Microstructurally controlled trace element (Zr,U–Pb) concentrations in metamorphic rutile: An example from the amphibolites of the Bergen Arcs

As a common constituent of metamorphic assemblages, rutile provides constraints on the timing and conditions of rock transformation at high resolution. However, very little is known about the links between trace element mobility and rutile microstructures that result from synmetamorphic deformation. To address this issue, here we combine in situ LA-ICP-MS and sensitive high-resolution ion microprobe trace element data with electron back-scatter diffraction microstructural analyses to investigate the links between rutile lattice distortions and Zr and U–Pb systematics. Furthermore, we apply this integrated approach to constrain further the temperature and timing of amphibolite facies metamorphism and deformation in the Bergen Arcs of southwestern Norway. In outcrop, the formation of porphyroblastic rutile in dynamically hydrated leucocratic domains of otherwise rutile-poor statically hydrated amphibolite provides key contextual information on both the ambient conditions of hydration and deformation and the composition of the reactive fluid. Rutile in amphibolite recorded ambient metamorphic temperatures of ~590–730°C during static hydration of the granulitic precursor. By contrast, rutile from leucocratic domains in the directly adjacent shear zone indicates that deformation was accompanied by a localized increase in temperature. These higher temperatures are recorded in strain-free rutile (~600–860°C) and by Zr concentration measurements on low-angle boundaries and shear bands (620–820°C). In addition, we also observe slight depletions of Zr and U along rutile low-angle boundaries relative to strain-free areas in deformed grains from the shear zone. This indicates that crystal–plastic deformation facilitated the compositional re-equilibration of rutile upon cooling to slightly below the peak temperature of deformation. Cessation of deformation at mid-crustal conditions near ~600°C is recorded by late stage growth of small (<150 µm) rutile in the high-strain zones. U–Pb age data obtained from the strain-free and distorted rutile grains cluster in distinct populations of 437.4 ± 2.7 Ma and c. 405–410 Ma, respectively. These different ages are interpreted to reflect the difference in closure for thermally induced Pb diffusion between undeformed and deformed rutile during post-deformation exhumation and cooling. Thus, our results provide a reconstruction of the thermochronological history of the amphibolite facies rocks of the Lindås Nappe and highlight the importance of integration of microstructural data during application of thermometers and geochronometers.     

Seasonal variation in albedo and radiation exchange between a burned and unburned forested peatland: implications for peatland evaporation

Forested boreal peatlands represent a precipitation‐dependent ecosystem that is prone to wildfire disturbance. Solar radiation exchange in forested peatlands is modified by the growth of a heterogeneous, open‐crown tree canopy, as well as by likely disturbance from wildfire. Radiation exchange at the peat surface is important in peatlands, as evaporation from the peat surface is the dominant pathway of water loss in peatlands of continental western North America. We examined shortwave and longwave radiation exchange in two forested ombrotrophic peatlands of central Alberta, Canada: one with (>75 years since wildfire; unburned) and another without a living spruce canopy (1–4 years since wildfire; burned) between the autumn of 2007 and 2010. Above‐canopy winter albedo was nearly two times greater in the recently burned peatland than the unburned peatland. Incoming shortwave radiation at the peat surface was much higher at the burned peatland, which increases the amount of energy available for evaporation. This is especially true for hollow microforms that are generally shaded by the tree canopy in unburned peatlands. Snow‐free albedo was similar between peatlands, although an increase in longwave losses at the burned site resulted in slightly greater net radiation at the unburned site. Copyright © 2015 John Wiley & Sons, Ltd.     

The effect of increasing gravel cover on forest roads for reduced sediment delivery to stream crossings

Direct sediment inputs from forest roads at stream crossings are a major concern for water quality and aquatic habitat. Legacy road–stream crossing approaches, or the section of road leading to the stream, may have poor water and grade control upon reopening, thus increasing the potential for negative impacts to water quality. Rainfall simulation experiments were conducted on the entire running surface area associated with six reopened stream crossing approaches in the south‐western Virginia Piedmont physiographic region, USA. Event‐based surface run‐off and associated total suspended solid (TSS) concentrations were compared among a succession of gravel surfacing treatments that represented increasing intensities of best management practice (BMP) implementation. The three treatments were no gravel (10–19% cover), low gravel (34–60% cover), and high gravel (50–99% cover). Increased field hydraulic conductivity was associated with maximized surface cover and ranged from 7.2 to 41.6, 11.9 to 46.3, and 16.0 to 58.6 mm h⁻¹ respectively for the no gravel, low gravel, and high gravel treatments. Median TSS concentration of surface run‐off for the no gravel treatment (2.84 g l⁻¹) was greater than low gravel (1.10 g l⁻¹) and high gravel (0.82 g l⁻¹) by factors of 2.6 and 3.5 respectively. Stream crossing approaches with 90–99% surface cover had TSS concentrations below 1 g l⁻¹. Reducing the length of road segments that drain directly to the stream can reduce the costs associated with gravel surfacing. This research demonstrates that judicious and low‐cost BMPs can ameliorate poor water control and soil erosion associated with reopening legacy roads. Copyright © 2014 John Wiley & Sons, Ltd.     

