Soil hydrophobic effects on infiltration and catchment runoff

After dry summers or drought, eucalypt forest soils at two sites in southeastern Australia developed hydrophobic or non-wetting surface characteristics that reduced infiltration, measured using a sprinkling infiltrometer. At one site the development of hydrophobic conditions caused the rainfall to runoff conversion efficiency of a forested catchment to increase from 5 per cent to 15 per cent. Under non-hydrophobic conditions at this site, grassland always generated more runoff than forest. However, one major rainfall-runoff was recorded at a time of highly hydrophobic forest soil conditions and this storm generated greater runoff on the forested catchment than the grassland catchment. At the second site forest soils have naturally highly conductive surface layers because of a dense network of macropores and pathways for preferential flow. Hydrophobic conditions produced by drought caused soil water movement to be confined to only a few of the larger macropores exposed to surface ponded water. Even so, infiltration rates remained relatively high so that the impacts of hydrophobic soils were not translated into increased catchment runoff as at the first site.     

Kornerupine in Mg-Al-rich gneisses from Namaqualand,South Africa: mineralogy and evidence for late-metamorphic fluid activity

Three kornerupine occurrences are reported in distinctive SiO₂-poor, MgO- and Al₂O₃-rich paragneisses from the Namaqualand Metamorphic Complex in South Africa. Kornerupine coexists stably with phlogopite, cordierite, orthopyroxene, gedrite, sapphirine, sillimanite and plagioclase and, in sapphirine-free rocks, with spinel and corundum. Tourmaline of a texturally older generation than kornerupine is commonly present in the same samples.Ten analysed kornerupines show a variation in total Fe as FeO from 1.8 to 10.9 weight per cent. B₂O₃ contents are estimated from x-ray data and a few spectrochemical analyses to range from 0.9 to 3.5 weight per cent. There is a strong inverse correlation between B³⁺ and Al³⁺. Total iron content has a strong and systematic effect on refractive index, colour and dispersion. Fe and Mg are systematically partitioned with the other minerals, and Mg/(Mg+Fe) ratios increase as follows: spinel 相似文献   

Al,Si ordering in cordierite using “magic angle spinning” NMR

A method of determining the number of Al-O-Al bonds per unit cell from ²⁹Si nuclear magnetic resonance (NMR) data of synthetic cordierites with increasing Si, Al order is described. The number of Al-O-Al bonds is found to vary linearly with the logarithm of the annealing time. This may be correlated with previously published heat of solution data on similar samples (Carpenter et al. 1983) to determine the enthalpy change Δh, associated with a single Al?Si interchange in cordierite. Δh is found to be 8.1 kcal/mole. The NMR data show that the short range Al, Si order cannot be described in terms of twin domains of ordered orthorhombic cordierite. An ordering model derived from group theoretical constraints on possible Al, Si distributions within the hexagonal symmetry of the cordierite is found to provide a better fit to the NMR data.     

Slope process change and colluvium deposition in Swaziland: An SEM analysis

Electron microscope analysis of sixty samples taken from six colluvium sites in Swaziland has shown that the quartz grains exhibit marked edge abrasion in the uppermost beds of exposures. This edge abrasion is lacking in the lower beds in all sections examined and indicates slope process change during colluvium deposition. A model of slope evolution is provided, in which slope erosion progressively brings about more channelling and causes greater surface roughness because of the exhumation of more core stones and differentially weathered rock. This roughness causes increased edge abrasion.     

Interdecadal climate variability in the subpolar North Atlantic

The statistical relationships between various components of the subpolar North Atlantic air-sea-ice climate system are reexamined in order to investigate potential processes involved in interdecadal climate variability. It is found that sea surface temperature anomalies concentrated in the Labrador Sea region have a strong impact upon atmospheric sea level pressure anomalies over Greenland, which in turn influence the transport of freshwater and ice anomalies out of the Arctic Ocean, via Fram Strait. These freshwater and ice anomalies are advected around the subpolar gyre into the Labrador Sea affecting convection and the formation of Labrador Sea Water. This has an impact upon the transport of North Atlantic Current water into the subpolar gyre and thus, also upon sea surface temperatures in the region. An interdecadal negative feedback loop is therefore proposed as an internal source of climate variability within the subpolar North Atlantic. Through the lags associated with the correlations between different climatic components, observed horizontal advection time scales, and the use of Boolean delay equation models, the time scale for one cycle of this feedback loop is determined to have a period of about 21 years.     

