Os mobilization during melt percolation: The evolution of Os isotope heterogeneities in the mantle sequence of the troodos ophiolite, Cyprus

This study focuses on the origin of the Os isotope heterogeneities and the behaviour of Os and Re during melt percolation and partial melting processes in the mantle sequence of the Troodos Ophiolite Complex. The sequence has been divided into an eastern (Unit 1) and a western part (Unit 2) (Batanova and Sobolev, 2000). Unit 1 consists mainly of spinel-lherzolites and a minor amount of dunites, which are surrounded by cpx-bearing harzburgites. Unit 2 consists of harzburgites, dunites, and contains chromitite deposits.Unit 1 (¹⁸⁷Os/¹⁸⁸Os: 0.1169 to 0.1366) and Unit 2 (¹⁸⁷Os/¹⁸⁸Os 0.1235 to 0.1546) peridotites both show large ranges in their Os isotopic composition. Most of the ¹⁸⁷Os/¹⁸⁸Os ratios of Unit 1 lherzolites and harzburgites are chondritic to subchondritic, and this can be explained by Re depletion during ancient partial melting and melt percolation events. The old Os isotope model ages (>800 Ma) of some peridotites in a young ophiolitic mantle show that ancient Os isotopic heterogeneities can survive in the Earth upper mantle. Most harzburgites and dunites of Unit 2 have suprachondritic ¹⁸⁷Os/¹⁸⁸Os ratios. This is the result of the addition of radiogenic Os during a younger major melt percolation event, which probably occurred during the formation of the Troodos crust 90 Ma ago.Osmium concentrations tend to decrease from spinel-lherzolites (4.35 ± 0.2 ng/g) to harzburgites (Unit 1: 4.06 ± 1.12 ng/g; Unit 2: 3.46 ± 1.38 ng/g) and dunites (Unit 1: 2.71 ± 0.84 ng/g; Unit 2: 1.85 ± 1.20 ng/g). Therefore, this element does not behave compatibly during melt percolation as it is observed during partial melting, but becomes dissolved and mobilized by the percolating melt. The Os contents and Re/Os ratios in the mantle peridotites can be explained if they represent mixing products of old depleted mantle with cpx- and opx-veins, which are crystallization products of the percolating melt. This mixing occurred during the melting of a continuously fluxed mantle in a supra-subduction zone environment.This study shows that Unit 1 and Unit 2 of the Troodos mantle section have a complex and different evolution. However, the Os isotopic characteristics are consistent with a model where the harzburgites and dunites of both units belong to the same melting regime producing the Troodos oceanic crust.     

Boron-isotope fractionation between tourmaline and fluid: an experimental re-investigation

The fractionation of boron isotopes between synthetic dravitic tourmaline and fluid was determined by hydrothermal experiments between 400 and 700°C at 200 MPa and at 500°C, 500 MPa. Tourmaline was crystallized from an oxide mix in presence of water that contained boron in excess. In one series of experiments, [B]_fluid/[B]_tour was 9 after the run; in another series it was 0.1. All experiments produced tourmaline as the sole boron-bearing solid, along with traces of quartz and talc. Powder XRD and Rietveld refinements revealed no significant amounts of tetrahedrally coordinated boron in tourmaline. ¹¹B always preferentially fractionated into the fluid. For experiments where [B]_fluid/[B]_tour was 9, a consistent temperature-dependent boron isotope fractionation curve resulted, approximated by Δ¹¹B_{(tour–fluid)} = −4.20 · [1,000/T (K)] + 3.52; R ² = 0.77, and valid from 400 to 700°C. No pressure dependence was observed. The fractionation (−2.7 ± 0.5‰ at 400°C; and −0.8 ± 0.5‰ at 700°C) is much lower than that previously presented by Palmer et al. (1992). Experiments where [B]_fluid/[B]_tour was 0.1 showed a significant larger apparent fractionation of up to −4.7‰. In one of these runs, the isotopic composition of handpicked tourmaline crystals of different size varied by 1.3‰. This is interpreted as resulting from fractional crystallization of boron isotopes during tourmaline growth due to the small boron reservoir of the fluid relative to tourmaline, thus indicating larger fractionation than observed at equilibrium. The effect is eliminated or minimized in experiments with very high boron excess in the fluid. We therefore suggest that values given by the above relation represent the true equilibrium fractionations.     

