Thermochronology and exhumation rates of granitic intrusions at Mesa Central,Mexico

ABSTRACT

The Mesa Central of Mexico (MC) is an elevated plateau located 2000 m above sea level in central Mexico, where intrusions outcrop that register the history of exhumation-erosion occurring during the Late Cretaceous-Paleogene. The tectonic history of the region records formation of the Late Cretaceous-Paleogene ‘Mexican orogen’; this was followed by extension of the entire region and several plutons were then exhumed. The age and magnitude of the crustal uplift and erosion occurring during exhumation has not been addressed to date. Therefore, this study reports the crystallization and cooling ages of two plutons, the Tesorera Granodiorite and the Comanja Granite, and estimates their emplacement depths. Based on these data, the exhumation age of the Tesorera Granodiorite is estimated to be between ~73 Ma and ~63 Ma at an exhumation rate of ~528 m/m. y. and that of the Comanja Granite is 52 Ma and 48 Ma at an exhumation rate of ~2500 m/m. y. Exhumation-erosion event of the Tesorera Granodiorite was located on the trace of the San Luis-Tepehuanes Fault System and that of the Comanja Granite on the a trace of the El Bajío Fault System. Furthermore, the high exhumation rate in the Comanja Granite suggests that gravitational collapse played an important role during exhumation.     

Structure, ordering and cation interactions in Ca-free P2 1 /c clinopyroxenes

A suite of 14 synthetic Ca-free P2 ₁ /c low-clinopyroxenes of compositions across the enstatite-ferrosilite (En-Fs) join have been studied by X-ray powder diffraction and Mössbauer spectroscopy. The crystal structure of one sample with composition X _Fs=0.39 was determined by single-crystal X-ray diffraction. The powder diffraction data show that there is no significant (<0.25% at X _Fs=0.5) excess volume of mixing on the enstatite-ferrosilite join. The molar volumes are described by V=31.261(17)+1.677(23) X _Fs cm³.mol(MSiO₃)^–1. The linear behaviour of volume with composition arises from the compensating effects of non-linear changes in the unit-cell parameters with composition. Unweighted fits to the data yielded the relationships: a=9.6100(15)+0.105(2)X _Fs, b=8.8156(28)+0.218(12)X _Fs+0.0481(117)X ² _Fs , c?=5.1702(4)+0.0879(21)X _Fs–0.0214(21)X ² _Fs , β=108.345(8)+0.947(30)X _Fs–0.805(26)X ² _Fs . The strong positive deviation of β from linearity is directly correlated to the difference in site occupancies between M1 and M2 as determined by Mössbauer spectroscopy and arises directly from the expansion of M2-O1 and M2-O3 bonds upon initial substitution of Fe for Mg in enstatite. The hyperfine parameters from Mössbauer spectra are consistent with variations in the average local environment as recorded by the X-ray data. Asymmetric line broadening of the Mössbauer spectra provides evidence for next-nearest neighbour effects, and is consistent with no significant clustering of Fe or Mg within the samples.     

The partial molal volume of silicic acid in 0.725 m NaCl

The partial molal volume ($\text{V}\text{?}$) of silicic acid in 0.725 m NaCl at 20°C has been calculated from (1) direct volume changes due to the dissolution of anhydrous sodium silicate and (2) some literature values for the partial molal volumes of NaOH and water. , unconnected for electrostriction effects, was found to be 53 ± 2 ml mole^?1. , corrected for volume changes due to solvent electrostriction by charged Si species, was estimated to be in the range 58–62 ml mole^?1; this range is 7–11 ml mole^?1 greater than the calculated from Willey's (Mar. Chem. 2, 239–250, 1974) solubility data obtained from the dissolution, in seawater, of amorphous silica subjected to hydrostatic pressure. Our does, however, agree within experimental error with the calculated from Jones and Pytkowicz's (Bull. Soc. Roy. Sci. Liege 42, 118–120, 1973) data for the solubility of amorphous silica in seawater at high pressure and is nearly in agreement with Willey's (Ph.D. thesis, Dalhousie University, 1975) solubility data for amorphous silica in 0.6 m NaCl.     

