacts of these construction processes on biodiversity in subalpine and alpine environments. We find that the effects of PHES construction-related disturbances are likely to be negative for subalpine and alpine biodiversity, with impacts including the proliferation of exotic flora, habitat loss resulting from vegetation clearing, altered landscape hydrology and reduced water quality. Management recommendations to limit these impacts are provided and further research is recommended to assess: (i) the effects of PHES on fish populations in alpine reservoirs; (ii) the utility of spoil as artificial habitat for endemic fauna; and (iii) the chemical and physical impacts of spoil dumping in alpine reservoirs.     

Atmospheric electricity measurements over the Indian Ocean

Summary Results of measurements of the atmospheric electrical conductivity and potential gradient made during the sixth Scientific Cruise of the Indian Oceanographic Ship INS Kistna in the Bay of Bengal during February–March 1963 are presented. Observations were made when the skies were generally clear and the sea calm, in the geographical area 8°N to 17°N and 80°E to 95°E, on the outward journey of INS Kistna from Madras (80°E, 13°N) to Port Blair (93°E, 12°N) and on the return journey to Madras.Over the ocean where there are no local sources of pollution, the measured values of conductivity and potential gradient are in agreement with theoretical values, assuming that an ion equilibrium exists, that ions are destroyed primarily by collision with small ions of opposite sign and that small ions are produced only by cosmic radiation. The values of electrical conductivity obtained are generally of the same order as those to be expected from theoretical considerations and in general agreement with those obtained during the Carnegie cruises in the Indian Ocean in 1920. There are, however, significant variations near the coast where the electric structure above the ocean is affected by continental sources of pollution. Conductivity values near the land are about half that in the unpolluted air over the ocean but prevailing winds prevent the extension of pollution beyond 100–200 km from the coast in this season.

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Zusammenfassung Es wird über Messungen der luftelektrischen Leitfähigkeit und des Potentialgefälles berichtet, welche während der Sechsten Wissenschaftlichen Kreuzfahrt des indischen Ozeanographischen Forschungsschiffes Ins Kistna in der Bengalischen Bucht im Februar und März 1963 ausgeführt wurden. Die Beobachtungen sind im allgemeinen bei klarem Himmel und ruhiger See gemacht worden, und zwar in dem geographischen Bereich zwischen 8 und 17°N und 80 und 95°E während der Ausfahrt der INS Kistna von Madras (80°E, 13°N) nach Port Blair (93°E, 12°N) und auf der Rückreise nach Madras. In den Bereichen des Ozeans, in denen keine örtlichen Pollutionsquellen bestehen, stimmen die gemessenen Werte der Leitfähigkeit und des Potentialgefälles mit den theoretischen Werten überein, die man erhält, wenn man annimmt, dass ein Ionengleichgewicht besteht, dass die schnellen Ionen vorwiegend durch Zusammenstoss mit schnellen Ionen des entgegengesetzten Vorzeichens vernichtet werden, und dass die schnellen Ionen nur durch die kosmische Höhenstrahlung erzeugt werden. Die Werte der Leitfähigkeit stimmen mit denen überein, die man aus theoretischen Überlegungen gewinnt, und auch mit denen, die während der Kreuzfahrten des Forschungsschiffes Carnegie im Indischen Ozean im Jahre 1920 gemessen Küste sind jedoch bedeutsame Abweichungen festzustellen, wo die elektrischen Verhältenisse über dem Ozean durch Pollutionsquellen auf dem Lande beeinflusst werden. Die Leitfähigkeitswerte nahe dem Land sind nur ungefähr halb so gross wie die in der pollutionsfreien Luft des offenen Ozeans-jedoch haben die während der Mess-Jahreszeit vorherrschenden Winde eine Ausbreitung der Pollutionszone auf einen Bereich von 100 bis 200 km von der Küste beschränkt.

     

Microbial photosynthesis in coral reef sediments (Heron Reef, Australia)

We investigated microphytobenthic photosynthesis at four stations in the coral reef sediments at Heron Reef, Australia. The microphytobenthos was dominated by diatoms, dinoflagellates and cyanobacteria, as indicated by biomarker pigment analysis. Conspicuous algae firmly attached to the sand grains (ca. 100 μm in diameter, surrounded by a hard transparent wall) were rich in peridinin, a marker pigment for dinoflagellates, but also showed a high diversity based on cyanobacterial 16S rDNA gene sequence analysis. Specimens of these algae that were buried below the photic zone exhibited an unexpected stimulation of respiration by light, resulting in an increase of local oxygen concentrations upon darkening. Net photosynthesis of the sediments varied between 1.9 and 8.5 mmol O₂ m⁻² h⁻¹ and was strongly correlated with Chl a content, which lay between 31 and 84 mg m⁻². An estimate based on our spatially limited dataset indicates that the microphytobenthic production for the entire reef is in the order of magnitude of the production estimated for corals. Photosynthesis stimulated calcification at all investigated sites (0.2–1.0 mmol Ca²⁺ m⁻² h⁻¹). The sediments of at least three stations were net calcifying. Sedimentary N₂-fixation rates (measured by acetylene reduction assays at two sites) ranged between 0.9 to 3.9 mmol N₂ m⁻² h⁻¹ and were highest in the light, indicating the importance of heterocystous cyanobacteria. In coral fingers no N₂-fixation was measurable, which stresses the importance of the sediment compartment for reef nitrogen cycling.