Gypsum karst intensification as a consequence of sulphur mining activity (Jaziv field,Western Ukraine)

The scope of this study is to evaluate the parameters of the gypsum–anhydrite strata karstification under the influence of the quarry exploitation of Jaziv sulphur field (West Ukraine) accompanying by drainage. The quarry drainage provoked the enormous depression cone forming with 100 km² in area and the corresponding intensification of chemical denudation of the gypsum–anhydrite strata. The gypsum karstification rate for the 29-year period of the quarry drainage was 0.06% with the dissolved rock volume of 1,328,507 m³ that is about 80 times higher than in natural conditions. For the drainage period (29 years) the karst denudation rate was 17,952 m³/km² against the natural background of 231.3 m³/km². The absolute value of artificial denudation for the studied massif area is 1.79 cm for 29 years or 0.062 mm/year while the denudation rate under natural conditions would be 0.231 cm for 29 years or 0.0008 mm/year. The forecasted volumes of the surface-evident collapses are evaluated using the relationship between the calculated amount of dissolved sulphate rocks and volumes of the current surface-evident collapses. According to this evaluation, the current collapses correspond to about 34% only from the dissolved rocks volume calculated for the drainage period.     

RAT0455+1305: another pulsating hybrid sdB star

RAT0455+1305 was discovered during the Rapid Temporal Survey which aims in finding any variability on timescales of a few minutes to several hours. The star was found to be another sdBV star with one high amplitude mode and relatively long period. These features along with estimation of T _eff and log?g makes this star very similar to Balloon?090100001. Encouraged by prominent results obtained for the latter star we have decided to perform white light photometry on RAT0455+1305. In 2009 we used the 1.5 m telescope located in San Pedro Martir Observatory in Mexico. Fourier analysis confirmed the dominant mode found in the discovery data, uncovered another peak close to the dominant one, and three peaks in the low frequency region. This shows that RAT0455+1305 is another hybrid sdBV star pulsating in both p- and g-modes.     

Modelling the pre-failure instabilities of sand

A simple incremental model describing the pre-failure behaviour of granular soils is presented. The model describes both the dry/fully drained and undrained response. It takes into account an initial anisotropy of soil and an initial state defined as either contractive or dilative. A physically sound definition of loading/unloading is assumed, which differs from elasto-plastic approaches. The model is based on extensive empirical data and gives predictions conformable with experimental results. It also describes pre-failure instabilities of granular soils, both dry/fully drained and undrained. The Hill’s criterion was used to examine stability. It was shown that this condition can be formulated either in terms of the effective stresses or by the total stresses. In the extreme cases of either dry/fully drained or undrained conditions, these alternative formulations are equivalent. This is not so in the case of partial drainage of pore water and associated volumetric deformations as well as pore pressure changes. The model describes the pre-failure instabilities well, and additionally allows for analytical derivation of the instability line. It was shown that the second order work, appearing in the Hill’s condition, is equivalent to the entropy source.     

Damped harmonic oscillator interpretation of the soft-state power spectra of Cyg X-1

We develop a model of an accretion disc in which the variability induced at a given radius is governed by a damped harmonic oscillator at the corresponding epicyclic frequency. That variability induces both linear and non-linear responses in the locally emitted radiation. The total observed variability of a source is the sum of these contributions over the disc radius weighted by the energy dissipation rate at each radius. It is shown that this simple model, which effectively has only three parameters including the normalization, can explain the range of the power spectra observed from Cyg X-1 in the soft state. Although a degeneracy between the black hole mass and the strength of the damping does not allow a unique determination of the mass, we can still constrain it to  ≲(16–20) M_⊙  . We also show that our model preserves the observed linear rms–flux relationship even in the presence of the non-linear flux response.     

Fen ecosystem responses to water‐level fluctuations during the early and middle Holocene in central Europe: a case study from Wilczków,Poland

