Enstatite-diopside solvus and geothermometry

The enstatite-diopside solvus presents certain interesting thermodynamic and crystal-structural problems. The solvus may be considered as parts of two solvi one with the ortho-structure and the other with clino-structure. By assuming the standard free energy change for the two reactions (MgMgSi₂O₆)opx ? (MgMgSi₂O₆)cpx and (CaMgSi₂O₆) opx ? (CaMgSi₂O₆) cpx as 500 and 1 000 to 3 000 cal/mol respectively, it is possible to calculate the regular solution parameter W for orthopyroxene and clinopyroxene. These W's essentially refer to mixing on M2 sites. The expression for the equilibrium constant by assuming ideal mixing for Fe-Mg, Fe-Ca and non-ideal mixing for Ca-Mg on binary M1 and ternary M2 sites is given by 1 $$K_a = \frac{{X_{{\text{Mg - cpx}}}^{{\text{M1}}} X_{{\text{Mg - cpx}}}^{{\text{M2}}} \exp \left[ {\frac{{W_{{\text{cpx}}} }}{{RT}}\left\{ {X_{{\text{Ca - cpx}}}^{{\text{M2}}} \left( {X_{{\text{Ca - cpx}}}^{{\text{M2}}} + X_{{\text{Fe - cpx}}}^{{\text{M2}}} } \right)} \right\}} \right]}}{{X_{{\text{Mg - cpx}}}^{{\text{M1}}} X_{{\text{Mg - opx}}}^{{\text{M2}}} \exp \left[ {\frac{{W_{{\text{cpx}}} }}{{RT}}\left\{ {X_{{\text{Ca - opx}}}^{{\text{M2}}} \left( {X_{{\text{Ca - opx}}}^{{\text{M2}}} + X_{{\text{Fe - opx}}}^{{\text{M2}}} } \right)} \right\}} \right]}}$$ where X's are site occupancies, R is 1.987 and T is temperature in ^oK. Temperature of pyroxene crystallization may be estimated by substituting for T in the above equation until the equation ?RT In K _a=500 is satisfied. The shortcomings of this method are the incomplete standard free energy data on the end member components and the absence of site occupancy data in pyroxenes at high temperatures. The assumed free energy data do, however, show the possible extent of inaccuracy in temperature estimates resulting from the neglect of Mg-Ca non ideality.     

Land use pattern of upper tons catchment district,Uttarkashi, U. P.

Aerial Photographs of 1:50,000 scale pertaining to Tons Catchment were used for generating a land use map showing cultivated lands, forests land, grass land, barren land with rock outcrops, snow and glaciers. The area was divided into 4 altitudinal Zones. More than 81% lies above 3000 m height and should be left for natural regeneration. Cultivated land occupies 4.97% of the area and is concentrated below 3000 m altitudinal zone and lies along river courses and on river terraces. Distribution of forest lands in altitudinal zone indicates that percent area covered under forest is higher than the average distribution of forest as reported by Seth (1978). Grass and open scrub, barren Innd with rock outcrops, glaciers and snow covered areas occupy 6.8%, 18.1%, 16.5% and 28.0% respectively.     

Assessment of sedimentation in harakud reservoir using digital remote sensing technique

As per recommendations of Working Group for National Action for Reservoir Sedimentation Assessment, National Institute of Hydrology has taken up study on sedimentation for 25 reservoirs in India during X plan period using remote sensing technique. One such study for Hirakud reservoir in Mahanadi basin in Orissa for year 1999–2001 is described here. Reservoir’s original utilizable and gross volumes were 5818 and 8136 M m³, respectively. Minimum draw down level (MDDL) and full reservoir level (FRL) for reservoir are 179.83 and 192.02 m, respectively. Linear Imaging Self Scanning (LISS)- III data of Indian Remote Sensing Satellites (IRS) 1C and 1D, covering elevation range between 180.68 and 191.89 m, were used. Rule based classification was applied to ‘water index’ and radiances of near infrared band to determine water spread area. Revised live storage capacity was 4842 M m³. The silt index for the live storage area was 2.623 ha m (100 km² year)^-1 (0.376 % of live storage or 21.9 M m³ year^-1). Total live storage lost in sedimentation was 984 M m³ (16.90 % of live storage).     

