The biogeochemical sulfur cycle in the marine boundary layer over the Northeast Pacific Ocean

The major components of the marine boundary layer biogeochemical sulfur cycle were measured simultaneously onshore and off the coast of Washington State, U.S.A. during May 1987. Seawater dimethylsulfide (DMS) concentrations on the continental shelf were strongly influenced by coastal upwelling. Concentration further offshore were typical of summer values (2.2 nmol/L) at this latitude. Although seawater DMS concentrations were high on the biologically productive continental shelf (2–12 nmol/L), this region had no measurable effect on atmospheric DMS concentrations. Atmospheric DMS concentrations (0.1–12 nmol/m³), however, were extremely dependent upon wind speed and boundary layer height. Although there appeared to be an appreciable input of non-sea-salt sulfate to the marine boundary layer from the free troposphere, the local flux of DMS from the ocean to the atmosphere was sufficient to balance the remainder of the sulfur budget.     

Nutrient pore water chemistry,Great Bay,New Hampshire: Benthic fluxes

Benthic fluxes of C, N, P and Si have been measured at two sites in Great Bay Estuary, New Hampshire. Higher fluxes of reactive phosphate, nitrate and reactive silicate were observed at the site where bioturbation is known to occur and the fluxes of NH₄ ⁺, PO₄ ^?3 and reactive silicate at this location were from 3 to 6 times higher than that calculated by simple pore water diffusion models. *** DIRECT SUPPORT *** A01BY019 00010     

Observational estimation of heat budgets on drifting ice and open water over the Arctic Ocean

It is of major scientific interests to determine the parameters of momentum, heat and vapor exchange in the planetary boundary layer in order to study the effects of ocean-ice-atmosphere interactions and their feedback mechanisms on global climate[1]. Lin…     

The geometry and petrogenesis of hydrothermal dolomites at Navan, Ireland

The dolomites at Navan, Ireland, formed in Courceyan peritidal and shallow-shelf limestones. The dolomite body has a plume-like geometry, cross-cutting both lithological boundaries and diagenetic barriers generated by sea-floor cementation and emergence. The dolomitizing fluids rose parallel to major faults to diffuse laterally through the succession, controlled by variations in permeability that reflect both facies variation on deposition and pre-dolomitization diagenesis. Cathodoluminescent zones reveal three principal stages of dolomite emplacement, separated by dissolution surfaces, with each stage reflecting several changes in the character of dolomitizing solutions. The predominance of dull zones indicates burial rather than surface conditions. The dolomites formed some time after burial in response to an areally limited hydrothermally-driven flow. Isotope values (σ¹⁸O of — 6σ6 to — 10.4%_δ and σ¹³C of — 0σ2 to +2σ5%_δ PDB), and fluid inclusion data, suggest that these fluids had compositions similar to those of Carboniferous seawater. However, these became hotter with time, with temperature increasing from 60 to 160δC. The Navan dolomites are closely associated with Europe's largest zinc-lead deposit. The distribution of the ores follows the same trend as that of the dolomites and paragenetic relationships indicate that dolomitization and mineralization were temporally and genetically related.     

Al,Si ordering in cordierite using “magic angle spinning” NMR

A method of determining the number of Al-O-Al bonds per unit cell from ²⁹Si nuclear magnetic resonance (NMR) data of synthetic cordierites with increasing Si, Al order is described. The number of Al-O-Al bonds is found to vary linearly with the logarithm of the annealing time. This may be correlated with previously published heat of solution data on similar samples (Carpenter et al. 1983) to determine the enthalpy change Δh, associated with a single Al?Si interchange in cordierite. Δh is found to be 8.1 kcal/mole. The NMR data show that the short range Al, Si order cannot be described in terms of twin domains of ordered orthorhombic cordierite. An ordering model derived from group theoretical constraints on possible Al, Si distributions within the hexagonal symmetry of the cordierite is found to provide a better fit to the NMR data.     

The OSO-1 solar neutron experiment

BF₃ counters on OSO-1 were used to look for solar neutrons by trying to observe a diurnal variation in count rate. No effect was observed and an upper limit was placed on the solar neutron flux at the earth of J _n < 2 × 10^–3 neut/cm²/sec of 10 keV < E _n < 10 meV for the period March to May 1962. No proton-producing flares occurred during this time, so the most obvious source of solar neutrons could not be studied. The emulsion experiment of Apparao et al., flown during this period, which seemed to indicate solar neutrons has probably been misinterpreted.     

Cloud effects on air-sea interactions during the 1979 Indian summer monsoon as studied from satellite observations

Summary The Indian summer monsoon, one of the earth's most vigorous and energetic seasonally occurring weather events, influences the global atmospheric circulation. Its onset, duration, and intensity are governed by large- and meso-scale geophysical processes, such as surface solar heating and air-sea interactions. In this paper, using innovative combinations of satellite sensor data, we investigate some of these fundamental processes which are closely tied to clouds and control the monsoon system's evolution. The study, which focuses on the monsoon period of June, 1979, examines the low-frequency variability of clouds and their effects on air-sea processes through an analysis of the complex influence clouds play on the surface heat and water budgets. First, the effects of clouds on both the solar and longwave components of the surface radiation budget are assessed using a cloud radiative forcing parameter. While the effects of clouds on the long-wave irradiance act in a manner opposite to their effects on the shortwave irradiance, only a partial compensation is found to take place and the net effect results in a maximum cloud forcing of 60 Wm^–2 in the southwestern Arabian Sea. Second, employing satellite-derived precipitation and evaporation estimates, the paper analyzes the net surface fresh water budget variability around the monsoon onset. This budget is important in that fresh water affects the upper ocean density distribution and, consequently, the thermohaline circulation. Two regions are found to dominate the analysis: the western Arabian Sea, where evaporation is dominant by more than 10 mm day^–1, and the eastern Arabian Sea, where precipitation is dominant by more than 10 mm day^–1. Thus, a strong zonal gradient of fresh water at the surface is established during the monsoon. The last topic investigated is the intraseasonal variability of convection as analyzed using a cloud parameter indicative of deep convection. Cloud oscillations of 30–50 days, associated with the different phases of the monsoon, are found to propagate northward in the eastern Indian Ocean and eastward in the Bay of Bengal. Our analysis not only supports the hypothesis that the 30–50-day oscillation is driven by deep convection but also, and more importantly, suggests that the ocean thermal forcing is modulated by 30–50-day oscillations through cloud-induced surface radiative forcing. Although the results presented are limited in scope and preliminary because of the diffculty in quantifying the accuracy of the parameters examined, they do demonstrate: 1) the role of clouds in modulating the surface heat and water budgets, 2) the advantage of using combinations of multi-sensor and multi-platform satellite observations to quantify interrelated surface heat/water budget processes, and 3) the potential to examine the intraseasonal variability of air-sea interaction processes associated with the monsoon, even though these processes are not directly measurable from space.With 6 FiguresB. DiJulio passed away in September 1990.