Specific effects of background electrolytes on the kinetics of step propagation during calcite growth

The mechanisms by which background electrolytes modify the kinetics of non-equivalent step propagation during calcite growth were investigated using Atomic Force Microscopy (AFM), at constant driving force and solution stoichiometry. Our results suggest that the acute step spreading rate is controlled by kink-site nucleation and, ultimately, by the dehydration of surface sites, while the velocity of obtuse step advancement is mainly determined by hydration of calcium ions in solution. According to our results, kink nucleation at acute steps could be promoted by carbonate-assisted calcium attachment. The different sensitivity of obtuse and acute step propagation kinetics to cation and surface hydration could be the origin of the reversed geometries of calcite growth hillocks (i.e., rate of obtuse step spreading < rate of acute step spreading) observed in concentrated (ionic strength, IS = 0.1) KCl and CsCl solutions. At low IS (0.02), ion-specific effects seem to be mainly associated with changes in the solvation environment of calcium ions in solution. With increasing electrolyte concentration, the stabilization of surface water by weakly paired salts appears to become increasingly important in determining step spreading rate. At high ionic strength (IS = 0.1), overall calcite growth rates increased with increasing hydration of calcium in solution (i.e., decreasing ion pairing of background electrolytes for sodium-bearing salts) and with decreasing hydration of the carbonate surface site (i.e., increasing ion pairing for chloride-bearing salts). Changes in growth hillock morphology were observed in the presence of Li⁺, F⁻ and , and can be interpreted as the result of the stabilization of polar surfaces due to increased ion hydration. These results increase our ability to predict crystal reactivity in natural fluids which contain significant amounts of solutes.     

River channel adjustments downstream from channelization works in England and Wales

Relatively little attention has been given to river channel adjustments that occur downstream from channelization works. This study is concerned with the nature of channel adjustments downstream from a total of 46 channelization works located in low and high energy environments in England and Wales. Channel changes are identified principally by the method of field survey and by reconstructing the original positions of eroded beds and banks. Use is also made of maps, aerial photographs, and engineering drawings of different dates and the technique of space-for-time substitution is applied. Enlargement of channel cross-sections through erosion had occurred downstream from a variety of types, sizes, and dates of channelization works. The maximum increase of channel size was 153 per cent. Out of a total of 14 sites with enlarged channel cross-sections, seven had undergone a change of width only, at a further three width increased rather than depth, and at the remaining four sites depth increases were dominant. These sites all have relatively high stream powers. Factors causing spatial variation of erosion included tree roots locally binding bank sediments and the occurrence of bends. Planform change had taken place at only one site. A further three high stream power sites had downstream reaches incised into bedrock and therefore did not exhibit adjustment. Channel enlargement is explained in terms of increased flood flows downstream from channelization works causing higher stream velocities, which in turn cause erosion, thereby increasing channel width and/or depth. Examination of flow records for 35 stations revealed flood events which would formerly have spread overbank but are now confined by the channelization works and are therefore likely to alter downstream flows. At sites with downstream change it is proposed that the energy of increased flows was sufficient to exceed a threshold required for erosion of perimeter sediments. By contrast the absence of change at a majority of sites in low energy lowland areas could be a reflection of both the incompetence of increased flows to erode and resistance provided by perimeter sediments. Sites with erosion features appear not to have yet attained new equilibrium conditions.     

Wind-forced continental shelf waves from a geographical origin

The response of a barotropic coastal ocean on a step-shaped continental shelf to a traveling sinusoidal wind stress forcing is predicted theoretically using a frictional force proportional to the alongshore current velocity. This theory is compared to a small set of observations from the northeast coast of Australia where a sudden widening of the continental shelf provides a geographical origin. The comparison is accomplished by means of frequency response functions relating alongshore wind stress with alongshore velocity. Amplitudes of the response functions are predicted to increase with alongshore distance equatorward and also to decrease with frequency at any location. These predictions are verified by the measurements. Predicted phase lags are generally less than about 30°, with observations agreeing with theory to within about 20°C. In general, the measurements provide reasonable evidence to support the theory of wind-forced continental shelf waves from a geographical origin.     

Statistical model of silicate analysis and results of investigation of G-1 and W-1 samples

An analysis of the results of investigation of the G- 1 and W- 1 samples are given and differ from F. Chayes’ point of view. Results of the samples can be evaluated by comparison of frequency-distribution properties of determinations for chemical elements from different laboratories with some standard distribution, which gives the idea of a statistical model. The comparative results indicate that oxides from minerals of the same density have positive correlations and that oxides from minerals of different density have negative correlations. The different results therefore are not from the precision of analysis, but rather from differentiation of sample powder particles by density and shape in the course of preparation.     