Optimization of spatial statistical approaches to identify land use/land cover change hot spots of Pune region of Maharashtra using remote sensing and GIS techniques

This study investigated land use/land cover change (LULCC) dynamics using temporal satellite images and spatial statistical cluster analysis approaches in order to identify potential LULCC hot spots in the Pune region. LULCC hot spot classes defined as new, progressive and non-progressive were derived from Gi* scores. Results indicate that progressive hot spots have experienced high growth in terms of urban built-up areas (20.67% in 1972–1992 and 19.44% in 1992–2012), industrial areas (0.73% in 1972–1992 and 3.46% in 1992–2012) and fallow lands (4.35% in 1972–1992 and ?6.38% in 1992–2012). It was also noticed that about 28.26% of areas near the city were identified as new hot spots after 1992. Hence, non-significant change areas were identified as non-progressive after 1992. The study demonstrated that LULCC hot spot mapping through the integrated spatial statistical approach was an effective approach for analysing the direction, rate, spatial pattern and spatial relationship of LULCC.     

The solani-ganga interfluve; an application of remote sensing technique on soil resource mapping for agricultural planning

The area of the Solani-Ganga interfluve, which lies between 29°16′N to 30°15′N latitude and 77°45′E to 78°15′E longitude was undertaken for the present study using LANDSAT imagery of band 5 and 7 and the false colour composite on the scale of 1:250,000 in combination with aerial photographs (1:25,000). Major geomorphic units, e.g., Siwalik Hills. Solani-upper alluvial plain, Solani lower alluvial plain, ‘Tarai’ and Ganga alluvial plain were delineated on LANDSAT and colour composite. Sample areas selected from LANDSAT were studied on aerial photographs in details and soil physiography relationship was developed. The soils on Siwalik hills are classified as Orthents. The soils of the pledmont plain and the recent terraces of Solani river and its tributaries were Psamments, Orthents, Fluvents, Orchrepts and Aquepts. The soils of upper alluvial tract of the Ganga plain is mostly Ustalfs with inclusion of Aqualfs, while the strong hydromorphic Tarai tract consists of partly Aquepts, Ochrepts (cultivated) and partly of Aquolls, Ustolls and Ustalfs (under forest). The present study aims to pin point the nature of soil relief relationship with the help of LANDSAT imagery and aerial photographs and diagnose the intensity of the depletion of soil resources (by prevailing factors like swift run off of biykderfed torrents, fast-flow of ground water, soil creep, mass wasting) through field studies and then treat them with ecological dose of soil conservation. For agronomic development of the region, it is worked out that the present crop-combination and crop-rotation systems should be slightly modified according to its ecosystem to prevent the depletion of soil nutrients.     

A model of Earth’s deep interior basedon mineralogical data

Summary ?We describe here a model of formation of the core and the early history of Earth based on recent experimental mineralogical data. In a nebular setting, where differentiated planetesimals with their iron cores were plentiful, hot condensing solids mixed with the planetesimal irons and formed the solid proto-core (Fe-Ni-S-C). FeO from unmixing in magnesiowustite and from a dissociation of perovskite in the newly accreted mantle concentrated at the core-mantle interface and reacted with the nascent core. The interface grew to form the liquid core (Fe-Ni-O-S-C) at the expense of the solid proto-core and the formation of much of the outer core was complete within the first 500 million years. The model is consistent with geochemical data and has important implications for the dynamics of the inner core.

