From the Sun to the Earth: The 13 May 2005 Coronal Mass Ejection

We report the results of a multi-instrument, multi-technique, coordinated study of the solar eruptive event of 13 May 2005. We discuss the resultant Earth-directed (halo) coronal mass ejection (CME), and the effects on the terrestrial space environment and upper Earth atmosphere. The interplanetary CME (ICME) impacted the Earth’s magnetosphere and caused the most-intense geomagnetic storm of 2005 with a Disturbed Storm Time (Dst) index reaching ?263 nT at its peak. The terrestrial environment responded to the storm on a global scale. We have combined observations and measurements from coronal and interplanetary remote-sensing instruments, interplanetary and near-Earth in-situ measurements, remote-sensing observations and in-situ measurements of the terrestrial magnetosphere and ionosphere, along with coronal and heliospheric modelling. These analyses are used to trace the origin, development, propagation, terrestrial impact, and subsequent consequences of this event to obtain the most comprehensive view of a geo-effective solar eruption to date. This particular event is also part of a NASA-sponsored Living With a Star (LWS) study and an on-going US NSF-sponsored Solar, Heliospheric, and INterplanetary Environment (SHINE) community investigation.     

Global change and marine communities: alien species and climate change

Anthropogenic influences on the biosphere since the advent of the industrial age are increasingly causing global changes. Climatic change and the rising concentration of greenhouse gases in the atmosphere are ranking high in scientific and public agendas, and other components of global change are also frequently addressed, among which are the introductions of non indigenous species (NIS) in biogeographic regions well separated from the donor region, often followed by spectacular invasions. In the marine environment, both climatic change and spread of alien species have been studied extensively; this review is aimed at examining the main responses of ecosystems to climatic change, taking into account the increasing importance of biological invasions. Some general principles on NIS introductions in the marine environment are recalled, such as the importance of propagule pressure and of development stages during the time course of an invasion. Climatic change is known to affect many ecological properties; it interacts also with NIS in many possible ways. Direct (proximate) effects on individuals and populations of altered physical-chemical conditions are distinguished from indirect effects on emergent properties (species distribution, diversity, and production). Climatically driven changes may affect both local dispersal mechanisms, due to the alteration of current patterns, and competitive interactions between NIS and native species, due to the onset of new thermal optima and/or different carbonate chemistry. As well as latitudinal range expansions of species correlated with changing temperature conditions, and effects on species richness and the correlated extinction of native species, some invasions may provoke multiple effects which involve overall ecosystem functioning (material flow between trophic groups, primary production, relative extent of organic material decomposition, extent of benthic-pelagic coupling). Some examples are given, including a special mention of the situation of the Mediterranean Sea, where so many species have been introduced recently, and where some have spread in very large quantities. An increasing effort by marine scientists is required, not only to monitor the state of the environment, but also to help predicting future changes and finding ways to mitigate or manage them.     

Thermal infrared (vibrational) spectroscopy of Mg–Fe olivines: A review and applications to determining the composition of planetary surfaces

The reststrahlen features in thermal infrared, or vibrational, spectra of Mg-Fe olivines ((Mg,Fe)₂SiO₄) exhibit trends in position, strength, and number of features that are diagnostic of the relative proportions of the Mg and Fe cations in the minerals. Although band positions move to lower wavenumbers (longer wavelengths) across the forsterite–fayalite compositional binary in a generally linear manner, specific feature shifts in transmittance data are described best by two linear fits with a break in slope near Fo₇₀. The break in slope may be accompanied by an offset as well; both traits are attributed to structural changes in olivine brought about by distortion of the crystal lattice by Fe. Reflectance and emissivity spectra exhibit similar trends in band position with composition, and all three types of data demonstrate that some olivine band strengths change across the Mg–Fe solid solution series and also are diagnostic of composition. Olivines have been identified in a wide array of thermal infrared spectra of planetary materials and have been interpreted as being present on the surfaces of Mercury, the Moon, Mars, and a number of asteroids based on the analysis of thermal infrared spectra. New linear least squares models of the emissivity spectra of olivine-bearing Martian meteorites enable a preliminary estimation of the accuracy with which quantitative estimates of olivine abundance and solid solution composition can be derived from the spectra of mixtures.     

