Setting new thermal standards for transitional and coastal (TraC) waters

The construction of a new generation of coastal power stations in the UK and other western European countries has highlighted the absence of robust standards for thermal discharges to transitional and coastal waters. The proposed discharge volumes are greater than hitherto, yet there has been little independent critical examination of their potential impact, whilst much of the existing guidance has been adapted from freshwater practice. This review considers the available knowledge on the tolerance and behaviour of fish and other marine biota to heated effluents. Appropriate ways are suggested of grouping fish species to reflect their sensitivity to thermal effects. The plethora of existing standards are considered and their validity assessed in a framework of predicted seawater temperature rise. Those species or groups of organisms most likely to be affected are identified and finally specific recommendations for thermal standards consistent with long term sustainability are proposed.     

Carbon and sulfur in the Swaziland sequence

Sedimentary and igneous rocks of the Swaziland Sequence of South Africa (>3,200 my. old) contain total carbon (0.09–8.28%), organic carbon (0.04–1.95%) and sulfur (9–53,000 ppm). Amounts of organic carbon are generally high in the lower part of the Sequence (based on two samples from the Theespruit Formation). Sulfur content varies widely with no obvious correlations or trends. These rocks may contain clues to the early carbon and sulfur cycles on earth.     

Flood hydrology and geomorphic effectiveness in the central Appalachians

This paper compares hydrologic records and geomorphic effects of several historic floods in the central Appalachian region of the eastern United States. The most recent of these, occurring in November 1985, was the largest ever recorded in West Virginia, with peak discharges exceeding the estimated 500-year discharge at eight of eleven stations in the South Branch Potomac River and Cheat River basins. Geomorphic effects on valley floors included some of the most severe and widespread floodplain erosion ever documented and exceeded anything seen in previous floods, even though comparable or greater rainfall and unit discharge have been observed several times in the region over the past 50 years. Comparison of discharge-drainage area plots suggests that the intensity and spatial scale of the November 1985 flood were optimal for erosion of valley floors along the three forks of the South Branch Potomac River. However, when a larger geographic area is considered, rainfall totals and discharge-drainage area relationships are insufficient predictors of geomorphic effectiveness for valley floors at drainage areas of 250 to 2500 km². Unit stream power was calculated for the largest recorded flood discharge at 46 stations in the central Appalachians. Maximum values of unit stream power are developed in bedrock canyons, where the boundaries are resistant to erosion and the flow cross-section cannot adjust its width to accommodate extreme discharges. The largest value was 2570 W m^?2; record discharge at most stations was associated with unit stream power values less than 300 W m^?2, but more stations exceeded this value in the November 1985 flood than in the other floods that were analysed. Unit stream power at indirect discharge measurement sites near areas experiencing severe erosion in this and other central Appalachian floods generally exceeded 300 W m^?2; reach-average values of 200-500 W m^?2 were calculated for valleys where erosion damage was most widespread. Despite these general trends, unit stream power is not a reliable predictor of geomorphic change for individual sites. Improved understanding of flood impacts will require more detailed investigation of interactions between local site characteristics and patterns of flood flow over the valley floor.     

Growing up green on serpentine soils: Biogeochemistry of serpentine vegetation in the Central Coast Range of California

Serpentine soils derived from the weathering of ultramafic rocks and their metamorphic derivatives (serpentinites) are chemically prohibitive for vegetative growth. Evaluating how serpentine vegetation is able to persist under these chemical conditions is difficult to ascertain due to the numerous factors (climate, relief, time, water availability, etc.) controlling and affecting plant growth. Here, the uptake, incorporation, and distribution of a wide variety of elements into the biomass of serpentine vegetation has been investigated relative to vegetation growing on an adjacent chert-derived soil. Soil pH, electrical conductivity, organic C, total N, soil extractable elements, total soil elemental compositions and plant digestions in conjunction with spider diagrams are utilized to determine the chemical relationships of these soil and plant systems. Plant available Mg and Ca in serpentine soils exceed values assessed in chert soils. Magnesium is nearly 3 times more abundant than Ca in the serpentine soils; however, the serpentine soils are not Ca deficient with Ca concentrations as high as 2235 mg kg⁻¹. Calcium to Mg ratios (Ca:Mg) in both serpentine and chert vegetation are greater than one in both below and above ground tissues. Soil and plant chemistry analyses support that Ca is not a limiting factor for plant growth and that serpentine vegetation is actively moderating Mg uptake as well as tolerating elevated concentrations of bioavailable Mg. Additionally, results demonstrate that serpentine vegetation suppresses the uptake of Fe, Cr, Ni, Mn and Co into its biomass. The suppressed uptake of these metals mainly occurs in the plants’ roots as evident by the comparatively lower metal concentrations present in above ground tissues (twigs, leaves and shoots). This research supports earlier studies that have suggested that ion uptake discrimination and ion suppression in the roots are major mechanisms for serpentine vegetation to tolerate the chemistry of serpentine soils.     

