Continuous fluorescence assessment of organic matter variability on the Bournbrook River,Birmingham, UK

Continuous monitoring of dissolved organic matter (DOM) character and concentration at hourly resolution is rare, despite the importance of analysing organic matter variability at high‐temporal resolution to evaluate river carbon budgeting, river water health by detecting episodic pollution and to determine short‐term variations in chemical and ecological function. The authors report a 2‐week experiment performed on DOM sampled from Bournbrook, Birmingham, UK, an urban river for which spectrophotometric (fluorescence, absorbance), physiochemical (dissolved organic carbon [DOC], electrical conductivity, pH) and isotopic (D/H) parameters have been measured at hourly frequency. Our results show that the river had sub‐daily variations in both organic matter concentration and characteristics. In particular, after relatively high‐magnitude precipitation events, organic carbon concentration increased, with an associated increase in intensity of both humic‐like and tryptophan‐like fluorescence. D/H isotopic ratio demonstrates different hydrological responses to different rainfall events, and organic matter character reflects this difference. Events with precipitation < 2 mm typically yielded isotopically heavy water with relatively hydrophilic DOM and relatively low specific absorbance. Events with precipitation > 2 mm had isotopically lighter water with higher specific absorbance and a decrease in the proportion of microbially derived to humic‐like fluorescence. In our heavily urbanized catchment, we interpret these signals as one where riverine DOM is dominated by storm sewer‐derived ‘old’ organic matter at low‐rainfall amounts and a mixed signal at high‐precipitation amounts where ‘event’ surface runoff‐derived organic matter dominate during storm sewer and combined sewer overflow routed DOM. Copyright © 2009 John Wiley & Sons, Ltd.     

Mechanical Study of Shear Failure of Vertical Goaf Drainage Hole

Geotechnical and Geological Engineering - Most of the published research on goaf-hole failures are performed using 2D numerical analyses. However, 2D analyses of the goaf-hole failure mechanism,...     

The NOAA Goes-12 Solar X-Ray Imager (SXI) 2. Performance

The Solar X-ray Imager (SXI) was launched on 23 July 2001 on NOAAs GOES-12 satellite and completed post-launch testing on 20 December 2001. It was brought into operations on 21 January 2003. This paper documents SXI performance and calibrations prior to an instrument degradation that occurred on 5 November 2003 and thus covers more than 420000 soft X-ray images of the Sun. This paper details component-level as well as full-system calibrations characterizing the spatial and spectral performance of the instrument, including the grazing-incidence mirror, filters, and the properties of the MCP-intensified CCD detector system. Routine image corrections are also described. These include background (dark current) subtraction, flat-fielding, off-band light-leak correction, and image pointing and timing considerations. In addition, a signal-to-noise analysis is presented. The information contained in this study is intended to enable researchers to conduct quantitative analysis of GOES-12 SXI images.     

A review of the metallogeny and tectonics of the Lachlan Orogen

Future mineral exploration within eastern Australia will be enhanced by resolving the tectonic evolution of the Lachlan Orogen to establish the spatial and temporal terrane distribution of the various mineral deposits. The Lachlan Orogen, from north-eastern Tasmania through to central and eastern New South Wales, is host to a number of major mineral deposit styles—including orogenic gold (e.g. Stawell, Ballarat, Bendigo), volcanic-hosted massive sulphide (e.g. Woodlawn, Currawong), sediment-hosted Cu–Au (e.g. Cobar Basin deposits), porphyry Au–Cu (e.g. Cadia, Parkes, Cowal) and granite-related Sn (e.g. Ardlethan, Beechworth). Each of these mineral deposit styles is a sensitive and diagnostic indicator of the prevalent tectonic environment during their formation. In this review, we briefly summarise the deposit- to large-scale factors that define the diverse metallogenic evolution of the Lachlan Orogen. This overview is intended to “set the scene” for subsequent specialist papers published in this thematic issue on the metallogeny and tectonics of the Lachlan Orogen in south-east Australia.     

Funding low carbon cities: local perspectives on opportunities and risks

There are compelling reasons for policy makers to be interested in the low-carbon agenda. More than half of the world's population lives in, and more than half of the world's economic output comes from, cities. Up to 70% of global carbon emissions can also be attributed to consumption that takes place in cities. Recent research has shown that cost-effective investments in low-carbon options could deliver a 40% reduction in GHG emissions from cities by 2020, while also providing wider economic benefits such as enhanced competitiveness and increased employment. As yet, however, investments in low-carbon cities have not been made at scale due mainly to the scale of the finance required, local government budgetary constraints, and perceptions about their costs and benefits. With a focus on the UK, a contemporary account is provided of what local authorities see as the major financial risks associated with funding low-carbon cities. Practical proposals – which also have more general relevance to the future financing of low-carbon cities around the world – are offered on how local authorities, in conjunction with central government, the private sector, and institutional investors, can effectively manage these risks.