Climate change transformation: A definition and typology to guide decision making in urban environments

Climate change presents a threat to the sustainability of cities and their societies, and must be adequately addressed. Urban environments (cities) are responsible for the creation of a significant amount of greenhouse gas emissions which are the source of climate change. Cities have been increasingly the focus of action to address climate change, yet emissions are not significantly reducing. Additionally, there a lack of integration between adaptation and mitigation. This prevents responses adequate to limit global warming to 1.5^OC, and to be well adapted to anticipated changes. This paper critically analyses existing definitions and typologies of climate change actions. A definition of ‘climate change transformation’ is proposed which includes the integration of adaptation and mitigation goals to enable a new regime in which global warming is limited to 1.5^OC. A new three-part typology: ‘coping, malaction and transformation,’ is presented for categorising climate change actions by the extent to which they integrate adaptation and mitigation, and define a new regime. The typology is accompanied by illustrations to demonstrate the relationship between adaptation and mitigation. The definition, typology and illustration serve to guide effective climate change decision making, and provides principles to guide application in urban environments.     

Low-molecular weight hydrocarbons in vent fluids from the Main Endeavour Field, northern Juan de Fuca Ridge

Despite its location on sediment-free basalt, vent fluids from the Main Endeavour Field (MEF) contain chemical species that indicate fluids have interacted with sediments during circulation. We report on the distribution and isotopic abundances of organic compounds (C₁-C₃ alkanes and alkenes, benzene and toluene) in fluids collected from the Main Endeavour Field (MEF) in July, 2000, to understand the processes that regulate their abundances and characterize fluid sources. Aqueous organic compounds are derived from the thermal alteration of sedimentary organic matter and subsequently undergo further oxidation reactions during fluid flow. Fluid:sediment mass ratios calculated using ΣNH₄ concentrations indicate that the sediments are distal to the MEF, resulting in a common reservoir of fluids for all of the vents. Following the generation from sediment alteration, aqueous organic compounds undergo secondary alteration reactions via a stepwise oxidation reaction mechanism. Alkane distributions and isotopic compositions indicate that organic compounds in MEF fluids have undergone a greater extent of alteration as compared to Middle Valley fluids, either due to differences in subsurface redox conditions or the residence time of fluids at subsurface conditions. The distributions of the aromatic compounds benzene and toluene are qualitatively consistent with the subsurface conditions indicated by equilibration of aqueous alkanes and alkanes. However, benzene and toluene do not achieve chemical equilibrium in the subsurface. Methane and CO₂ also do not equilibrate chemically or isotopically at reaction zone temperatures, a likely result of an insufficient reaction time after addition of CO₂ from magmatic sources during upflow. The organic geochemistry supports the assumption that the sediments with which MEF fluids interact has the same composition as sediments present in Middle Valley itself, and highlight differences in subsurface reaction zone conditions and fluid flow pathways at these two sites.     

Methane and sulfide fluxes in permanent anoxia: In situ studies at the Dvurechenskii mud volcano (Sorokin Trough, Black Sea)

The Dvurechenskii mud volcano (DMV) is located in permanently anoxic waters at 2060 m depth (Sorokin Trough, Black Sea). The DMV was studied during the RV Meteor expedition M72/2 as an example of an active mud volcano system, to investigate the significance of submarine mud volcanism for the methane and sulfide budget of the anoxic Black Sea hydrosphere. Our studies included benthic fluxes of methane and sulfide, as well as the factors controlling transport, consumption and production of both compounds within the sediment. The pie-shaped mud volcano showed temperature anomalies as well as solute and gas fluxes indicating high fluid flow at its summit north of the geographical center. The anaerobic oxidation of methane (AOM) coupled to sulfate reduction (SR) was repressed in this zone due to the upward flow of sulfate-depleted fluids through recently deposited subsurface muds, apparently limiting microbial methanotrophic activity. Consequently, the emission of dissolved methane into the water column was high, with an estimated rate of 0.46 mol m⁻² d⁻¹. On the wide plateau and edge of the mud volcano surrounding the summit, fluid flow and total methane flux were lower, allowing higher SR and AOM rates correlated with an increase in sulfate penetration into the sediment. Here, between 50% and 70% of the methane flux (0.07-0.1 mol m⁻² d⁻¹) was consumed within the upper 10 cm of the sediment. The overall amount of dissolved methane released from the entire mud volcano structure into the water column was significant with a discharge of 1.3 × 10⁷ mol yr⁻¹. The DMV maintains also high areal rates of methane-fueled sulfide production and emission of on average 0.05 mol m⁻² d⁻¹. This is a difference to mud volcanoes in oxic waters, which emit similar amounts of methane, but not sulfide. However, based on a comparison of this and other mud volcanoes of the Black Sea, we conclude that sulfide and methane emission into the hydrosphere from deep-water mud volcanoes does not significantly contribute to the sulfide and methane inventory of the Black Sea.     

