Isotopic archives of sulphate in speleothems

The hemispheric impact of industrial emissions upon atmospheric sulphur loading is reflected in the sulphur depositional history recorded in cores from ice sheets. However, these do not reveal regional variations. Recently deposited speleothems are used here as archives of regional sulphur depositional history at two locations within the United Kingdom and Ireland. δ³⁴S-so₄ and δ¹⁸O-so₄ present within speleothem carbonate are measured for the first time as part of a dual isotope approach to decode the speleothem sulphur record. The largely refractory nature of δ³⁴S-so₄ under oxidising conditions enables source provenance of atmospheric SO₂, whereas the complex cycles of isotopic exchange and fractionation during incorporation of oxygen into sulphate molecules enable δ¹⁸O-so₄ signatures to yield insights into ambient environmental conditions and biogeochemical cycling in the ecosystem above the cave. δ³⁴S-so₄ values extracted from speleothem carbonate formed within Browns Folly Mine, UK, range from +3.5 to +5.5‰ and δ¹⁸O-so₄ +10.3 to +13.7‰. Both signatures lie within the range expected from sulphate deposition in industrial locations and reflect the transfer of sulphate into speleothem calcite with little fractionation. However, δ¹⁸O-so₄ signatures at Crag Cave, western Ireland, are isotopically heavier than expected and approach isotopic equilibrium with δ¹⁸O-h₂o under reducing conditions. Dual isotope analysis of δ³⁴S-so₄ and δ¹⁸O-so₄ optimises the correct identification of sulphur sources and biogeochemical cycling prior to incorporation into the speleothem record. At carefully selected cave sites where drip water flowpaths into the cave remain oxic, speleothems hold the potential to retain records of atmospheric sulphur loading at the local and regional scale.     

Speleothem and glacier records of latest Pleistocene–early Holocene climate change in the western North American interior

Rapid and high-magnitude North Atlantic climate oscillations following the Last Glacial Maximum have been correlated to climate change events in western North America. However, the strength of teleconnections between the North Atlantic and the interior of western North America remains poorly understood. We present a U-series calibrated speleothem record from Timpanogos Cave National Monument, located at 2040 m asl in the Wasatch Mountains of Utah, spanning 13.5–10.6 ka. Additionally, we carried out a climate reconstruction for a coeval glacier advance in the Wind River Range of Wyoming. Our results indicate that between 13.5 and 12.8 ka, the Wasatch was probably first cool and dry and then warmed. After 12.8 ka, our record suggests cool and/or wetter conditions followed by reduced moisture until 11.8 ka, followed by an early Holocene wet period. The Timpanogos record exhibits few similarities with those from the North Atlantic. Climate reconstructions of the Titcomb Basin glacier suggest modest temperature depressions relative to modern (<−3 °C) were necessary to sustain the glacier with a moderate increase in precipitation (>150%). The high-altitude speleothem record presented here provides a valuable basis for understanding latest Pleistocene–early Holocene glacial episodes in western North America.     

Thérèse Mound: a case study of coral bank development in the Belgica Mound Province,Porcupine Seabight

High-resolution seismic profiles, swath bathymetry, side-scan sonar data and video imageries are analysed in this detailed study of five carbonate mounds from the Belgica mound province with special emphasis on the well-surveyed Thérèse Mound. The selected mounds are located in the deepest part of the Belgica mound province at water depths of 950 m. Seismic data illustrate that the underlying geology is characterised by drift sedimentation in a general northerly flowing current regime. Sigmoidal sediment bodies create local slope breaks on the most recent local erosional surface, which act as the mound base. No preferential mound substratum is observed, neither is there any indication for deep geological controls on coral bank development. Seismic evidence suggests that the start-up of the coral bank development was shortly after a major erosional event of Late Pliocene–Quaternary age. The coral bank geometry has been clearly affected by the local topography of this erosional base and the prevailing current regime. The summits of the coral banks are relatively flat and the flanks are steepest on their upper slopes. Deposition of the encased drift sequence has been influenced by the coral bank topography. Sediment waves are formed besides the coral banks and are the most pronounced bedforms. These seabed structures are probably induced by bottom current up to 1 m/s. Large sediment waves are colonised by living corals and might represent the initial phase of coral bank development. The biological facies distribution of the coral banks illustrate a living coral cap on the summit and upper slope and a decline of living coral populations toward the lower flanks. The data suggest that the development of the coral banks in this area is clearly an interaction between biological growth processes and drift deposition both influenced by the local topography and current regime.     

Diversity and burglary: Do community differences matter?

