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371.
Andreas Schiller 《Continental Shelf Research》2011,31(10):1087-1095
The ocean circulation on Australia's Northern Shelf is dominated by the Monsoon and influenced by large-scale interannual variability. These driving forces exert an ocean circulation that influences the deep Timor Sea Passage of the Indonesian Throughflow, the circulation on the Timor and Arafura Shelves and, further downstream, the Leeuwin Current. Seasonal maxima of northeastward (southwestward) volume transports on the shelf are almost symmetric and exceed 106 m3/s in February (June). The associated seasonal cycle of vertical upwelling from June to August south of 8.5°S and between 124°E and 137.5°E exceeds 1.5×106 m3/s across 40 m depth. During El Niño events, combined anomalies from the seasonal means of high regional wind stresses and low inter-ocean pressure gradients double the northeastward volume transport on the North Australian Shelf to 1.5×106 m3/s which accounts for 20% of the total depth-integrated transport across 124°E and reduce the total transport of the Indonesian Throughflow. Variability of heat content on the shelf is largely determined by Pacific and Indian Ocean equatorial wind stress anomalies with some contribution from local wind stress forcing. 相似文献
372.
In this paper, we investigate the information content in “nanosensors” with limited functionality that might be injected into a reservoir or an aquifer to provide information on the spatial distribution of properties. The two types of sensors that we consider are sensors that can potentially measure pressure at various times during transport, and sensors can be located in space by perturbations in electrical, magnetic, or acoustic properties. The intent of the study is to determine the resolution of estimates of properties that can be obtained from various combinations of sensors, various frequencies of observations, and various specifications on sensor precision.Our goal is to investigate the resolution of model estimates for various types of measurements. For this, we compute linearized estimates of the sensitivity of the observations to the porosity and permeability assuming gaussian errors in the pressure and location observations. Because the flow is one-dimensional and incompressible, observations of location are sensitive to the porosity between the injection location and the sensor location, while the location of particles is sensitive to the effective permeability over the entire interval from injector to producer. When only the pressure is measured but the location of the sensor is unknown, as might be the situation for a threshold sensor, the pressure is sensitive to both permeability and porosity only in the region between the injector and sensor.In addition to the linearized sensitivity and resolution analyses, Markov chain Monte Carlo sampling is used to estimate the posterior pdf for model variables for realistic (non-Gaussian) likelihood models. For a Markov chain of length one million samples approximately 200-500 independent samples are generated for uncertainty and resolution assessment. Results from the MCMC analysis are not in conflict with the linearized analysis. 相似文献
373.
Pierre Bouilhol Urs Schaltegger Massimo Chiaradia Maria Ovtcharova Andreas Stracke Jean-Pierre Burg Hamid Dawood 《Chemical Geology》2011,280(3-4):243-256
The combination of age determination and geochemical tracers allows understanding the source evolution during magmatism. We studied the Sapat Complex, in the exhumed Cretaceous Kohistan Paleo-Island Arc, to reconstruct the formation of the juvenile lower arc crust and the evolution of the mantle source during arc magmatism. High precision ID-TIMS U/Pb dating on zircon, shows that a protracted period of magmatic accretion formed the Sapat Complex between 105 and 99 Ma. Since continued melt percolation processes that formed the lower crust obscured the original bulk rock Nd–Pb–Sr isotopic composition, we rely on the Hf isotopic composition of zircons of different ages to unravel the source evolution. Nd and Pb bulk isotopic compositions coupled with Hf isotopic composition on zircons allow reconstructing a geodynamical scenario for the Sapat Complex, and the Cretaceous history of the Arc. We suggest that trenchward migration of the hot mantle source at 105 Ma explains the small heterogeneous εHf signal between + 14 and + 16. This heterogeneity vanished within ca. 2 million years, and the εHf of the source evolved from + 16 to + 14 at 99 Ma. Integrated to the Kohistan Cretaceous history, which has a baseline of εHf ≈ 14, these data pinpoint two geodynamical events, with slab retreat and the formation of the Sapat Complex followed by splitting of the Kohistan island arc at 85 Ma. 相似文献
374.
Conflicting sorption coefficients for ortho‐phenylphenol (OPP) have been reported in the literatures, which resulted in the conflicting assessments on OPP mobility in soil. To ascertain the sorption coefficient of OPP, batch experiments were performed based on OECD guideline 106, using three types of soils. Headspace solid‐phase microextraction (HS‐SPME) and GC‐MS were applied to the determination of OPP concentration in the liquid phase. The sorption isotherms obtained for all three soils under equilibrium conditions were described well, assuming linear sorption. The organic carbon normalized distribution coefficients (Koc) ranged from 894 to 1703 L kg?1, which suggested that OPP is moderately mobile in soil. The results also showed that the Koc value of OPP can be predicted precisely from Kow, whereas it was underestimated by one order of magnitude when water solubility is used. 相似文献
375.