Comparative studies on compounds occluded inside asphaltenes hierarchically released by increasing amounts of H2O2/CH3COOH

Being the heaviest fraction of crude oils, asphaltenes are liable to aggregate, and other molecules in the oils can be steadily adsorbed onto, and even occluded inside the macromolecular structures of the asphaltenes. These occluded compounds inside the asphaltenes can survive over geological time in oil reservoirs owing to effective protection by the macromolecular structures of the asphaltenes. The asphaltenes of a crude oil (ZG31) from the central Tarim Basin, NW China, were hierarchically degraded by increasing the amount of H₂O₂/CH₃COOH to release the occluded compounds. Besides the common components, series of even numbered n-alk-1-enes and 3-ethylalkanes were detected among the occluded compounds. Comparison of the biomarker distributions and the compound-specific C isotopic results between the compounds from the maltenes and those from the occluded fraction, the ZG31 reservoir was suggested to have been charged multiple times, with different charges being derived from different strata of source rocks.     

Links Between Bottom-Water Anoxia,the Polychaete <Emphasis Type="Italic">Nereis diversicolor</Emphasis>, and the Growth of Green-Algal Mats

Sediment–water incubations were used to study effects of episodic anoxia on filamentous Ulva sp. Treatments included undisturbed sediment with (AnoxSed) and without (NatSed) exposure to 5 days of anoxia, and cores with only the top 0.5 cm of sediment (SurfSed; no macrofauna, restricted pore-water nutrient pool). All three treatments contained Ulva propagules. An Ulva mat developed in the SurfSed, and after the anoxic period in the AnoxSed cores. No growth was observed in the NatSed treatment. In the AnoxSed, Ulva was progressively removed upon reoxygenation through grazing by Nereis. The results suggest that episodic anoxia stimulates the growth of macroalgal mats not only by increasing the availability of nutrients from the sediment, but also by reducing macrofaunal grazing pressure. Infauna (grazing and bioturbation), benthic microalgae (nutrient competition and retention), and pore-water nutrients appear key components in a biogeochemical network with complex feedbacks controlling the growth of green-algal mats in shallow-water systems.     

A Plan to Push Limits? Investigating the ecologically sustainable development dimensions of Melbourne's Central Region sustainable water strategy

Drawing upon theory from the field of urban political ecology, we analyse a major strategic water plan for Melbourne, Australia—the Sustainable water strategy for the Central Region, published in 2006. We assess the extent to which the strategy identified and addressed ecological sustainability in terms of: cultural frames; ecological context; social equity; and engagement processes. We identify that the strategy's framing of water was largely separate from its social and ecological context. This framing resulted in the importance of issues such as environmental flows, social equity and cultural values being diminished, thus avoiding the inevitable confrontation with environmental limits needed to ensure long-term ecological sustainability. Our analysis shows that the discursive dominance of economics limited the response to persuasive scientific arguments for greater ecological consideration in the strategy. Our findings suggest that broadening engagement with the diverse ways in which water is valued is likely to contribute to more equitable and ecologically sustainable water futures.     

Geochronology and paleoenvironment of pluvial Harper Lake,Mojave Desert,California, USA

Accurate reconstruction of the paleo-Mojave River and pluvial lake (Harper, Manix, Cronese, and Mojave) system of southern California is critical to understanding paleoclimate and the North American polar jet stream position over the last 500 ka. Previous studies inferred a polar jet stream south of 35°N at 18 ka and at ~ 40°N at 17–14 ka. Highstand sediments of Harper Lake, the upstream-most pluvial lake along the Mojave River, have yielded uncalibrated radiocarbon ages ranging from 24,000 to > 30,000 ¹⁴C yr BP. Based on geologic mapping, radiocarbon and optically stimulated luminescence dating, we infer a ~ 45–40 ka age for the Harper Lake highstand sediments. Combining the Harper Lake highstand with other Great Basin pluvial lake/spring and marine climate records, we infer that the North American polar jet stream was south of 35°N about 45–40 ka, but shifted to 40°N by ~ 35 ka. Ostracodes (Limnocythere ceriotuberosa) from Harper Lake highstand sediments are consistent with an alkaline lake environment that received seasonal inflow from the Mojave River, thus confirming the lake was fed by the Mojave River. The ~ 45–40 ka highstand at Harper Lake coincides with a shallowing interval at downstream Lake Manix.