Regional Seas integrative studies,as a basis for an ecosystem-based approach to management: The case of the Bay of Biscay

Marine legislation world-wide has, as a recent final objective, the maintenance of a good environmental or ecological status for marine waters, habitats and resources. The concept of environmental status takes into account the structure, function and processes of marine ecosystems, bringing together physical, chemical, physiographic, geographic and climatic factors: subsequently, integrating such conditions, with anthropogenic impacts and activities undertaken in the area concerned. Such an approach is intended to permit an assessment of the environmental status at the ecosystem level, i.e. ‘ecosystem-based approach’, or ‘ecosystem-based management’.Such legislation emphasises the need for the development of methodologies, to assess environmental status. As such the knowledge acquired within Regional Seas, discussed at International Symposia and, finally, published as Special Issues, can serve as the basis for a regional ecosystem-based approach to management and the integrative assessment of marine systems. Hence, the Bay of Biscay is used in this contribution, as an example, to show past and present research, together with perspectives for the future. It is concluded that collaboration between institutions (marine research institutes, universities) and countries (France, Spain, Portugal, the United Kingdom and Ireland) could result in an interesting ‘case-study’, for the further implementation of the European Marine Strategy Framework Directive, at the level of this particular Regional Sea. In this way, the experience gained in the implementation of the Water Framework Directive within the ecoregion, together with the information collated in the eleven International Symposia of Oceanography of the Bay of Biscay, celebrated until now, can be very useful, for an ecosystem-based management approach for this Regional Sea.     

Assessing the benthic quality status of the Bohai Bay (China) with proposed modifications of M-AMBI

Multivariate AZTI's Marine Biotic Index (M-AMBI) was designed to indicate the ecological status of European coastal areas. Based upon samples collected from 2009 to 2012 in the Bohai Bay, we have tested the response of variations of M-AMBI, using biomass (M-BAMBI) in the calculations, with different transformations of the raw data. The results showed that the ecological quality of most areas in the study indicated by M-AMBI was from moderate to bad status with the worse status in the coastal areas, especially around the estuaries, harbors and outfalls, and better status in the offshore areas except the area close to oil platforms or disposal sites. Despite large variations in nature of the input data, all variations of M-AMBI gave similar spatial and temporal distribution patterns of the ecological status within the bay, and showed high correlation between them. The agreement of new ecological status obtained from all M-AMBI variations, which were calculated according to linear regression, was almost perfect. The benthic quality, assessed using different input data, could be related to human pressures in the bay, such as water discharges, land reclamation, dredged sediment and drilling cuts disposal sites. It seems that M-BAMBI were more effective than M-NABMI (M-AMBI calculated using abundance data) in indicating human pressures of the Bay. Finally, indices calculated with more severe transformations, such as presence/absence data, could not indicate the higher density of human pressures in the coastal areas of the north part of our study area, but those calculated using mild transformation (i.e., square root) did.     

Trends in Abundance Indices of Fishes in Maryland’s Coastal Bays During 1972–2009

Maryland’s coastal bays provide habitat for juveniles of many commercially and recreationally important species of shellfish and finfish. Since 1972, the Maryland Department of Natural Resources has conducted the Maryland Coastal Bays Trawl and Seine Survey to monitor the populations of key species. The survey has undergone substantial spatial and methodological changes affecting the interpretation of simple indices of abundance. We developed generalized linear models to standardize the indices of abundance of five commonly caught fish species: Atlantic menhaden Brevoortia tyrannus, weakfish Cynoscion regalis, spot Leiostomus xanthurus, bay anchovy Anchoa mitchilli, and summer flounder Paralichthys dentatus. Density declined significantly since 1972 for menhaden, bay anchovy, and spot in at least one region within the coastal bays. The northern bays had significantly higher densities than the southern bays for all species. Changes in abundance indices of the five species examined were not related to sea grass coverage, temperature, salinity, nitrogen-to-phosphorus ratios, and other habitat variables but were likely a result of stock-wide recruitment processes.     

Nonextensive Statistical Mechanics: Some Links with Astronomical Phenomena

A variety of astronomical phenomena appear to not satisfy the ergodic hypothesis in the relevant stationary state, if any. As such, there is no reason for expecting the applicability of Boltzmann–Gibbs (BG) statistical mechanics. Some of these phenomena appear to follow, instead, nonextensive statistical mechanics. In the same manner that the BG formalism is based on the entropy S _BG=?k∑ _i p _i ln p _i, the nonextensive one is based on the form S _q=k(1 ?∑ _i p _i ^q)/(q? 1) (with S ₁=S _BG). The stationary states of the former are characterized by an exponential dependence on the energy, whereas those of the latter are characterized by an (asymptotic) power law. A brief review of this theory is given here, as well as of some of its applications, such as the solar neutrino problem, polytropic self-gravitating systems, galactic peculiar velocities, cosmic rays and some cosmological aspects. In addition to these, an analogy with the Keplerian elliptic orbits versus the Ptolemaic epicycles is developed, where we show that optimizing S _q with a few constraints is equivalent to optimizing S _BG with an infinite number of constraints.     

