Temporal Changes in Seawater Carbonate Chemistry and Carbon Export from a Southern California Estuary

Estuaries are important subcomponents of the coastal ocean, but knowledge about the temporal and spatial variability of their carbonate chemistry, as well as their contribution to coastal and global carbon fluxes, are limited. In the present study, we measured the temporal and spatial variability of biogeochemical parameters in a saltmarsh estuary in Southern California, the San Dieguito Lagoon (SDL). We also estimated the flux of dissolved inorganic carbon (DIC) and total organic carbon (TOC) to the adjacent coastal ocean over diel and seasonal timescales. The combined net flux of DIC and TOC (F_DIC?+?TOC) to the ocean during outgoing tides ranged from ??1.8±0.5?×?10³ to 9.5±0.7?×?10³?mol C h^?1 during baseline conditions. Based on these fluxes, a rough estimate of the net annual export of DIC and TOC totaled 10±4?×?10⁶?mol C year^?1. Following a major rain event (36 mm rain in 3 days), F_DIC?+?TOC increased and reached values as high as 29.0 ±?0.7?×?10³?mol C h^?1. Assuming a hypothetical scenario of three similar storm events in a year, our annual net flux estimate more than doubled to 25 ±?4?×?10⁶?mol C year^?1. These findings highlight the importance of assessing coastal carbon fluxes on different timescales and incorporating event scale variations in these assessments. Furthermore, for most of the observations elevated levels of total alkalinity (TA) and pH were observed at the estuary mouth relative to the coastal ocean. This suggests that SDL partly buffers against acidification of adjacent coastal surface waters, although the spatial extent of this buffering is likely small.     

<Superscript>10</Superscript>Be surface exposure dating of the last deglaciation in the Aare Valley,Switzerland

The combined Rhone and Aare Glaciers presumably reached their last glacial maximum (LGM) extent on the Swiss Plateau prior to 24 ka. Two well-preserved, less extensive moraine stades, the Gurten and Bern Stade, document the last deglaciation of the Aare Valley, yet age constraints are very scarce. In order to establish a more robust chronology for the glacial/deglacial history of the Aare Valley, we applied ¹⁰Be surface exposure dating on eleven boulders from the Gurten and Bern Stade. Several exposure ages are of Holocene age and likely document post-depositional processes, including boulder toppling and quarrying. The remaining exposure ages, however yield oldest ages of 20.7 ± 2.2 ka for the Gurten Stade and 19.0 ± 2.0 ka for the Bern Stade. Our results are in good agreement with published chronologies from other sites in the Alps.     

Adaptation of the Canadian Fire Weather Index to Mediterranean forests

Natural Hazards - The Canadian Fire Weather Index (FWI) is one of the most used tools to forecast forest fire hazard. In this paper, we propose an adaptation of the FWI to take into account the...     

Brixenbach research catchment: Quantification of runoff process proportions in a small Alpine catchment depending on soil moisture states and precipitation characteristics

The Brixenbach valley is a small Alpine torrent catchment (9.2 km², 820–1950 m a.s.l., 47.45°, 12.26°) in Tyrol, Austria. Intensive hydrological research in the catchment since more than 12 years, including a hydrogeological survey, pedological and land use mapping, measurements of precipitation, runoff, soil moisture and infiltration as well as the conduction of rainfall simulations, has contributed to understand the hydrological response of the catchment, its subcatchments and specific sites. The paper presents a synthesis of the research in form of runoff process maps for different soil moisture states and precipitation characteristics, derived with the aid of a newly developed Soil-hydrological model. These maps clearly visualize the differing runoff reaction of different subcatchments. The pasture dominated areas produce high surface flow rates during short precipitation events (1 h, 86 mm) with high rainfall intensity, whilst the forested areas often develop shallow subsurface flow. Dry preconditions lead to a slight reduction of surface flow, long rainfall events (24 h, 170 mm) to a dominance of deep subsurface flow and percolation.     