Diversity within a population has been linked to levels of both social cohesion and crime. Neighborhood crimes are the result of a complex set of factors, one of which is weak community cohesion. This article seeks to explore the impacts of diversity on burglary crime in a range of neighborhoods, using Leeds, UK as a case study. We propose a new approach to quantifying the correlates of burglary in urban areas through the use of diversity metrics. This approach is useful in unveiling the relationship between burglary and diversity in urban communities. Specifically, we employ stepwise multiple regression models to quantify the relationships between a number of neighborhood diversity variables and burglary crime rates. The results of the analyses show that the variables that represent diversity were more significant when regressed against burglary crime rates than standard socio‐demographic data traditionally used in crime studies, which do not generally use diversity variables. The findings of this study highlight the importance of neighborhood cohesion in the crime system, and the key place for diversity statistics in quantifying the relationships between neighborhood diversities and burglary. The study highlights the importance of policy planning aimed at encouraging community building in promoting neighborhood safety.     

Lateglacial to early Holocene multiproxy record from Loch Assynt,NW Scotland

A core, recovered from a water depth of 53 m in Loch Assynt, North-West Scotland, has yielded a 9 m sequence comprising two distinct units, an upper, organic-rich unit (Unit I, ca. 6 m) overlying a sequence of laminated clays, silts and sands (Unit II, ca. 3 m). The upper unit is essentially Holocene in age based upon three bulk AMS radiocarbon dates while a fourth radiocarbon date from Unit II confirms a late-glacial age for that interval and supports a broadly linear age–depth relationship. Distinct variations in the magnetic susceptibility record of the lower unit can be visually correlated to major changes in the Greenland ice core (GISP2), this together with pollen evidence supports the radiocarbon dating suggesting an age of approximately 11,000 to around 17,000 cal. BP for Unit II, with evidence for the Younger Dryas (Loch Lomond) stadial and the Bolling–Allerød climatic phases. Variations in the magnetic susceptibility record of the late-glacial sediments are thought to relate to climatically driven changes in soil cover and erosion rates. The multiproxy record from Loch Assynt indicates relatively continuous, sub-aqueous sedimentation during the last ～17,000 years, providing an approximate age for the initiation of modern Loch Assynt and supporting recent dates of moraine retreat lines in the Loanan Valley from about 14–15 ka BP. Pollen and chironomid sampling provides further insights to the history of this relatively deep water body and compliment existing high-resolution palaeo-precipitation records for the mid to late Holocene interval from speleothem archives within the loch catchment.     

The Holme Pierrepont sand and gravel and the timing of Middle and Late Devensian floodplain aggradation in the English Midlands

This paper provides the first detailed, multi-proxy environmental record for the character of Lateglacial conditions in the lowest Pleistocene terrace of the main valley floor of the River Trent at Holme Pierrepont near Nottingham. The analysis of pollen, plant, insect and mollusc remains preserved within organic channels near the base of the terrace, named the Holme Pierrepont Sand and Gravel by the British Geological Survey (historically known as the Floodplain Terrace), provided evidence of cool, though not fully arctic climatic conditions and a largely treeless landscape, roamed by large herbivores. Radiocarbon dating indicates that these sediments were deposited during the Loch Lomond Stadial (Younger Dryas GS-1). Comparison of these dates from Holme Pierrepont with those from morphostratigraphically similar deposits in the wider Trent catchment suggests that the Holme Pierrepont Sand and Gravel may have been laid down in two separate pulses of braidplain aggradation either side of the ‘Last Glacial Maximum’. It has been demonstrated from historical documentation and riverine archaeological evidence that the middle Trent has been particularly sensitive to changing flood frequency and magnitude associated with climatic oscillations during the late Holocene; this study demonstrates that such sensitivity appears to extend back into the late Pleistocene. The timing of fluvial aggradation recorded at Holme Pierrepont agrees broadly with that recorded from other sites across England and north-west Europe.     