Growth of diamond in hydrous silicate melts

This study demonstrates that a hydrous, halide bearing silicate melt is a viable medium for diamond growth. Experiments were conducted in the MgO–SiO₂–H₂O–C ± KCl ± NaCl system, which was used as a model for harzburgitic mantle. In no case did we observe crystals that could be interpreted as spontaneously nucleated, but growth of diamond on seed crystals at 1,400–1,600°C and 7 GPa in experiments of 4 h duration was observed. The addition of KCl to the system produced crystallization of diamond at temperatures as low as 1,400°C. At higher temperatures, larger growth features were produced than those that seen in the KCl-free system at the same conditions. The NaCl-bearing system is different; in these experiments, the diamond seed crystals show evidence of possible dissolution and layer growth, albeit more subdued growth than in the KCl system. Therefore, NaCl may be an inhibitor of diamond growth in a hydrous silicate melt. Based on these results, hydrous silicate melts could play a role in formation of diamond in either deep subduction zones, or above slabs imbricated against a lithospheric ‘root’ in the sub-continental lithospheric mantle. The water and halide necessary for their formation could be transported into the mantle in hydrous phases such as serpentine in subducting lithospheric slabs. Dehydration of serpentine at >200 km depth would release hydrous, halide-bearing fluids into the overlying mantle wedge or lithospheric root, triggering melting at conditions similar to those of the formation of natural diamond.     

Abiotic interactions of natural dissolved organic matter and carbonate aquifer rock

Abiotic interactions between natural dissolved organic matter (NDOM) and carbonate aquifer rock may be controlling factors of biogeochemical processes and contaminant fate in carbonate aquifer systems. The importance and effects of these interactions were examined using batch adsorption experiments of soil NDOM and representative carbonate sorbents from the Floridan Aquifer. Adsorption of NDOM carbon to aquifer rocks was well-described using a modified linear model and was mostly reversible. Significant adsorption was observed at higher NDOM concentrations, while the release of indigenous organic matter from the rocks occurred at lower concentrations. Longer interaction periods led to more adsorption, indicating that adsorption equilibrium was not achieved. For relatively pure carbonate rock samples, sorbent surface area was found to be the most important controlling factor of adsorption, whereas the presence of indigenous organic matter and subdominant mineral phases were more important, when they occurred. Preferential adsorption of a high over low molecular weight and humic over fulvic components of NDOM onto carbonate sorbents was detected using liquid size exclusion chromatography and excitation–emission fluorometry, respectively. The presence of NDOM inhibited mineral dissolution, though this inhibition was not proportional to NDOM concentration as surface area and mineralogy of carbonate sorbents played additional roles. Though the NDOM–carbonate rock adsorption mechanism could not be completely determined due to the heterogeneity and complexity of NDOM and sorbent surfaces, it is speculated that both rapid and weak outer-sphere bonding and stronger but slower hydrophobic interaction occur. These results have important implications for groundwater quality and hydrogeologic projects such as aquifer storage and recovery.     

Physical dynamics controlling variability in nearshore fecal pollution: Fecal indicator bacteria as passive particles

We present results from a 5-h field program (HB06) that took place at California’s Huntington State Beach. We assessed the importance of physical dynamics in controlling fecal indicator bacteria (FIB) concentrations during HB06 using an individual based model including alongshore advection and cross-shore variable horizontal diffusion. The model was parameterized with physical (waves and currents) and bacterial (Escherichia coli and Enterococcus) observations made during HB06. The model captured surfzone FIB dynamics well (average surfzone model skill: 0.84 {E. coli} and 0.52 {Enterococcus}), but fell short of capturing offshore FIB dynamics. Our analyses support the hypothesis that surfzone FIB variability during HB06 was a consequence of southward advection and diffusion of a patch of FIB originating north of the study area. Offshore FIB may have originated from a different, southern, source. Mortality may account for some of the offshore variability not explained by the physical model.     

