An evaluation of metal bioaccessibility in estuarine sediments using the commercially available protein, bovine serum albumin

The bioaccessibility of metals (Al, Ca, Fe, Mn, Ag, Cd, Co, Cu, Ni, Pb, Sn, Zn) in oxic estuarine sediments has been evaluated using solutions of a commercially available protein (bovine serum albumin; BSA) that mimic the chemical conditions encountered in the gut environment of many deposit-feeding organisms. Over a 20 h incubation period with 5 g L^− 1 BSA, metal mobilisation was generally biphasic in that a relatively short period of rapid release was succeeded by more gradual release or approach to equilibrium, although in some cases metal readsorption was evident during the time-courses. Availability to BSA, defined as metal released after 20 h relative to metal extracted by boiling aqua regia, was greatest for Cd, Ni, Ca and Zn and lowest for Fe and Mn, and correlated well with, but was an order of magnitude lower than, metal digested by acidified hydrogen peroxide. Time-courses conducted in the absence of the protein revealed that significant quantities of Ca and Mn were water-soluble, reflecting the partial dissolution of carbonates and hydrous Mn oxides, respectively. Additional experiments indicated a net increase in metal release with increasing BSA concentration and, with the exception of Ca and Mn, a substantial increase in metal mobilisation after sediment organic matter had been digested by peroxidation. These observations suggest that, apart from Ca and Mn, metal release proceeds via complexation with component amino acids of the protein, denudation of organic host phases, and exposure of inorganic, metal-bearing minerals. Accordingly, the bioaccessibility of a metal is predicted to be dependent on its (i) affinity for proteinaceous ligands, (ii) association with components of digestible sediment organic matter, and (iii) degree of binding at relatively weak sites on sediment phases that are exposed or modified by the action of proteins and other chemical constituents of the gut environment.     

Quantifying the storm erosion hazard for coastal planning

The quantity of coastline retreat resulting from storm erosion is one of the most important phenomena that needs to be accurately quantified to facilitate effective coastal management strategies. Historically, the volume of storm erosion (and coastline retreat) accommodated for coastal planning decisions has been directly linked to the storm (usually defined by considering wave height and duration only) with a certain pre-defined return period, known as a Synthetic Design Storm (SDS) (e.g. 1 in 100 year storm). The SDS method of estimating storm erosion volumes for coastal planning thus assumes that, for example, the 1 in 100 year storm event also results in a 1 in 100 year erosion event. This communication discusses the physical reality of this assumption and demonstrates the improved performance of a new method, based on Joint Probability Distributions (JPD) for estimating storm erosion volumes proposed by Callaghan et al. [Callaghan, D.P., Nielsen, P., Short, A.D. and Ranasinghe, R., 2008. Statistical simulation of wave climate and extreme beach erosion. Coastal Engineering, 55(5): 375–390] using one of the world's longest beach profile surveys from Sydney, Australia.     

GNSS satellite-based augmentation systems for Australia

We provided an overview of various satellite-based augmentation systems (SBAS) options for augmented GNSS services in Australia, and potentially New Zealand, with the aim to tease out key similarities and differences in their augmentation capabilities. SBAS can technically be classified into two user categories, namely SBAS for aviation and “non-aviation” SBAS. Aviation SBAS is an International Civil Aviation Organization (ICAO) certified civil aviation safety-critical system providing wide-area GNSS augmentation by broadcasting augmentation information using geostationary satellites. The primary aim was to improve integrity, availability and accuracy of basic GNSS signals for aircraft navigation. On the other hand, “non-aviation” SBAS support numerous GNSS applications using positioning techniques such as wide-area differential-GNSS (DGNSS) and precise point positioning (PPP). These services mainly focus on delivering high-accuracy positioning solutions and guaranteed levels of availability, and integrity remains secondary considerations. Next-generation GNSS satellites capable of transmitting augmentation signals in the L1, L5 and L6 frequency bands will also be explored. These augmentation signals have the data capacity to deliver a range of augmentation services such as SBAS, wide-area DGNSS and PPP, to meet the demands of various industry sectors. In addition, there are well-developed plans to put in place next-generation dual-frequency multi-constellation SBAS for aviation. Multi-constellation GNSS increases robustness against potential degradation of core satellite constellations and extends the service coverage area. It is expected that next-generation SBAS and GNSS will improve accuracy, integrity, availability and continuity of GNSS performance.     