Simulation of the effect of doubled atmospheric CO2 on the climate of northern and central California

A Local Climate Model (LCM) is described that can provide a high-resolution (10 km) simulation of climate resulting from a doubling of atmospheric CO₂ concentrations. A canonicalregression function is used to compute the monthly temperature (mean of daily-maximum-temperature) and precipitation for any point, given a set of predictor variables. Predictor variables represent the influence of terrain, sea-surface temperature (SST), windfields, CO₂ concentration, and solar radiation on climate. The canonical-regression function is calibrated and validated using empirical windfield, SST, and climate data from stations in the western U.S. To illustrate an application of the LCM, the climate of northern and central California is simulated for a doubled CO₂ (600 ppmv) and a control scenario (300 ppmv CO₂). Windfields and SSTs used to compute predictor variables are taken from general circulation model simulations for these two scenarios. LCM solutions indicate that doubling CO₂ will result in a 3 C° increase in January temperature, a 2 C° increase in July temperature, a 16 mm (37%) increase in January precipitation, and a 3 mm (46%) increase in July precipitation.     

River channel adjustments downstream from channelization works in England and Wales

Relatively little attention has been given to river channel adjustments that occur downstream from channelization works. This study is concerned with the nature of channel adjustments downstream from a total of 46 channelization works located in low and high energy environments in England and Wales. Channel changes are identified principally by the method of field survey and by reconstructing the original positions of eroded beds and banks. Use is also made of maps, aerial photographs, and engineering drawings of different dates and the technique of space-for-time substitution is applied. Enlargement of channel cross-sections through erosion had occurred downstream from a variety of types, sizes, and dates of channelization works. The maximum increase of channel size was 153 per cent. Out of a total of 14 sites with enlarged channel cross-sections, seven had undergone a change of width only, at a further three width increased rather than depth, and at the remaining four sites depth increases were dominant. These sites all have relatively high stream powers. Factors causing spatial variation of erosion included tree roots locally binding bank sediments and the occurrence of bends. Planform change had taken place at only one site. A further three high stream power sites had downstream reaches incised into bedrock and therefore did not exhibit adjustment. Channel enlargement is explained in terms of increased flood flows downstream from channelization works causing higher stream velocities, which in turn cause erosion, thereby increasing channel width and/or depth. Examination of flow records for 35 stations revealed flood events which would formerly have spread overbank but are now confined by the channelization works and are therefore likely to alter downstream flows. At sites with downstream change it is proposed that the energy of increased flows was sufficient to exceed a threshold required for erosion of perimeter sediments. By contrast the absence of change at a majority of sites in low energy lowland areas could be a reflection of both the incompetence of increased flows to erode and resistance provided by perimeter sediments. Sites with erosion features appear not to have yet attained new equilibrium conditions.     

Patterns of dissolved organic matter in subarctic peatlands

Samples of water from poor to very rich fens in the Schefferville region of subarctic Quebec revealed strong spatial and temporal variations in dissolved organic carbon (DOC), ranging from 2 to 40 mg 1^?1. Concentrations of DOC tend to increase during the summer and decrease in the autumn, at most sites, which probably reflects increased plant tissue decomposition and higher rates of evapotranspiration. Principal components analysis revealed that DOC is strongly associated with Fe, NO^?₃-N and NO^?₂-N, but essentially independent of other chemical properties of the peat water, such as pH, Ca, Mg, K, P, and NH⁺₄-N. Based on observed concentrations of DOC and estimates of summer runoff (June to September), export of DOC from four peatlands ranges from 1·1 to 4·9 gCm^?2, with the lowest values for peatlands underlain by dolomite. Molecular weight fractionation of four samples revealed significant differences in the dissolved organic matter (DOM), with the largest fractions (GF/C to 10 000 nmw) being dominant in the more acid samples. The ratio of absorbance at 400 and 600 nm wavelengths (E₄:E₆) has been used as a simple indicator of differences in DOM type, ranging from 3 to 15. There is a strong seasonal pattern of increasing E₄:E₆ ratio during the summer at many sites, though this ratio is essentially independent of other chemical properties of peat waters.     

Possible effects of pre-existing basement topography on thrust fault ramping

Finite-element models show that one way in which thrust ramps may arise is through the mechanical interaction between basement and overlying sediments. In the simplest case, shear coupling between a planar basement—sediment contact causes the differential stresses in the sediments to die out with depth and distance from the applied load. For such cases, curved thrust faults may result if the strength of the rock is exceeded. Basement topography may also affect the location and shape of ramps by acting as a stress concentrator, by producing a stress shadow and by changing principal stress orientations. Modeling suggests that whether or not these basement topographic features cause ramping will depend on the height and angularity of the feature as well as the rock types that overlie it.Under the assumption of linear elasticity and for given boundary conditions, the Poisson's ratio plays an important role in determining the orientation and magnitude of the principal stresses. Calculations using experimentally measured Poisson's ratios predict that the earliest maximum compressive stress directions should be nearly vertical in the more cratonward portions of thrust belts. However, the stress directions which are inferred to have occurred earliest in this part of thrust belts are nearly horizontal. This suggests that non-elastic or ductile processes have an effect on the propagation of thrust faults.