Geostrophic Adjustment Problems in a Polar Basin

The geostrophic adjustment of a homogeneous fluid in a circular basin with idealized topography is addressed using a numerical ocean circulation model and analytical process models. When the basin is rotating uniformly, the adjustment takes place via excitation of boundary propagating waves and when topography is present, via topographic Rossby waves. In the numerically derived solution, the waves are damped because of bottom friction, and a quasi-steady geostrophically balanced state emerges that subsequently spins-down on a long time scale. On the f-plane, numerical quasi-steady state solutions are attained well before the system's mechanical energy is entirely dissipated by friction. It is demonstrated that the adjusted states emerging in a circular basin with a step escarpment or a top hat ridge, centred on a line of symmetry, are equivalent to that in a uniform depth semicircular basin, for a given initial condition. These quasi-steady solutions agree well with linear analytical solutions for the latter case in the inviscid limit.

On the polar plane, the high latitude equivalent to the β-plane, no quasi-steady adjusted state emerges from the adjustment process. At intermediate time scales, after the fast Poincaré and Kelvin waves are damped by friction, the solutions take the form of steady-state adjusted solutions on the f-plane. At longer time scales, planetary waves control the flow evolution. An interesting property of planetary waves on a polar plane is a nearly zero eastward group velocity for the waves with a radial mode higher than two and the resulting formation of eddy-like small-scale barotropic structures that remain trapped near the western side of topographic features.

RÉSUMÉ?Traduit par la rédaction] Nous étudions l'ajustement géostrophique d'un fluide homogène dans un bassin circulaire ayant une topographie idéalisée à l'aide d'un modèle numérique de circulation océanique et de modèles analytiques de processus. Quand le bassin est en rotation uniforme, l'ajustement se fait par l'excitation d'ondes de propagation aux limites, et en présence de topographie, par des ondes de Rossby topographiques. Dans la solution numériquement dérivée, les ondes sont amorties à cause frottement contre le fond, et un état quasi-stable géostrophiquement équilibré s’établit pour ensuite décélérer sur une longue période de temps. Sur le plan f, les solutions numériques d’états quasi-stables sont atteintes bien avant que l’énergie du système mécanique soit entièrement dissipée par le frottement. Nous démontrons que les états ajustés apparaissant dans un bassin circulaire avec un accore en forme de marche ou une crête en forme de merlon, centrés sur une ligne de symétrie, sont équivalents à ceux d'un bassin semi-circulaire de profondeur uniforme pour une condition initiale donnée. Les solutions quasi-stables s'accordent bien avec les solutions analytiques linéaires pour le dernier cas dans la limite de la non-viscosité.

Sur le plan polaire, la haute latitude équivalente au plan β, le processus d'ajustement n'aboutit à aucun état ajusté quasi-stable. Aux échelles de temps intermédiaires, après l'amortissement des ondes rapides de Poincaré et Kelvin par le frottement, les solutions prennent la forme de solutions ajustées d’états stables sur le plan f. Aux échelles de temps plus longues, les ondes planétaires déterminent l’évolution de l’écoulement. Une propriété intéressante des ondes planétaires sur un plan polaire est une vitesse de groupe presque nulle vers l'est pour les ondes ayant un mode radial plus grand que deux et la formation résultante de structures barotropiques de petite échelle de type remous qui demeurent emprisonnées près du bord ouest des caractéristiques topographiques.     

The effect of seawater magnesium on natural fluorescence during estuarine mixing,and implications for tracer applications

Natural fluorescence, which is thought to result from low molecular weight humic and fulvic compounds, can be used as a tracer to distinguish between individual river waters. Natural fluorescence exhibits conservative mixing with seawater, except for a slight fluorescence increase which is sometimes observed in the low salinity range (0–5‰). This increase is not due to the inner filter effect (internal quenching). Laboratory experiments can reproduce this low-salinity natural fluorescence increase. Of the major seawater ions, only magnesium can cause a similar natural fluorescence increase. Variation in sample pH, ionic strength, or particle content cannot explain the natural fluorescence increase, nor does it appear to be related to the estuarine flocculation of humic material. Addition of seawater magnesium to the fluorescent material with subsequent loss of hydrogen ions could enhance fluorescence by adding crosslinking to the structure. Replacement of a fluorescence-depressing metal like copper or iron by magnesium could also enhance fluorescence, essentially by removing the quenching effect of the metal. Experimental data in this study are consistent with both of these possible mechanisms. Calcium also enhances fluorescence, however the effect of seawater calcium during estuarine mixing is not as apparent as the magnesium effect. The implications of this low-salinity natural fluorescence increase with respect to estuarine and coastal tracer applications depend on whether individual rivers mix in the high or low salinity region of an estuary or coastal area.