Policy relevance

Cities house more than half of the world's population, generate more than half of the world's economic output, and produce between 40% and 70% of all anthropogenic GHG emissions. In the UK, 70% of such emissions are under the influence of its local authorities. Thus, one of the key public policy challenges for the low-carbon transition is how it should be financed. There are several obstacles and related risks to this transition, including financial and legal obstacles and the differing views and perceptions of stakeholders. These can be attenuated, somewhat, by national government support at scale, local authority leadership, and cooperation between other authorities and the private sector, and the development of tools and guidance to reduce transaction costs.     

Suspended sediment and phosphorus in proglacial rivers: bioavailability and potential impacts upon the P status of ice‐marginal receiving waters

This paper adopts standard tests developed in temperate catchment research to determine the total phosphorus (TP) and the algal available (base‐extractable) phosphorus (NaOH–P) content of a wide range of glaciofluvial sediments from the Northern Hemisphere. We find that the TP content of these sediments is broadly similar to the P content of major rock types in Earth's crust (230–670 µgP/g) and so the TP yields of glacier basins may be high owing to the efficacy of suspended sediment evacuation by glacial meltwaters. We show that this is best achieved where subglacial drainage systems are present. The NaOH–P pool of the sediments is found to be low (1–23 µgP/g) relative to the TP pool and also to the NaOH–P pool of suspended sediments in temperate, non‐glacierized catchments. This most probably reflects the restricted duration of intimate contact between dilute meltwaters and glacial suspended sediments during the ablation season. Thus, despite the high surface‐area:volume ratio of glacial suspended sediments, the potential for P adsorption to mineral surfaces following release by dissolution is also low. Further, sorption experiments and sequential extraction tests conducted using glacial suspended sediments from two Svalbard catchments indicate that the generation of reactive secondary minerals (e.g. Fe‐ and other hydroxides) with a strong capacity to scavenge P from solution (and thereby promote the continued dissolution of P) may also be limited by the short residence times. Most P is therefore associated with poorly weathered, calcite/apatite‐rich mineral phases. However, we use examples from the Svalbard glacier basins (Austre Brøggerbreen and Midre Lovénbreen) to show that the high sediment yields of glaciers may result in appreciable NaOH–P loading of ice‐marginal receiving waters. Again, the importance of subglacial drainage is highlighted, as it produces a major, episodic release of NaOH–P at Midre Lovénbreen that results in a yield (8·2 kg NaOH–P/km²/year) more than one order of magnitude greater than that at Austre Brøggerbreen (where subglacial drainage is absent and the yield is 0·48 kg NaOH‐P/km²/year). Therefore, as since both detrimental and beneficial effects of sediment‐bound P loading in ice marginal receiving waters are possible (i.e. either reduced primary productivity owing to increased turbidity or P fertilization following desorption) there is a pressing need to assess the ambient P status of such environments and also the capacity for ice‐marginal ecosystems to adapt to such inputs. Copyright © 2004 John Wiley & Sons, Ltd.     

Rapid delineation of subsurface petroleum contamination using the site characterization and analysis penetrometer system

 The Site Characterization and Analysis Penetrometer System (SCAPS) was used to investigate subsurface petroleum contamination at Aberdeen Proving Ground, Maryland. The SCAPS is a rapid site-screening tool developed by the Tri-Services (U.S. Army, Navy, and Air Force) to reduce the cost of installation restoration activities. The system, consisting of a geophysical cone penetrometer fitted with a laser-induced fluorescence petroleum sensor, is capable of simultaneous, real-time delineation of subsurface stratigraphy and petroleum contamination. Onsite processing of the SCAPS data allows three-dimensional visualization of both subsurface stratigraphy and petroleum contaminant distribution. The site investigation described herein successfully identified three distinct areas of subsurface petroleum contamination caused by leaking underground storage tanks containing No. 2 healing oil. The SCAPS petroleum sensor response was verified by obtaining 20 soil samples and performing onsite and conventional laboratory analyses for petroleum contaminants. Verification sample results indicate a strong correlation between the SCAPS fluorescence data and conventional measures of petroleum contamination. This investigation illustrates the capabilities of the SCAPS for rapid site characterization. Received: 27 November 1995 · Accepted: 11 December 1995