The ortho- to para- ratio of H2 in the starburst of NGC 253

We present measurements of several near-infrared emission lines from the nearby galaxy NGC 253. We have been able to measure four H₂ lines across the circumnuclear starburst, from which we estimate the ortho- to para- ratio of excited H₂ to be ∼2. This indicates that the bulk of the H₂ emission arises from photodissociation regions (PDRs), rather than from shocks. This is the case across the entire region of active star formation.
As the H₂ emission arises from PDRs, it is likely that the ratio of H₂ to Brγ (the bright hydrogen recombination line) is a measure of the relative geometry of O and B stars and PDRs. Towards the nucleus of NGC 253 the geometry is deduced to be tightly clustered O and B stars in a few giant H  II regions that are encompassed by PDRs. Away from the nuclear region, the geometry becomes that of PDRs bathed in a relatively diffuse ultraviolet radiation field.
The rotation curves of 1–0 S(1) and Brγ suggest that the ionized gas is tracing a kinetic system different from that of the molecular gas in NGC 253, particularly away from the nucleus.     

Aliphatic and aromatic hydrocarbons in benthic invertebrates from two sites in Antarctica

Samples of marine benthic invertebrates collected from two sites in the Antarctic have been analysed for both aliphatic and aromatic hydrocarbons in order to establish baseline concentrations for some classes of hydrocarbons.Samples from Signy Island, a pristine site, contained low concentrations of the hydrocarbons determined, whereas those from King Edward Cove, South Georgia, contained significantly higher concentrations. King Edward Cove has a known history of pollution from whaling operations.Platt & Mackie (1979) have suggested that the hydrocarbons in sediments from King Edward Cove are a result of the world-wide dissemination of the pyrolysis products of fossil fuels. Our work suggests, in contrast, that the hydrocarbons in the benthos are derived from local sources.     

A test of Sporormiella representation as a predictor of megaherbivore presence and abundance

Spores of the dung fungus Sporormiella have been suggested to indicate the presence, perhaps also the abundance of past megaherbivore populations. Nonetheless, basic studies demonstrating a correlation between Sporormiella concentration in lacustrine sediments and modern herbivore abundance are lacking. This study of Sporormiella representation in grazed and ungrazed landscapes provides supporting evidence for the application of Sporormiella as an indicator of megaherbivore presence and abundance in ancient landscapes. However, Sporormiella representation is spatially sensitive to the distance from the dung source. In lakes where Sporomiella are abundant in shoreline sediments, they decline sharply with increasing distance from the lake edge. Although this study provides supporting evidence for the application of Sporormiella as a proxy for herbivore presence and abundance, independent proxies should be applied in conjunction with Sporormiella to control for changes in lake size.     

The Most Recent Cascadia Earthquake and Native American Narratives

The Cascadia subduction zone fault lies just off the Pacific coast of the USA and Canada. Although this fault has been seismically inactive over the written history of the Cascadia region, it has the potential to produce catastrophic earthquakes and tsunamis. A variety of dating methods have been used to show that the most recent Cascadia earthquake occurred in 1700. Among these methods is an informal analysis of oral traditions handed down by Native American peoples that appear to refer to a major earthquake in this region. A central difficulty in analyzing these narratives quantitatively is their use of a generation and other qualitative measures of time that have no fixed lengths. Here, these narratives are analyzed under an explicit statistical model of the lengths of these measures. The results raise a question about the previous conclusion that these narratives all refer to the most recent Cascadia earthquake.

     

Microbial photosynthesis in coral reef sediments (Heron Reef, Australia)

We investigated microphytobenthic photosynthesis at four stations in the coral reef sediments at Heron Reef, Australia. The microphytobenthos was dominated by diatoms, dinoflagellates and cyanobacteria, as indicated by biomarker pigment analysis. Conspicuous algae firmly attached to the sand grains (ca. 100 μm in diameter, surrounded by a hard transparent wall) were rich in peridinin, a marker pigment for dinoflagellates, but also showed a high diversity based on cyanobacterial 16S rDNA gene sequence analysis. Specimens of these algae that were buried below the photic zone exhibited an unexpected stimulation of respiration by light, resulting in an increase of local oxygen concentrations upon darkening. Net photosynthesis of the sediments varied between 1.9 and 8.5 mmol O₂ m⁻² h⁻¹ and was strongly correlated with Chl a content, which lay between 31 and 84 mg m⁻². An estimate based on our spatially limited dataset indicates that the microphytobenthic production for the entire reef is in the order of magnitude of the production estimated for corals. Photosynthesis stimulated calcification at all investigated sites (0.2–1.0 mmol Ca²⁺ m⁻² h⁻¹). The sediments of at least three stations were net calcifying. Sedimentary N₂-fixation rates (measured by acetylene reduction assays at two sites) ranged between 0.9 to 3.9 mmol N₂ m⁻² h⁻¹ and were highest in the light, indicating the importance of heterocystous cyanobacteria. In coral fingers no N₂-fixation was measurable, which stresses the importance of the sediment compartment for reef nitrogen cycling.