Andreas Dehnert Oliver Kracht Frank Preusser Naki Akçar Hans Axel Kemna Peter W. Kubik Christian Schlüchter 《Quaternary Geochronology》2011,6(3-4):313-325
Cosmogenic isotope burial dating, using 10Be and 26Al, was applied to Plio–Pleistocene fluvial successions from the Lower Rhine Embayment, Germany. The approach consists of three principal steps: (1) measurement of cosmogenic nuclides in depth profiles, (2) modelling of hypothetical nuclide concentrations based on a first-order conceptualisation of the geological context and the principal succession of depositions and subsequent erosional and burial phases, and (3) using parameter estimation to identify values for the a priori unknown model parameters (burial age, initial nuclide concentrations, terrace erosion rates) that result in minimal disagreement between hypothetical and measured nuclide concentrations.The Late Pliocene Kieseloolite Formation was dated to 3650 ± 1490 ka and the Early Pleistocene Waalre Formation to 900 ± 280 ka. The unconformably overlying Upper Terrace Formation revealed ages of 740 ± 210 ka and 750 ± 250 ka for the two different sites. These findings are in good agreement with independent age control derived by bio-, magneto-, and litho-stratigraphy. Furthermore, identifiability and uncertainty analysis reveal a relationship between burial depth and sensitivity of isotope concentrations to burial age and erosion rate. Our results indicate that using shallower buried samples would enable a considerably more robust estimation of the burial age and the terrace erosion rate. Uncertainties arose mainly from nuclide measurements, and not from the uncertainties derived from modelling or insufficient knowledge of nuclide production and decay properties. 相似文献
376.
Claudia Hohmann Georges Ona-Nguema Gordon E. Brown Jr. Andreas Kappler 《Geochimica et cosmochimica acta》2011,75(17):4699-4712
Sorption of contaminants such as arsenic (As) to natural Fe(III) (oxyhydr)oxides is very common and has been demonstrated to occur during abiotic and biotic Fe(II) oxidation. The molecular mechanism of adsorption- and co-precipitation of As has been studied extensively for synthetic Fe(III) (oxyhydr)oxide minerals but is less documented for biogenic ones. In the present study, we used Fe and As K-edge X-ray Absorption Near Edge Structure (XANES), extended X-ray Absorption Fine Structure (EXAFS) spectroscopy, Mössbauer spectroscopy, XRD, and TEM in order to investigate the interactions of As(V) and As(III) with biogenic Fe(III) (oxyhydr)oxide minerals formed by the nitrate-reducing Fe(II)-oxidizing bacterium Acidovorax sp. strain BoFeN1. The present results show the As immobilization potential of strain BoFeN1 as well as the influence of As(III) and As(V) on biogenic Fe(III) (oxyhydr)oxide formation. In the absence of As, and at low As loading (As:Fe ≤ 0.008 mol/mol), goethite (Gt) formed exclusively. In contrast, at higher As/Fe ratios (As:Fe = 0.020-0.067), a ferrihydrite (Fh) phase also formed, and its relative amount systematically increased with increasing As:Fe ratio, this effect being stronger for As(V) than for As(III). Therefore, we conclude that the presence of As influences the type of biogenic Fe(III) (oxyhydr)oxide minerals formed during microbial Fe(II) oxidation. Arsenic-K-edge EXAFS analysis of biogenic As-Fe-mineral co-precipitates indicates that both As(V) and As(III) form inner-sphere surface complexes at the surface of the biogenic Fe(III) (oxyhydr)oxides. Differences observed between As-surface complexes in BoFeN1-produced Fe(III) (oxyhydr)oxide samples and in abiotic model compounds suggest that associated organic exopolymers in our biogenic samples may compete with As oxoanions for sorption on Fe(III) (oxyhydr)oxides surfaces. In addition HRTEM-EDXS analysis suggests that As(V) preferentially binds to poorly crystalline phases, such as ferrihydrite, while As(III) did not show any preferential association regarding Fh or Gt. 相似文献
377.
Achim G. Reisdorf Andreas Wetzel Rudolf Schlatter Peter Jordan 《Swiss Journal of Geoscience》2011,104(1):97-146
The deposits of the Early Jurassic in northern Switzerland accumulated in the relatively slowly subsiding transition zone
between the southwestern part of the Swabian basin and the eastern part of the Paris basin under fully marine conditions.
Terrigenous fine-grained deposits dominate, but calcarenitic and phosphorit-rich strata are intercalated. The total thickness
varies between 25 and 50 m. In the eastern and central parts of N Switzerland, sediments Sinemurian in age constitute about
90% of the total thickness. To the West, however, in the Mont Terri area, Pliensbachian and Toarcian deposits form 70% of
the total thickness. Stratigraphic gaps occur on a local to regional scale throughout N Switzerland. Such hiatus comprise
a subzone to a stage in time. With respect to lithology and fossil content, the Early Jurassic deposits in northern Switzerland
are similar to those in SW Germany. Nonetheless, an exact stratigraphic correlation is hardly possible, particulary in the
southern and southwestern Folded Jura where distinct facies changes occur over short distances. Revised existing and new litho-
and biostratigraphic data form the base to refine the stratigraphic subdivision of the deposits that have been informally
called “Lias”. The name Staffelegg Formation is suggested and defined as the mapping unit for the Early Jurassic. The Staffelegg
Formation is introduced for Early Jurassic sediments in northern Switzerland between the Doubs River and Mt. Weissenstein
in the west and the Randen Hills located north of the city of Schaffhausen in the east. The Staffelegg Formation starts within
the Planorbis zone of the Hettangian. The upper boundary to the overlying Aalenian Opalinus-Ton is diachronous. The lithostratigraphic
names previously in use have been replaced by new ones, in accordance within the rules of lithostratigraphic nomenclature.