Historical footprints in contemporary land use systems: forest cover changes in savannah woodlands in the Sudano-Sahelian zone

The paper analyses land use trajectories in savannah woodlands in the Central-West Region, Burkina Faso and the Upper East Region in northern Ghana by use of satellite images and historical archives. Observed trends differ in terms of spatial location and correlation with population pressure from normally accepted characterizations. Colonial forestry policies are proposed as key determinants of present-day land use patterns. However, these reinforced pre-colonial land use patterns inasmuch as land gazetted as forest reserves were tracts affected by vectors of human and livestock disease. It is suggested that the transformation of wooded agricultural landscapes in the Sudano-Sahelian region is the outcome of historically and culturally embedded interactions between complex social, economic and ecological processes which operate at widely varying scales and which change over time; the implications hereof for modelling of global environmental issues is discussed.     

Transfer of lipids from plankton to blubber of harp and hooded seals off East Greenland

Sub-Arctic marine ecosystems are some of the most productive ecosystems in the world's oceans. The capacity of herbivorous zooplankton, such as Calanus, to biosynthesize and store large amounts of lipids during the short and intense spring bloom is a fundamental adaptation which facilitates the large production in these ecosystems. These energy-rich lipids are rapidly transferred through the food chain to Arctic seals. The fatty acids and stable isotopes from harp seal (Phoca groenlandica) and hooded seal (Cystophora cristata) off East Greenland as well as their potential prey, were analysed. The results were used to describe the lipid dynamics and energy transfer in parts of the East Greenland ecosystem. Even if the two seal species showed considerable overlap in diet and occurred at relatively similar trophic levels, the fatty acid profiles indicated that the bases of the food chains of harp and hooded seals were different. The fatty acids of harp seals originate from diatom-based food chain, whereas the fatty acids of hooded seals originate from dinoflagellate and the prymnesiophyte Phaeocystis pouchetii-based food chain. Stable isotope analyses showed that both species are true carnivores on the top of their food chains, with hooded seal being slightly higher on the food chain than harp seal.     

Time lapse structure‐from‐motion photogrammetry for continuous geomorphic monitoring

Recent advances are made in earth surface reconstruction with high spatial resolution due to SfM photogrammetry. High flexibility of data acquisition and high potential of process automation allows for a significant increase of the temporal resolution, as well, which is especially interesting to assess geomorphic changes. Two case studies are presented where 4D reconstruction is performed to study soil surface changes at 15 seconds intervals: (a) a thunderstorm event is captured at field scale and (b) a rainfall simulation is observed at plot scale. A workflow is introduced for automatic data acquisition and processing including the following approach: data collection, camera calibration and subsequent image correction, template matching to automatically identify ground control points in each image to account for camera movements, 3D reconstruction of each acquisition interval, and finally applying temporal filtering to the resulting surface change models to correct random noise and to increase the reliability of the measurement of signals of change with low intensity. Results reveal surface change detection with cm‐ to mm‐accuracy. Significant soil changes are measured during the events. Ripple and pool sequences become obvious in both case studies. Additionally, roughness changes and hydrostatic effects are apparent along the temporal domain at the plot scale. 4D monitoring with time‐lapse SfM photogrammetry enables new insights into geomorphic processes due to a significant increase of temporal resolution. Copyright © 2017 John Wiley & Sons, Ltd.     

Isotopic evidence (Sr/Sr, δLi) for alteration of the oceanic crust at deep-rooted mud volcanoes in the Gulf of Cadiz, NE Atlantic Ocean

