Headwaters drive streamflow and lowland tracer export in a large-scale humid tropical catchment

Headwaters are generally assumed to contribute the majority of water to downstream users, but how much water, of what quality and where it is generated are rarely known in the humid tropics. Here, using monthly monitoring in the data scarce (2,370 km²) San Carlos catchment in northeastern Costa Rica, we determined runoff-area relationships linked to geochemical and isotope tracers. We established 46 monitoring sites covering the full range of climatic, land use and geological gradients in the catchment. Regression and cluster analysis revealed unique spatial patterns and hydrologically functional landscape units. These units were used for seasonal and annual Bayesian tracer mixing models to assess spatial water source contributions to the outlet. Generally, the Bayesian mixing analysis showed that the chemical and isotopic imprint at the outlet is throughout the year dominated by the adjacent lowland catchments (68%) with much less tracer influence from the headwaters. However, the headwater catchments contributed the bulk of water and tracers to the outlet during the dry season (>50%) despite covering less than half of the total catchment area. Additionally, flow volumes seemed to be linearly scaled by area maintaining a link between the headwaters and the outlet particularly during high flows of the rainy season. Stable isotopes indicated mean recharge elevations above the mean catchment altitude, which further supports that headwaters were the primary source of downstream water. Our spatially detailed “snap-shot” sampling enabled a viable alternative source of large-scale hydrological process knowledge in the humid tropics with limited data availability.     

SO2 from episode 48A eruption,Hawaii: Sulfur dioxide emissions from the episode 48A East Rift Zone eruption of Kilauea volcano,Hawaii

An SO₂ flux of 1170±400 (1) tonnes per day was measured with a correlation spectrometer (COSPEC) in October and November 1986 from the continuous, nonfountaining, basaltic East Rift Zone eruption (episode 48A) of Kilauea volcano. This flux is 5–27 times less than those of highfountaining episodes, 3–5 times greater than those of contemporaneous summit emissions or interphase Pu'u O'o emissions, and 1.3–2 times the emissions from Pu'u O'o alone during 48A. Calculations based on the SO₂ emission rate resulted in a magma supply rate of 0.44 million m³ per day and a 0.042 wt% sulfur loss from the magma upon eruption. Both of these calculated parameters agree with determinations made previously by other methods.     

Angélica Copper Deposit: Exotic Type Mineralization in the Tocopilla Plutonic Complex of the Coastal Cordillera, Northern Chile

The Angélica copper deposit is situated at the southernmost sector of the Jurassic Tocopilla plutonic complex in the North Chilean Coastal Cordillera. This deposit occurs in monzonitic to monzodioritic rocks, and has platelike orebodies with no appreciable hydrothermal alteration nor sulfide mineralization. The mineralized zones are located in the western side of the two main normal faults with NE and NW orientations, and are characterized principally by impregnation of supergene copper products of atacamite and minor amounts of chrysocolla, lavendulan and “black copper”. Generally, chrysocolla is more abundant at a distal NE sector of the deposit. The black copper is Cu‐Fe‐Mn‐Si‐Cl‐rich multimineral aggregates composed of atacamite with minor amounts of quartz, pseudomalachite, dioptase, neotocite, gypsum, paratacamite and melanothallite, and its surface exhibits nanometer‐sized cylindrical morphologies. All these characteristics suggest an exotic origin for the Angélica copper deposit. A few vein‐type copper deposits situated at the southwestern sector along the NE‐oriented fault are inferred as the possible source of the Angélica copper deposit.     

Signatures of climate vs. sea-level change within incised valley-fill successions: Quaternary examples from the Texas GULF Coast

The passive margin Texas Gulf of Mexico Coastal Plain consists of coalescing late Pleistocene to Holocene alluvial–deltaic plains constructed by a series of medium to large fluvial systems. Alluvial–deltaic plains consist of the Pleistocene Beaumont Formation, and post-Beaumont coastal plain incised valleys. A variety of mapping, outcrop, core, and geochronological data from the extrabasinal Colorado River and the basin-fringe Trinity River show that Beaumont and post-Beaumont strata consist of a series of coastal plain incised valley fills that represent 100 kyr climatic and glacio-eustatic cycles.