This paper presents a palaeoenvironmental reconstruction of the Wilczków fen (central Poland). The fen developed in an inactive valley at the onset of the Holocene (~11 ka BP) and peat accumulation lasted until 5.7 ka BP. Multi‐proxy reconstructions were made on the basis of palaeobotanical, cladoceran, chironomid, beetle and geochemical analyses. A Kohonen self‐organizing map (SOM, unsupervised artificial neural network) of the biotic sequence distinguished four stages of fen history. Stage X₁ (11.0–10.7 ka BP) was relatively wet and cool. Organic matter started to accumulate but the habitat conditions remained unstable. Moss, sedge and fern communities then developed. Sedimentary changes reveal an intensive groundwater supply at that time. Numerous and diverse chironomid and cladoceran subfossils indicate nearly permanent aquatic conditions. During stage Y₁ (10.6–9.2 ka BP) conditions were dry and the upper peat layer desiccated. Cladocera nearly disappeared whereas chironomids were represented by semi‐terrestrial and predatory (Tanypodinae) species. Conditions started to be more reducing. All the remaining samples belonged to the interweaving stages X₂ and Y₂. Stage Y₂ (mostly 9.1–7.3 and 6.0–5.7 ka BP) was also dry but humidity increased towards the top. Oxidizing conditions occurred and the pH became more alkaline, favouring Cladium mariscus. The basin received mostly allochthonous matter input at that time. Stage X₂ (mostly 6.8–6.1 ka BP) was humid and warm. The groundwater supply remained low but there was an increase in precipitation, changing local conditions to ombrotrophic. Species‐rich chironomid and cladoceran communities were associated with temporary pools. Finally, conditions returned to those characteristic of stage Y₂. The presented reconstruction documents long‐term abiotic and biotic changes determined by water supply, including groundwater outflow, which have rarely been detected at a multi‐proxy scale. We show that inactivated valley fens are sensitive to climate‐driven hydrological fluctuations. Kohonen neural networks appear to be a promising method for analysing variability in multi‐proxy data.     

Analytical and Chemometric Evaluation of the Situation of Waterbodies in the Polish Tatra Mountains

Chemometric methods are powerful in finding hidden structures and latent information in environmental and other analytical datasets. This work shows the application of cluster analysis, discriminant analysis, and support vector machines for the evaluation of waterbodies in the Polish Tatra Mountains. After the analysis of in situ parameters and the determination of concentrations of cations and anions, cluster analysis shows that the previous separation into Western Tatras and High Tatras should be reconsidered, as the Bystra stream in the border region might have been incorrectly assigned to the Western Tatras up to now. Discriminant analysis not only confirms the geographical separation of waterbodies, but also the fact that the sampling time is a crucial factor in environmental analysis. Samples taken in different months do not result in a homogenous object of investigation. A uniform date should therefore be chosen so that the results will be comparable. The influence of the sampling month on the classification of samples is also approved by support vector machines.     

Particular application of a mathematical transport model incorporating sub-surface reactive pollutants

In the first part of the paper, a 2D transport equation was used, which takes into consideration only the non-linear adsorption term described by means of non-linear Freundlich isotherm. The equation of this type was the basis of numerical calculations of concentration for chosen indicators (nitrates and biochemical oxygen demand). In the second part, the presented equation took into consideration not only the nonlinear adsorption term, but also the term of biodegradation (biological denitrification), described by the first-order microbial reaction, most often applied in practice. Numerical calculations in the first and second parts of the paper were carried out using the same numerical scheme and the author’s program PCCS-2, presented in Aniszewski (2009) and compared afterwards with the measured concentration values. The calculation results made it possible to define the reduction degree of concentration reduction for the chosen chemicals as a result of reversible sorption and biodegradation processes.     

Estimation of global lightning activity and observations of atmospheric electric field

Variations in the global atmospheric electric circuit are investigated using a wide range of globally spaced instruments observing VLF (∼10 kHz) waves, ELF (∼300 Hz) waves, Schumann resonances (4–60 Hz), and the atmospheric fair weather electric field. For the ELF/VLF observations, propagation effects are accounted for in a novel approach using established monthly averages of lightning location provided by the Lightning Image Sensor (LIS) and applying known frequency specific attenuation parameters for daytime/nighttime ELF/VLF propagation. Schumann resonances are analyzed using decomposition into propagating and standing waves in the Earth-ionosphere waveguide. Derived lightning activity is compared to existing global lightning detection networks and fair weather field observations. The results suggest that characteristics of lightning discharges vary by region and may have diverse effects upon the ionospheric potential.     

Geochemical and statistical approach to evaluate background concentrations of Cd,Cu, Pb and Zn (case study: Eastern Poland)

An attempt was made to evaluate background concentrations of Cd, Cu, Pb and Zn by means of geochemical and statistical approach. As many as 753 samples taken from 51 profiles located in Eastern Poland were analysed. For the estimation of geochemical background values, direct geochemical methods and a statistical analysis for the whole population of samples were applied. Average values of heavy metal concentration in loess sediments (bedrock) as well as in profiles not affected by human activity were measured. The iterative 2σ technique and calculated distribution function were chosen as statistical methods. The resulting values (background concentrations range) were as follows: Cd 0.5–0.9 mg kg⁻¹, Cu 5–16 mg kg⁻¹, Pb 12–26 mg kg⁻¹ and Zn 31–47 mg kg⁻¹. All the methods applied gave similar results. The highest deviation of the background was noted for Cu and the lowest for Zn. The lowest values of background were obtained for loess sediments and the highest in the case of the multiple 2σ method.