The chemical and isotopic composition of pore fluids is presented for five deep-rooted mud volcanoes aligned on a transect across the Gulf of Cadiz continental margin at water depths between 350 and 3860 m. Generally decreasing interstitial Li concentrations and ⁸⁷Sr/⁸⁶Sr ratios with increasing distance from shore are attributed to systematically changing fluid sources across the continental margin. Although highest Li concentrations at the near-shore mud volcanoes coincide with high salinities derived from dissolution of halite and late-stage evaporites, clayey, terrigenous sediments are identified as the ultimate Li source to all pore fluids investigated. Light δ⁷Li values, partly close to those of hydrothermal vent fluids (δ⁷Li: +11.9‰), indicate that Li has been mobilized during high-temperature fluid/sediment or fluid/rock interactions in the deep sub-surface. Intense leaching of terrigenous clay has led to radiogenic ⁸⁷Sr/⁸⁶Sr ratios (∼0.7106) in pore fluids of the near-shore mud volcanoes. In contrast, non-radiogenic ⁸⁷Sr/⁸⁶Sr ratios (∼0.7075) at the distal locations are attributed to admixing of a basement-derived fluid component, carrying an isotopic signature from interaction with the basaltic crust. This inference is substantiated by temperature constraints from Li isotope equilibrium calculations suggesting exchange processes at particularly high temperatures (>200 °C) for the least radiogenic pore fluids of the most distal location.Advective pore fluids in the off-shore reaches of the Gulf of Cadiz are influenced by successive exchange processes with both oceanic crust and terrigenous, fine-grained sediments, resulting in a chemical and isotopic signature similar to that of fluids in near-shore ridge flank hydrothermal systems. This suggests that deep-rooted mud volcanoes in the Gulf of Cadiz represent a fluid pathway intermediate between mid-ocean ridge hydrothermal vent and shallow, marginal cold seep. Due to the thicker sediment coverage and slower fluid advection rates, the overall geochemical signature is shifted towards the sediment-diagenetic signal compared to ridge flank hydrothermal environments.     

Seasonal to decadal forcing of high water level percentiles in the German Bight throughout the last century

For the purpose of coastal planning and management, especially under changing climatic conditions, enhanced knowledge about the evolution of extreme sea levels in the past, present, and future is required. This paper presents statistical analyses of high seasonal water level percentiles of 13 tide gauges in the German Bight, spanning over a period of up to 109 years throughout the twentieth and twenty-first centuries. Seasonal and annual high percentile time series of water levels were investigated in comparison to the mean sea level (MSL) for changes on seasonal, inter-annual, and decadal timescales. While throughout the first half of the twentieth century extreme water levels generally followed changes in MSL, during the second half of the century, linear extreme sea level trends exceeded those in MSL in the order of 9–64 cm per century. The largest, although insignificant, contribution to the magnitude of these trends occurs in the winter season (January to March), while smaller but, due to the generally lower atmospheric variability, significant changes are observed during spring (April to June). The observed multi-decadal trends are generally in good agreement with multi-decadal trends in the corresponding percentiles of local zonal surface winds. Only small parts of the trends remain unexplained. It is suggested that these remaining trends result from modifications in the local tidal regime. For the aspects of coastal planning, the findings clarify that in the German Bight, in addition to changes in MSL, potential changes in storminess and in the tidal regime significantly contribute to the development of extreme water levels. Since these factors have influenced the characteristic of extremes throughout the recent past, they also have to be taken into account when estimating design water levels for, e.g., dikes (in a warming climate) under changing greenhouse gas emissions.     

Volcanic ash layers from the Last Glacial Termination in the NGRIP ice core

The tephrochronological record of the 1400–1640 m depth (～10 000–16 000 calendar ice core years before present) of the NGRIP ice core has been established by particle screening of selected samples. Ash was identified in 20 samples. Correlation with ice, marine and terrestrial records from volcanic source regions in the northern hemisphere positively identifies the Saksunarvatn Ash and the Vedde Ash (Ash Zone 1). Major element chemistry of the remaining identified ash layers mainly points towards an Icelandic origin. This tephrochronological record provides new important marker horizons for correlating the timing of the climatic changes associated with the Last Glacial Termination within the North Atlantic region, as well as outlining more details concerning the frequency and composition of volcanic eruptions occurring at this deglaciation. Copyright © 2005 John Wiley & Sons, Ltd.     

Preservice Geography Students’ Exposure to Systems Thinking and Cooperative Learning in Environmental Education

Education for Sustainable Development (ESD) is a cross-curricular approach that needs to be accommodated in all subjects in the training of students as recommended by UNESCO. This South African case study of preservice geography students is presented for the purpose of understanding how they experienced systems thinking and a cooperative teaching strategy. A qualitative research approach was applied as the research design. Interpretation of the data was done through thematic analysis, which indicated that exposure to the pedagogic approach bore positive results. Teaching and learning strategies promoting the integration of ESD should form part of the training of geography students.