Microbiological processes in banded iron formation deposition

Banded iron formations have been studied for decades, particularly regarding their potential as archives of the Precambrian environment. In spite of this effort, the mechanism of their deposition and, specifically, the role that microbes played in the precipitation of banded iron formation minerals, remains unresolved. Evidence of an anoxic Earth with only localized oxic areas until the Great Oxidation Event ca 2·45 to 2·32 Ga makes the investigation of O₂‐independent mechanisms for banded iron formation deposition relevant. Recent studies have explored the long‐standing proposition that Archean banded iron formations may have been formed, and diagenetically modified, by anaerobic microbial metabolisms. These efforts encompass a wide array of approaches including isotope, ecophysiological and phylogeny studies, molecular and mineral marker analysis, and sedimentological reconstructions. Herein, the current theories of microbial processes in banded iron formation mineral deposition with particular regard to the mechanisms of chemical sedimentation and post‐depositional alteration are described. The main findings of recent years are summarized and compared here, and suggestions are made regarding cross‐disciplinary information still required to constrain the role of the biosphere in banded iron formation deposition.     

Predicted effects from abatement action against eutrophication in two small bays of the Baltic Sea

The Baltic Sea has abnormal algal blooms during spring and summer which are effects of high concentrations of total phosphorus (TP) and other nutrients in the surface water. Björnöfjärden (BF), a coastal area connected to the Baltic Sea, is selected for investigating whether aluminium treatment of sediments may reduce TP concentrations in the water mass. The aim of this paper is to evaluate effects from different abatement actions in two bays, BF and Nyköpingsfjärden (NF). The four investigated scenarios are (1) no action, (2) reducing TP from local sources, (3) fixing TP in sediments with aluminium, and (4) decreasing TP concentrations in the outside sea. Magnitudes of different TP fluxes during the different scenarios were estimated using a dynamic mass balance model, CoastMab, which has previously been tested against data from Swedish coastal waters. Alternative actions such as aluminium treatment and reduction of TP from local sources would result in no or scant effect on the TP concentrations in the two bays according to model simulations. The only action which would result in a significant expected decrease in TP concentrations would be to decrease TP concentrations in the outside sea. It is concluded that BF and NF are not suitable for studying effects from local abatement action because of large TP fluxes from the outside sea.     

The depositional architecture and facies variability of shelf deltas in the Eocene Battfjellet Formation,Nathorst Land,Spitsbergen

Deltas are commonly classified according to their plan‐view morphology as either river‐dominated, tide‐dominated or wave‐dominated. However, most deltas form under the mixed influence of these processes, commonly with laterally varying process regimes. It has also become clear that there is a mismatch between the plan‐view morphology and internal facies composition in some deltas. Combined outcrop and subsurface data from the Eocene Battfjellet Formation, Spitsbergen, provide an example of ancient shelf deltas that formed under mixed influence. Internally, these shelf deltas are characterized by wave‐dominated facies that are normally associated with strike‐extensive, nearly linear shoreline sandstones. However, the formation comprises partially overlapping sandstone bodies of limited lateral extent (<20 km in any direction). This stacking pattern is attributed to frequent autogenic lobe switching that caused localized and rapid transgressions. Such processes typify fluvial‐dominated deltas and occur less commonly in wave‐dominated ones. Thus, there is an apparent mismatch between inferred plan‐view morphology and internal facies composition. It is argued that the Battfjellet deltas were flood‐dominated and prograded mainly during periods of high fluvial discharge. However, reworking of the fluvial‐flood facies by fair‐weather and storm waves, as well as longshore currents, resulted in a wave‐dominated facies character. Delta lobes undergoing auto‐retreat were particularly prone to reworking by basinal processes, including tidal currents. It is suggested that repeated delta progradation from inner shelf settings towards the outer shelf and shelf edge was aided by high sediment supply rather than relative falls in sea‐level as previously suggested. This interpretation is supported by: (i) the lack of major facies dislocations and extensive sub‐aerial unconformities; and (ii) an overall relative rise in sea‐level as evidenced by an overall low‐angle (0·8 to 1·2°) ascending shoreline trajectory. The latter results from the combined effect of basin subsidence, eustatic highstand and sediment compaction.     