Fluvial organic carbon composition and concentration variability within a peatland catchment—Implications for carbon cycling and water treatment

Fluvial organic carbon (OC) transformations are an important component of carbon cycling and greenhouse gas production in inland waters resulting in considerable recent interest in the fate of fluvial OC exported from carbon rich soils such as peatlands. Additionally, peatland catchments are important drinking water collection areas, where high OC concentrations in runoff have water treatment implications. This analysis presents the results from a year‐round intensive study within a water treatment catchment draining an area of peatland, considering carbon transformations along a continuum from headwater river, through a storage reservoir and pipe, to a water treatment works. The study uses a unique combination of methods (colourmetric, ultrafiltration, and ¹⁴C radiocarbon dating) to assess catchment wide changes in fluvial carbon composition (colour, size, and age) alongside concentration measures. The results indicate clear patterns of carbon transformations in the river and reservoir and dissolved low molecular weight coloured carbon to be most subject to change, with both loss and replacement within the catchment residence time. Although the evidence suggests dissolved OC (DOC) gains are from particulate OC breakdown, the mechanisms of DOC loss are less certain and may represent greenhouse gas losses or conversions to particulate OC. The transformations presented here appear to have minimal impact on the amount of harder to treat (<10 kDa) dissolved carbon, although they do have implications for total DOC loading to water treatment works. This paper shows that peatland fluvial systems are not passive receptors of particulate and dissolved organic carbon but locations where carbon is actively cycled, with implications for the understanding of carbon cycling and water treatment in peatland catchments.     

Post Gondwana breakup evolution of the SE Australia rifted margin revisited

Low‐temperature thermochronology (LTT) is commonly used to investigate onshore records of continental rifting and geomorphic evolution of passive continental margins. The SE Australian passive margin, like many others, has an elevated plateau separated from the coastal plain by an erosional escarpment, presumed to originate through Cretaceous rifting prior to Tasman Sea seafloor spreading. Previous LTT studies have focused on reconciling thermal histories with development of the present‐day topography. New apatite LTT data along an escarpment‐to‐coast transect define a classic “boomerang” (mean track length vs. fission‐track age), indicating variable overprinting of late‐Palaeozoic cooling ages by a younger, mid‐Cretaceous cooling event. Regionally, however, the boomerang trend diverges NNW away from the coast and crosses the escarpment, implying the underlying thermal history pre‐dates escarpment formation and is largely independent from post‐breakup landscape evolution. We suggest that Cretaceous cooling might relate to erosion of Permo‐Triassic sedimentary cover from a formerly more extensive Sydney Basin.     

A detailed post‐IR IRSL dating study of the Niuyangzigou loess site in northeastern China

In this study, we report standard quartz SAR OSL and post‐IR infrared (IR) stimulated luminescence (post‐IR IRSL; pIRIR₂₉₀) measurements made on sand‐sized quartz and K‐feldspar extracts from the loess‐palaeosol sequence at Niuyangzigou in northeastern China. The quartz OSL characteristics are satisfactory. Extensive pIRIR_50,290 dose recovery tests were performed by adding doses on top of the natural dose. We found that dose recovery ratios improve significantly when the test dose ranges between ~15 and ~80% of the total dose, and good dose recovery (within ±5% of unity) can be obtained up to ～800 Gy. Otherwise, the dose recovery ratio deviates from unity. The D_e values also depend on the test dose size and so we conclude that the effect of test dose size should be routinely considered in pIRIR dating. First IR stimulation plateau pIRIR₂₉₀ results are compared with multiple elevated temperature ‐pIRIR (MET‐pIRIR) data. It appears that the low temperature MET‐pIRIR data are strongly affected by poor dose recovery, but this is not the case for the pIRIR₂₉₀ results. Natural signal measurements at the highest (first IR) stimulation temperature on a sample expected to be in field saturation suggest that ~10% signal loss occurs in pIRIR signals. Long‐term laboratory bleaching experiments (>80 days) show that a constant (or very difficult to bleach) residual pIRIR₂₉₀ signal is reached after ~300 h, corresponding to a dose of 6.2±0.7 Gy. Quartz OSL and feldspar pIRIR_50,290 ages are in good agreement at least back to c. 70 ka. Beyond this the quartz ages begin to underestimate but the feldspar ages are in agreement with the expected Last Interglacial age palaeosol.