Impact of urban stormwater runoff on estuarine environmental quality

Urban stormwater runoff could contribute to the deterioration of water quality of a receiving water body. In this research, field studies and laboratory experiments were conducted to assess the microbial contamination resulting from urban stormwater runoff into the Lake Pontchartrain estuary. Fecal coliform, Escherichia coli and enterococci were used as indicator organisms. The specific objectives of the research were to examine the distribution of the indicator organisms in different environmental elements (water column, suspended particles and sediment) and to further investigate the mechanisms related to their fate. Results of the research indicated satisfactory water quality at the study sites during dry weather periods. However, a significant increase was observed in the concentrations of the indicator organisms in the water columns and sediment at specific study sites following a given stormwater event. Three to seven days were needed for the elevated indicator organisms to return back to their background levels in the water column and sediment, respectively. The mechanism of sedimentation contributed to a reduction in the microbial concentration in the water column, as the indicator organisms were found to attach to the suspended particles in the stormwater. The percentage of fecal coliform, E. coli and enterococci attached to the suspended particles was found to be within the range of 9.8–27.5%, 21.8–30.4%, and 8.4–11.5% of the total indicator organisms in the stormwater loaded into the estuary, respectively. About 75–80% of the total indicator organisms remained free-floating for some distance in the water column before dying off.     

An investigation of upper mantle heterogeneity beneath the Archaean and Proterozoic crust of western Canada from Lithoprobe controlled-source seismic experiments

Observations of upper mantle reflectivity at numerous locations around the world have been linked to the presence of a heterogeneous distribution of rock types within a broad layer of the upper mantle. This phenomenon is observed in wide-angle reflection data from Lithoprobe's Alberta Basement Transect [the SAREX and Deep Probe experiments of 1995] and Trans-Hudson Orogen Transect [the THoRE experiment of 1993]. SAREX and Deep Probe image the Archaean lithosphere of the Hearne and Wyoming Provinces, whereas THoRE images the Archaean and Proterozoic lithosphere of the Trans-Hudson Orogen and neighbouring areas.Finite-difference synthetic seismograms are used to constrain the position and physical properties of the reflective layer. SAREX/Deep Probe modelling uses a 2-D visco-elastic finite-difference routine; THoRE modelling uses a pseudospectral algorithm. In both cases, the upper mantle is parameterized in terms of two media. One medium is the background matrix; the other is statistically distributed within the first as a series of elliptical bodies. Such a scheme is suitable for modelling: (1) variations in lithology (e.g., a peridotite matrix with eclogite lenses) or (2) variations in rheology (e.g., lenses of increased strain within a less strained background).The synthetic seismograms show that the properties of heterogeneities in the upper mantle do not change significantly between the two Lithoprobe transects. Beneath the Trans-Hudson Orogen in Saskatchewan, the layer is best modelled to lie at depths between 80 and 150 km. Based on observations from perpendicular profiles, anisotropy of the heterogeneities is inferred. Beneath the Precambrian domains of Alberta, 400 km to the west, upper mantle heterogeneities are modelled to occur between depths of 90 and 140 km. In both cases the heterogeneous bodies within the model have cross-sectional lengths of tens of kilometers, vertical thicknesses less than 1 km, and velocity contrasts from the background of − 0.3 to − 0.4 km/s. Based on consistency with complementary data and other results, the heterogeneous layer is inferred to be part of the continental lithosphere and may have formed through lateral flow or deformation within the upper mantle.     

Experimental partitioning of trace elements into schreibersite with applications to IIG iron meteorites

Some of the defining characteristics of the IIG iron meteorite group are their high bulk P contents and massive, coarse schreibersite, which have been calculated to make up roughly 11–14 wt% of each specimen. In this study, we produced two data sets to investigate the formation of schreibersites in IIG irons: measurements of trace elements in the IIG iron meteorite Twannberg and experimental determinations of trace element partitioning into schreibersite. The schreibersite‐bearing experiments were conducted with schreibersite in equilibrium with a P‐rich melt and with bulk Ni contents ranging from 0 to 40 wt%. The partitioning behavior for the 20 elements measured in this study did not vary with Ni content. Comparison of the Twannberg measurements with the experimental results required a correction factor to account for the fact that the experiments were conducted in a simplified system that did not contain a solid metal phase. Previously determined solid metal/P‐rich melt partition coefficients were applied to infer schreibersite/solid metal partitioning behavior from the experiments, and once this correction was applied, the two data sets showed broad similarities between the schreibersite/solid metal distribution of elements. However, there were also differences noted, in particular between the Ni and P contents of the solid metal relative to the schreibersite inferred from the experiments compared to that measured in the Twannberg sample. These differences support previous interpretations that subsolidus schreibersite evolution has strongly influenced the Ni and P content now present in the solid metal phase of IIG irons. Quantitative attempts to match the IIG solid metal composition to that of late‐stage IIAB irons through subsolidus schreibersite growth were not successful, but qualitatively, this study corroborates the striking similarities between the IIAB and IIG groups, which are highly suggestive of a possible genetic link between the groups as has been previously proposed.