Deep‐burial alteration of early‐diagenetic carbonate concretions formed in Palaeozoic deep‐marine greywackes and mudstones (Bardo Unit,Sudetes Mountains,Poland)

Carbonate concretions formed in bathyal and deeper settings have been studied less frequently than those formed in shallow‐marine deposits. Similarly, concretions affected by catagenetic conditions have rarely been reported. Calcite concretions in deep‐marine mudstones and greywackes of the Bardo Unit (Sudetes Mountains, Poland) formed during early diagenesis and were buried to significant depths. Petrographic and geochemical (elemental and stable C and O isotopic) analyses document their formation close to the sediment–water interface, prior to mechanical compaction within the sulphate reduction zone and their later burial below the oil window. Although the concretions were fully formed during early diagenesis, the effects of increased temperature and interaction with late‐diagenetic interstitial fluids can be discerned. During maximum burial, the concretions underwent thorough recrystallization that caused alteration of fabric and elemental and O isotope composition. The initial finely crystalline cement was replaced by more coarsely crystalline, sheaf‐like, poikilotopic calcite in the concretions. These large calcite crystals engulf and partially replace unstable detrital constituents. The extremely low δ¹⁸O values (down to ?21·2‰ Vienna Pee Dee Belemnite) in the concretions are the result of the increased temperature in combination with alteration of volcanic glass, both causing a significant ¹⁸O‐depletion of bicarbonate dissolved in the interstitial fluids. Recrystallization led to uniform O isotope ratios in the concretions, but did not affect the C isotope signature. The δ¹³C values of the late‐diagenetic cements precipitated in the greywacke and in cracks cutting through concretions imply crystallization in the catagenetic zone and decarboxylation as a source of the bicarbonate. These late‐diagenetic processes took place in a supposedly overpressured setting, as suggested by clastic dykes and hydrofractures that cut through both concretions and host rock. All of these features show how the effects of early and late diagenesis can be distinguished in such rocks.     

The Purpose and Age of Underwater Walls in the Bay of Elaia of Western Turkey: A Multidisciplinary Approach

Pergamum (modern: Bergama) was operating an important harbour used by military forces and merchants at the city of Elaia during Hellenistic and Roman Imperial times. Harbour‐related facilities such as warehouses, breakwaters and wharfs document the importance of this harbour site not only for the Pergamenians. This paper focuses on the purpose and age of six submerged wall structures situated approximately 1 km south of the ancient closed harbour basin of Elaia. Geoelectric cross‐sections and semi‐aquatic coring near these walls failed to detect any solid basement under the walls which excludes their possible use as breakwaters or wharfs. Instead, the walls were most likely delineating and separating evaporation ponds of salt works, which compares well with similar structures from other periods and places around the Mediterranean. Combined OSL and ¹⁴C‐dating determined the construction age of the installation between the 4th and 6th centuries A.D. Subsequent (re‐)uses are likely and are in agreement with findings from archaeological surveys.     

Implementing Europe's climate targets at the regional level

Having agreed upon a binding emissions reduction path by 2020, the EU plays a leading role in international climate policy. The EU currently pursues a dual approach through an Emissions Trading Scheme (ETS) at the EU level and also via national targets in sectors not covered by the ETS. The latter include the buildings sector, transportation, agriculture, and waste. Emissions from these sectors are mainly subject to policies at provincial and local levels. A method is presented for elaborating and implementing a long-term climate policy process up to 2030 for the regional (provincial) level. Building on regional GHG inventory data, a set of indicators for each sector is developed in order to arrive at a target path consistent with the deduced regional GHG reduction requirement. Policy measures and their implementation are then settled subsequent to this process. Quantitative regional targets are found to be a prerequisite for the formation of regional climate policy as they increase participant responsibility and commitment. A five-step process of stakeholder participation ensures effective implementation of regional climate action plans. Insights from an exemplary European region are drawn upon, and policy issues are discussed in both quantitative and institutional terms.