Analytical and Chemometric Evaluation of the Situation of Waterbodies in the Polish Tatra Mountains

Chemometric methods are powerful in finding hidden structures and latent information in environmental and other analytical datasets. This work shows the application of cluster analysis, discriminant analysis, and support vector machines for the evaluation of waterbodies in the Polish Tatra Mountains. After the analysis of in situ parameters and the determination of concentrations of cations and anions, cluster analysis shows that the previous separation into Western Tatras and High Tatras should be reconsidered, as the Bystra stream in the border region might have been incorrectly assigned to the Western Tatras up to now. Discriminant analysis not only confirms the geographical separation of waterbodies, but also the fact that the sampling time is a crucial factor in environmental analysis. Samples taken in different months do not result in a homogenous object of investigation. A uniform date should therefore be chosen so that the results will be comparable. The influence of the sampling month on the classification of samples is also approved by support vector machines.     

Particular application of a mathematical transport model incorporating sub-surface reactive pollutants

In the first part of the paper, a 2D transport equation was used, which takes into consideration only the non-linear adsorption term described by means of non-linear Freundlich isotherm. The equation of this type was the basis of numerical calculations of concentration for chosen indicators (nitrates and biochemical oxygen demand). In the second part, the presented equation took into consideration not only the nonlinear adsorption term, but also the term of biodegradation (biological denitrification), described by the first-order microbial reaction, most often applied in practice. Numerical calculations in the first and second parts of the paper were carried out using the same numerical scheme and the author’s program PCCS-2, presented in Aniszewski (2009) and compared afterwards with the measured concentration values. The calculation results made it possible to define the reduction degree of concentration reduction for the chosen chemicals as a result of reversible sorption and biodegradation processes.     

Estimation of global lightning activity and observations of atmospheric electric field

Variations in the global atmospheric electric circuit are investigated using a wide range of globally spaced instruments observing VLF (∼10 kHz) waves, ELF (∼300 Hz) waves, Schumann resonances (4–60 Hz), and the atmospheric fair weather electric field. For the ELF/VLF observations, propagation effects are accounted for in a novel approach using established monthly averages of lightning location provided by the Lightning Image Sensor (LIS) and applying known frequency specific attenuation parameters for daytime/nighttime ELF/VLF propagation. Schumann resonances are analyzed using decomposition into propagating and standing waves in the Earth-ionosphere waveguide. Derived lightning activity is compared to existing global lightning detection networks and fair weather field observations. The results suggest that characteristics of lightning discharges vary by region and may have diverse effects upon the ionospheric potential.     

Geochemical and statistical approach to evaluate background concentrations of Cd,Cu, Pb and Zn (case study: Eastern Poland)

An attempt was made to evaluate background concentrations of Cd, Cu, Pb and Zn by means of geochemical and statistical approach. As many as 753 samples taken from 51 profiles located in Eastern Poland were analysed. For the estimation of geochemical background values, direct geochemical methods and a statistical analysis for the whole population of samples were applied. Average values of heavy metal concentration in loess sediments (bedrock) as well as in profiles not affected by human activity were measured. The iterative 2σ technique and calculated distribution function were chosen as statistical methods. The resulting values (background concentrations range) were as follows: Cd 0.5–0.9 mg kg⁻¹, Cu 5–16 mg kg⁻¹, Pb 12–26 mg kg⁻¹ and Zn 31–47 mg kg⁻¹. All the methods applied gave similar results. The highest deviation of the background was noted for Cu and the lowest for Zn. The lowest values of background were obtained for loess sediments and the highest in the case of the multiple 2σ method.     

On some methodological problems in the use of environmental tracers to estimate hydrogeologic parameters and to calibrate flow and transport models

Environmental tracers are used qualitatively for a better formulation of conceptual models and quantitatively for assessing groundwater ages with the aid of box models or for calibrating numerical transport models. Unfortunately, tracers often yield different ages that do not represent uniquely the water ages. Difficulties result also from different definitions of age, e.g. water age, advective age, tracer age, or radiometric tracer age, that are measured differently and depend on aquifer parameters and characteristics of particular tracers. Even the movement of an ideal tracer can be delayed with respect to the advective movement of water due to diffusion exchange between mobile and immobile water zones, which for fissured rocks or thin aquifers, may lead to significant differences between advective and tracer ages, i.e. also between advective and tracer velocities. The advective velocity is of importance in water resources considerations as being related to Darcy velocity, whereas the tracer velocity is a more useful term for the prediction of pollutant transport. When a groundwater system changes from one hydrodynamic steady state to another, environmental tracers need much more time to reach a new steady state. Several tracer studies are recalled as examples of tracer-specific effects on the estimations of groundwater age.     

Non-Integrability of the Problem of a Rigid Satellite in Gravitational and Magnetic Fields

In this paper we analyse the integrability of a dynamical system describing the rotational motion of a rigid satellite under the influence of gravitational and magnetic fields. In our investigations we apply an extension of the Ziglin theory developed by Morales-Ruiz and Ramis. We prove that for a symmetric satellite the system does not admit an additional real meromorphic first integral except for one case when the value of the induced magnetic moment along the symmetry axis is related to the principal moments of inertia in a special way.     

Tithonian–Early Valanginian evolution of deposition along the proto-Caribbean margin of North America recorded in Guaniguanico successions (western Cuba)

In the Guaniguanico Mountains of western Cuba, the Late Jurassic–Early Cretaceous limestones occur in three stratigraphic successions, which have accumulated along the proto-Caribbean margin of North America. The Late Jurassic subsidence and shallow-water carbonate deposition of the Guaniguanico successions have no counterpart on the northeastern Maya block, but some distant similarities with the southeastern Gulf of Mexico may exist. Four facies types have been distinguished in the Tithonian–Lower Valanginian deposits of the Guaniguanico tectonic units. Drowning of the Late Jurassic carbonate bank of the Sierra de los Organos occurred at the Kimmeridgian/Tithonian boundary. During this boundary interval, sedimentation in the west Cuban area and southwestern margin of the Maya block (Mexico) has evolved in a similar way in response to a major second-order transgression.The Lower Tithonian ammonite assemblages of the Guaniguanico successions indicate, in general, the neritic zone. Presence of juvenile gastropods and lack of adult specimens suggest unfavorable environment for these molluscs, probably related to low oxygenation levels. The Early Tithonian transgressive phase terminated about the lower boundary of the Chitinoidella Zone. The Late Tithonian “regressive” phase is weakly marked, whereas the latest Tithonian–earliest Berriasian strata were deposited during a deepening phase. The latter transgressive phase has ended in the Late Berriasian Oblonga Subzone. We correlate the bioturbated pelagic biomicrites of the Tumbitas Member of the Guasasa Formation with a significant fall of the sea level during the latest Berriasian–Early Valanginian. The average sedimentation rate for the Tumbitas Member biomicrites was about three times faster than for the Berriasian Tumbadero Member limestones. Sedimentation rates for the Tumbitas Member and the Valanginian limestones at the DSDP Site 535 in the southeastern Gulf of Mexico were similar. In the Los Organos succession, the Late Valanginian transgressive interval is associated with radiolarian limestones and black chert interbeds in the lower part of the Pons Formation. In the Southern Rosario succession, the pelagic limestones pass into the radiolarian cherts of the Santa Teresa Formation indicating a proximity of CCD during Late Valanginian–Hauterivian times.