The high hydraulic conductivity of three wooded tropical peat swamps in northeast Peru: measurements and implications for hydrological function

The form and functioning of peatlands depend strongly on their hydrological status, but there are few data available on the hydraulic properties of tropical peatlands. In particular, the saturated hydraulic conductivity (K) has not previously been measured in neotropical peatlands. Piezometer slug tests were used to measure K at two depths (50 and 90 cm) in three contrasting forested peatlands in the Peruvian Amazon: Quistococha, San Jorge and Buena Vista. Measured K at 50 cm depth varies between 0.00032 and 0.11 cm s^?1, and at 90 cm, it varies between 0.00027 and 0.057 cm s^?1. Measurements of K taken from different areas of Quistococha showed that spatial heterogeneity accounts for ~20% of the within‐site variance and that depth is a good predictor of K. However, K did not vary significantly with depth at Buena Vista and San Jorge. Statistical analysis showed that ~18% of the variance in the K data can be explained by between‐site differences. Simulations using a simple hydrological model suggest that the relatively high K values could lead to lowering of the water table by >10 cm within ~48 m of the peatland edge for domed peatlands, if subjected to a drought lasting 30 days. However, under current climatic conditions, even with high K, peatlands would be unable to shed the large amount of water entering the system via rainfall through subsurface flow alone. We conclude that most of the water leaves these peatlands via overland flow and/or evapotranspiration. Copyright © 2013 John Wiley & Sons, Ltd.     

PREDICTING THE DEPTH OF EROSION IN RESERVOIRS FOLLOWING DAM REMOVAL USING BANK STABILITY ANALYSIS

1 INTRODUCTION 1. 1 Dam Removal The aging of the more than 75,000 dams in the U.S., coupled with the increasing awareness of their environmental costs, has made dam decommissioning and removal a topic of current interest to the scientific community, management agencies, and the general public. It is estimated that 85% of the dams in the U.S. will be near the end of their operational lives by the year 2020 (FEMA, 1999), necessitating thorough consideration of dam removal or repair for…     

Modeling outflow from the Ernest Henry Fe oxide Cu–Au deposit: implications for ore genesis and exploration

The Ernest Henry Fe oxide Cu–Au (IOCG) deposit (>ca. 1.51 Ga) is hosted by breccia produced during the waning stages of an evolving hydrothermal system that formed a number of tens of metres to a kilometre scale, pre- and syn-ore alteration halos, although no demonstrable patterns have been attributed to fluids expelled through the outflow zones. However, the recognition of a population of hypersaline fluid inclusions representing the ‘spent’ fluids after Cu–Au deposition at Ernest Henry provides the basis to model the geochemical characteristics of the deposit's outflow zones. Geochemical modeling at 300 °C was undertaken at both high and low fluid/rock ratios via FLUSH models involving three host rock types: (1) granite, (2) calc–silicate rock, and (3) graphitic schist. In models run at high fluid/rock ratios, all rock types are essentially fluid-buffered, and produce an albite–quartz–hematite–barite-rich assemblage, although in low fluid–rock environments, the pH, redox, and geochemical character of the host rock exerts a greater influence on the mineralogy of the alteration assemblages (e.g., andradite, Fe–chlorite, and magnetite). Significant sulphide mineralization was predicted in graphitic schist where sphalerite occurred in both low- and high-porosity models, which indicates the possibility of an association between high-temperature IOCG mineralization and lower temperature base metal mineralization.Cooling experiments (from 300 to 100 °C) using the ‘spent fluids’ predict early high-T (300–200 °C) Na-, Ca-, Fe-, and Mn-rich, magnetite-bearing hydrothermal associations, whereas with cooling to below 200 °C, and with progressive fluid–rock interaction, the system produces rhodochrosite-bearing, hematite–quartz–muscovite–barite-rich assemblages. These results show that the radical geochemical and mineralogical changes associated with cooling and progressive fluid influx are likely to be accompanied by major transformations in the geophysical expression (e.g., spectral and magnetic character) of the alteration in the outflow zone, and highlight the potential link between magnetite- and hematite-bearing IOCG hydrothermal systems.     

Mesozoic–Tertiary exhumation history of the Altai Mountains, northern Xinjiang, China: New constraints from apatite fission track data

This study uses apatite fission track (FT) analysis to constrain the exhumation history of bedrock samples collected from the Altai Mountains in northern Xinjiang, China. Samples were collected as transects across the main structures related to Palaeozoic crustal accretion events. FT results and modeling identify three stages in sample cooling history spanning the Mesozoic and Tertiary. Stage one records rapid cooling to the low temperature part of the fission track partial annealing zone circa 70 ± 10 °C. Stage two, records a period of relative stability with little if any cooling taking place between 75 and 25–20 Ma suggesting the Altai region had been reduced to an area of low relief. Support for this can be found in the adjacent Junngar Basin that received little if any sediment during this interval. Final stage cooling took place in the Miocene at an accelerated rate bringing the sampled rocks to the Earth's surface. This last stage, linked to the far field effects of the Himalayan collision, most likely generated the surface uplift and relief that define the present-day Altai Mountains.