Valley fills contain a complex alluvial architecture. Falling stage to lowstand systems tracts consist of multiple laterally amalgamated sandy channelbelts that reflect deposition within a valley that was incised below highstand alluvial plains, and extended across a subaerially-exposed shelf. The lower boundary to falling stage and lowstand units comprises a composite valley fill unconformity that is time-transgressive in both cross- and down-valley directions. Coastal plain incised valleys began to fill with transgression and highstand, and landward translation of the shoreline: paleosols that define the top of falling stage and lowstand channelbelts were progressively onlapped and buried by heterolithic sandy channelbelt, sandy and silty crevasse channel and splay, and muddy floodbasin strata. Transgressive to highstand facies-scale architecture reflects changes through time in dominant styles of avulsion, and follows a predictable succession through different stages of valley filling. Complete valley filling promoted avulsion and the large-scale relocation of valley axes before the next sea-level fall, such that successive 100 kyr valley fills show a distributary pattern.

Basic elements within coastal plain valleys can be correlated with the record offshore, where cross-shelf valleys have been described from seismic data. Falling stage to lowstand channelbelts within coastal plain valleys were feeder systems for shelf-phase and shelf-margin deltas, respectively, and demonstrate that falling stage fluvial deposits are important valley fill components. Signatures of both upstream climate change vs. downstream sea-level controls are therefore interpreted to be present within incised valley fills. Signatures of climate change consist of the downstream continuity of major stratigraphic units and component facies, which extends from the mixed bedrock–alluvial valley of the eroding continental interior to the distal reaches, wherever that may be at the time. This continuity suggests the development of stratigraphic units and facies is strongly coupled to upstream controls on sediment supply and climate conditions within hinterland source regions. Signatures of sea-level change are critical as well: sea-level fall below the elevation of highstand depositional shoreline breaks results in channel incision and extension across the newly emergent shelf, which in turn results in partitioning of the 100 kyr coastal plain valleys. Moreover, deposits and key surfaces can be traced from continental interiors to the coastal plain, but there are downstream changes in geometric relations that correspond to the transition between the mixed bedrock–alluvial valley and the coastal plain incised valley. Channel incision and extension during sea-level fall and lowstand, with channel shortening and delta backstepping during transgression, controls the architecture of coastal plain and cross-shelf incised valley fills.     

From berries to blocks: carbon stock quantification of a California vineyard

Background

Quantifying terrestrial carbon (C) stocks in vineyards represents an important opportunity for estimating C sequestration in perennial cropping systems. Considering 7.2 M ha are dedicated to winegrape production globally, the potential for annual C capture and storage in this crop is of interest to mitigate greenhouse gas emissions. In this study, we used destructive sampling to measure C stocks in the woody biomass of 15-year-old Cabernet Sauvignon vines from a vineyard in California’s northern San Joaquin Valley. We characterize C stocks in terms of allometric variation between biomass fractions of roots, aboveground wood, canes, leaves and fruits, and then test correlations between easy-to-measure variables such as trunk diameter, pruning weights and harvest weight to vine biomass fractions. Carbon stocks at the vineyard block scale were validated from biomass mounds generated during vineyard removal.

Results

Total vine C was estimated at 12.3 Mg C ha^?1, of which 8.9 Mg C ha^?1 came from perennial vine biomass. Annual biomass was estimated at 1.7 Mg C ha^?1 from leaves and canes and 1.7 Mg C ha^?1 from fruit. Strong, positive correlations were found between the diameter of the trunk and overall woody C stocks (R² = 0.85), pruning weights and leaf and fruit C stocks (R² = 0.93), and between fruit weight and annual C stocks (R² = 0.96).

Conclusions

Vineyard C partitioning obtained in this study provides detailed C storage estimations in order to understand the spatial and temporal distribution of winegrape C. Allometric equations based on simple and practical biomass and biometric measurements could enable winegrape growers to more easily estimate existing and future C stocks by scaling up from berries and vines to vineyard blocks.