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Zusammenfassung ?Das Innere der Erde: Ein Modell basierend auf mineralogischen Daten Wir pr?sentieren ein Modell zur Bildung des Erdkerns und der frühen Geschichte der Erde, das auf neuen experimentellen mineralogischen Daten basiert. In einem nebularen System, in dem differenzierte Planetesimals mit Eisenkernen sehr h?ufig waren, mischten sich kondensierte Festk?rper mit dem Eisen der Planetesimals, um einen festen Protokern (Fe-Ni-S-C) zu formen. FeO, das aus Magnesiowüstit entmischte und durch Dissoziation aus Perovskit im Mantel entstand, konzentrierte sich in der Kern – Mantel – Grenzzone und reagierte mit dem neugebildeten Kern. Diese Grenzzone wuchs und es entstand ein flüssiger (Fe-Mi-O-S-C) Kern auf Kosten des festen Protokerns. Die Bildung des ?u?eren Kerns war innerhalb der ersten 500 Millionen Jahre abgeschlossen. Dieses Modell ist mit geochemischen Daten konsistent und hat wichtige Auswirkungen auf die Dynamik des inneren Kerns.

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Received February 9, 1999;/revised version accepted April 9, 1999     

Resource Flows of Villages with Contrasting Lifestyles in Nanda Devi Biosphere Reserve, Central Himalaya, India

Resource use efficiency analyses of village ecosystem are necessary for effective and efficient planning of resource utilization. This paper deals with economic and energy input-output analyses of different components of village ecosystem in representative buffer zone villages, which are practicing transhumance and settled way of lifestyles in Nanda Devi Biosphere Reserve （NDBR） of Garhwal Himalaya. While the villages practicing transhumance used various natural resources spatially segregated,the villages practicing settled way of lifestyle have to manage resources from a limited spatial area through rotation and varied extraction intensities. Forests subsidized the production activity in both type of villages and the per capita resource extractions were found to be greater in tran~humance village than settled village. Though crops provided maximum energy, in terms of economic criteria, animal husbandry played important role in both settled and transhumance villages. As villages representing both the situations showed different ways of adjustments to the conservation oriented land use changes, management authority needs to address the eco-development plans fulfilling the aspirations of all people traditionally using the resources of the Reserve to reduce the conflicts and encourage their participation in the conservation of the area.     

Reaction-Diffusion Systems and Nonlinear Waves

The authors investigate the solution of a nonlinear reaction-diffusion equation connected with nonlinear waves. The equation discussed is more general than the one discussed recently by Manne et al. (2000). The results are presented in a compact and elegant form in terms of Mittag-Leffler functions and generalized Mittag-Leffler functions, which are suitable for numerical computation. The importance of the derived results lies in the fact that numerous results on fractional reaction, fractional diffusion, anomalous diffusion problems, and fractional telegraph equations scattered in the literature can be derived, as special cases, of the results investigated in this article.     

Variation of ambient SO2 over Delhi

The temporal variation of ambient SO₂ and the chemical composition of particulate matters (PM_2.5 and PM₁₀) were studied at National Physical Laboratory (NPL), New Delhi (28°38′N, 77°10′E). Spatial variation of SO₂ at seven air quality monitoring stations over Delhi was also studied simultaneously. Wide range of ambient SO₂ was recorded during winter (2.55 to 17.43 ppb) compare to other seasons. SO₂ mixing ratio was recorded significantly high at industrial sites during winter and summer; however, no significant spatial difference in SO₂ mixing ratio was recorded during monsoon. SO ₄ ^2? /(SO₂+SO ₄ ^2? ) ratio was recorded high (0.74) during winter and low (0.69) during summer. Monthly variation of PSCF was analyzed using HYSPLIT seven days backward trajectories and daily average SO₂ data. PSCF analysis suggests that, during winter (December, January, February) ambient SO₂ at the study site might have contributed from long distance sources, located towards west and southwest directions; during monsoon (July, August, September) marine contribution was noticed; whereas, during summer (April, May and June) it was from regional sources (located within few 100 km of study site). During winter there was significant contribution from the long distance sources located in western Asia, northwestern Pakistan, Rajasthan and Punjab provinces of India. Coal used in thermal power plants at Panipat (in the northwestern side) and Faridabad (in the southeastern side), local industries, soil erosion and biomass burning may be major contributing factors for SO₂ during summer. The study establishes that the transport sector may not be the major source of ambient SO₂ in Delhi.