Development and application of a catchment scale diffuse nitrate modelling tool

Water pollution from diffuse sources is a problem of increasing concern. Efforts to control diffuse pollution have been confined mainly to agricultural land and forests. Little attention has been paid to sources of diffuse pollution from urban areas. A diffuse nitrate modelling tool (DNMT) has been developed for modelling the fate of nitrate in urban areas. This tool works at the catchment scale and has a modular structure that consists of three components: the hydrological module, the nitrogen cycle module and the nitrate transport module. The hydrological model describes the possible flow pathways. The nitrogen cycle model accounts for the mass balance of nitrate and calculates the amount of nitrate for potential loss. The nitrate transport module simulates the movement of nitrate within and from the soil to the receiving water. This paper demonstrates the development of the tool and its application in the White Cart Water catchment. This implementation of the tool shows that it has a good capability for simulating the fate of nitrate in urban catchments. Copyright © 2005 John Wiley & Sons, Ltd.     

The Jet Driven Motions in the Narrow Line Region of NGC 1068

We have obtained HST FOC f/48 long-slit spectroscopy of the central 2 arcseconds of the Narrow Line Region of NGC 1068 between 3500-5400\OA with a spectral resolution of 1.78\OA/pixel. At a spatial scale of 0″.0287 per pixel these data provide an order of magnitude improvement in resolution over previous ground based spectra and allow us to trace the interaction between the radio jet and the gas in the NLR. Our results show that, within ±0″.5 of the radio-jet the emission lines are split into two components whose velocity separation is 1500 km s-1. The emission line structure is reminiscent of that seen previously around the jet of 3C120. Furthermore, this material enveloping the radio-jet is in a much higher ionization state than that of the surrounding NLR gas. The highest excitation is coincident with the jet axis where emission in the coronal line of [FeVII] λ3769\OA is detected but where [OII] λ3727 \OA is depressed. These results imply that we are witnessing a cocoon of hot gas in expansion around the radio-jet created by its interaction with the gas, and that these shocks are sufficiently fast, at least ± km s-1, that they are creating localized ionization effects. This revised version was published online in July 2006 with corrections to the Cover Date.     

Detrital zircon geochronology of Carboniferous–Cretaceous strata in the Lhasa terrane, Southern Tibet

Sedimentary strata in the Lhasa terrane of southern Tibet record a long but poorly constrained history of basin formation and inversion. To investigate these events, we sampled Palaeozoic and Mesozoic sedimentary rocks in the Lhasa terrane for detrital zircon uranium–lead (U–Pb) analysis. The >700 detrital zircon U–Pb ages reported in this paper provide the first significant detrital zircon data set from the Lhasa terrane and shed new light on the tectonic and depositional history of the region. Collectively, the dominant detrital zircon age populations within these rocks are 100–150, 500–600 and 1000–1400 Ma. Sedimentary strata near Nam Co in central Lhasa are mapped as Lower Cretaceous but detrital zircons with ages younger than 400 Ma are conspicuously absent. The detrital zircon age distribution and other sedimentological evidence suggest that these strata are likely Carboniferous in age, which requires the existence of a previously unrecognized fault or unconformity. Lower Jurassic strata exposed within the Bangong suture between the Lhasa and Qiangtang terranes contain populations of detrital zircons with ages between 200 and 500 Ma and 1700 and 2000 Ma. These populations differ from the detrital zircon ages of samples collected in the Lhasa terrane and suggest a unique source area. The Upper Cretaceous Takena Formation contains zircon populations with ages between 100 and 160 Ma, 500 and 600 Ma and 1000 and 1400 Ma. Detrital zircon ages from these strata suggest that several distinct fluvial systems occupied the southern portion of the Lhasa terrane during the Late Cretaceous and that deposition in the basin ceased before 70 Ma. Carboniferous strata exposed within the Lhasa terrane likely served as source rocks for sediments deposited during Cretaceous time. Similarities between the lithologies and detrital zircon age‐probability plots of Carboniferous rocks in the Lhasa and Qiangtang terranes and Tethyan strata in the Himalaya suggest that these areas were located proximal to one another within Gondwanaland. U–Pb ages of detrital zircons from our samples and differences between the geographic distribution of igneous rocks within the Tibetan plateau suggest that it is possible to discriminate a southern vs. northern provenance signature using detrital zircon age populations.