     

Observations of the optical afterglow from GRB 060526 with the RTT-150 telescope

Multicolor photometric observations of the optical afterglow from GRB 060526 with the Russian-Turkish 1.5-m RTT-150 telescope (Mount Bakyrlytepe, Turkey) are presented. The afterglow light curve was measured in detail starting from about 5 h after the GRB and over five ensuing nights. In addition, upper limits were obtained on the rapid variability of the afterglow on the first night of observations and the history of afterglow color variations was measured in detail. In the time interval from 6 to 16 h after the burst, the flux gradually decreased approximately as a power law with a slope of ?1.14 ± 0.02. Subsequently, variability was observed on a time scale δt < t and the afterglow began to decay much faster. The afterglow color was approximately constant (V?R ≈ 0.5) throughout the observations, despite the flux variability. Variability time scales up to δt/t ≈ 0.0055 were observed at ΔF _ν/F _ν ≈ 0.3, which violates many constraints on the variability of the observed emission from an ultrarelativistic jet obtained by Ioka et al. (2005). We suggest explaining this variability by the fact that the shell motion is no longer ultrarelativistic at this time.     

Liberation study of apatite-nepheline ore comminuted by penetrating electrical discharges

A comparative study of the comminution products of an apatite-nepheline ore was carried out in a specially designed pulse-discharge apparatus, with electrical parameters and a dielectric medium as variables. Mineralogical analysis of the products confirmed the high selectivity of the process in liberation of monofractions, especially those of nepheline.     

Sulphur dioxide,particle and elemental emissions from Mount Etna,Italy during July 1987

Sulphur dioxide emission rates were measured at Mount Etna, Italy during July 1987 while the volcano was undergoing relatively quiet activity. The SO₂ flux averaged 930 ± 587 (1) Mg/d, excluding 19 July when the flux was 3200 ± 1730 (1) Mg/d. Rising magma and/or an influx of less degassed magma could explain the increased SO₂ flux. The high SO₂ flux did not correlate with changes in observed volcanic activity. This suggests that SO₂ monitoring may be useful as an indicator of shallow magmatic activity, but not as a predictor of future eruptions of Mount Etna.Particles emitted from the two active craters, Bocca Nuova and Southeast Crater (SE), were composed of silicates, sulphates and dithionites. Chloride species were only observed in particles from SE. Different eruptive styles probably produced the differences in particle compositions emitted from each crater.Vapour — magma enrichment factors were calculated for many elements from both craters. Cl, Br and S were the most enriched elements in the sampled fumes. Similar enrichment factors at both craters suggest a common magma supply.Cl, S and F have the largest elemental fluxes emitted from Mount Etna. During quiet activity, the Cl flux represents 27% of the global anthropogenic emissions, but its effect is limited to the local region due to atmospheric removal processes. Mount Etna also exhaled significant amounts of Zn, Br, Mo, F and Cu compared with regional anthropogenic emissions.     

The effects of volcanic ash on COSPEC measurements

Data from a series of laboratory experiments show the relationships between measured correlation spectrometer (COSPEC) sulfur-dioxide (SO₂) burdens, automatic gain control (AGC) deflections, and visible wavelength opacities in ash-laden plumes. The data show that the COSPEC reliably measures (within a 10% accuracy) SO₂ burdens up to AGC deflections of 2 V and visible wavelength opacities of 50%. Beyond these limits, the under measurement of the SO₂ burden is not well constrained. During typical COSPEC runs, these limits are rarely violated. The 10% error introduced by measuring ash-laden plumes is acceptable because the error is small relative to other error sources associated with the technique, especially plume velocity; and the error is correctable which allows for a wider range of plume conditions to be measured.These results imply that the densest SO₂ concentrations near the volcanic source can be measured. This is important so that SO₂ is not lost from the volcanic plume due to physical and chemical processes and that measurements are conducted under maximum signal to noise ratios.