The Staffelegg Formation comprises 11 members and 9 beds. Several of these beds are important correlation horizons in terms
of allostratigraphy. Some of them correspond to strata or erosional unconformities encountered in the Swabian realm, some
of them can be correlated with strata in the Paris basin. The facies transition to the Paris basin is expressed by introduction
of a corresponding lithostratigraphic unit. 相似文献
378.
Klaus Peter Jochum Steven A. Wilson Wafa Abouchami Marghaleray Amini Jérome Chmeleff Anton Eisenhauer Ernst Hegner Linda M. Iaccheri Bruno Kieffer Joachim Krause William F. McDonough Regina Mertz‐Kraus Ingrid Raczek Roberta L. Rudnick Denis Scholz Grit Steinhoefel Brigitte Stoll Andreas Stracke Sonia Tonarini Dominique Weis Ulrike Weis Jon D. Woodhead 《Geostandards and Geoanalytical Research》2011,35(2):193-226
This paper contains the results of an extensive isotopic study of United States Geological Survey GSD‐1G and MPI‐DING reference glasses. Thirteen different laboratories were involved using high‐precision bulk (TIMS, MC‐ICP‐MS) and microanalytical (LA‐MC‐ICP‐MS, LA‐ICP‐MS) techniques. Detailed studies were performed to demonstrate the large‐scale and small‐scale homogeneity of the reference glasses. Together with previously published isotopic data from ten other laboratories, preliminary reference and information values as well as their uncertainties at the 95% confidence level were determined for H, O, Li, B, Si, Ca, Sr, Nd, Hf, Pb, Th and U isotopes using the recommendations of the International Association of Geoanalysts for certification of reference materials. Our results indicate that GSD‐1G and the MPI‐DING glasses are suitable reference materials for microanalytical and bulk analytical purposes. 相似文献
379.
The hydraulic and hydrochemical interactions of surface water and groundwater in the riverbank of an alluvial stream in the Grand Duchy of Luxembourg were investigated. Hydraulic conductivity in the riverbank is low and the aquifer is confined. Gauged surface-water levels and groundwater levels were recorded over several months to observe potential effluent and influent aquifer conditions. Water samples were taken under different hydraulic conditions in the stream and from three observation wells in the riverbank. Samples were analysed for inorganic parameters and selected dissolved pharmaceuticals. The recorded groundwater levels in the riverbank responded almost without delay to changes in stream stage, which is very dynamic. Frequent changes from effluent to influent aquifer conditions were observed. The analyses for selected ions and pharmaceuticals support the assumption that the pharmaceutical compounds enter the riverbank via the stream only. The chosen trace organics are therefore suitable as anthropogenic tracers for groundwater and surface-water interactions at this field site. They prove that water exchanges also take place in riverbanks even where the hydraulic conductivity is low and for this reason indicate the existence of a hyporheic zone in the investigated section of the stream. 相似文献
380.
Andreas S. Stordal Hans A. Karlsen Geir Nævdal Hans J. Skaug Brice Vallès 《Computational Geosciences》2011,15(2):293-305
The nonlinear filtering problem occurs in many scientific areas. Sequential Monte Carlo solutions with the correct asymptotic
behavior such as particle filters exist, but they are computationally too expensive when working with high-dimensional systems.
The ensemble Kalman filter (EnKF) is a more robust method that has shown promising results with a small sample size, but the
samples are not guaranteed to come from the true posterior distribution. By approximating the model error with a Gaussian
distribution, one may represent the posterior distribution as a sum of Gaussian kernels. The resulting Gaussian mixture filter
has the advantage of both a local Kalman type correction and the weighting/resampling step of a particle filter. The Gaussian
mixture approximation relies on a bandwidth parameter which often has to be kept quite large in order to avoid a weight collapse
in high dimensions. As a result, the Kalman correction is too large to capture highly non-Gaussian posterior distributions.
In this paper, we have extended the Gaussian mixture filter (Hoteit et al., Mon Weather Rev 136:317–334, 2008) and also made the connection to particle filters more transparent. In particular, we introduce a tuning parameter for the
importance weights. In the last part of the paper, we have performed a simulation experiment with the Lorenz40 model where
our method has been compared to the EnKF and a full implementation of a particle filter. The results clearly indicate that
the new method has advantages compared to the standard EnKF. 相似文献