Li-bearing, disordered Mg-rich tourmaline from a pegmatite-marble contact in the Austroalpine basement units (Styria, Austria)

Pale-blue to pale-green tourmalines from the contact zone of Permian pegmatites to mica schists and marbles from different localities of the Austroalpine basement units (Rappold Complex) in Styria, Austria, are characterized. All these Mg-rich tourmalines have small but significant Li contents, up to 0.29 wt% Li₂O, and can be characterized as dravite, with FeO contents of ?~?0.9–2.7 wt%. Their chemical composition varies from ^X (Na_0.67Ca_0.19?K_0.02?_0.12) ^Y (Mg_1.26Al_0.97Fe²⁺ _0.36Li_0.19Ti⁴⁺ _0.06Zn_0.01?_0.15) ^Z (Al_5.31?Mg_0.69) (BO₃)₃ Si₆O₁₈ ^V (OH)₃? ^W [F_0.66(OH)_0.34], with a?=?15.9220(3), c?=?7.1732(2) Å to ^X (Na_0.67Ca_0.24?K_0.02?_0.07) ^Y (Mg_1.83Al_0.88Fe²⁺ _0.20Li_0.08Zn_0.01Ti⁴⁺ _0.01?_0.09) ^Z (Al_5.25?Mg_0.75) (BO₃)₃ Si₆O₁₈ ^V (OH)₃? ^W [F_0.87(OH)_0.13], with a?=?15.9354(4), c?=?7.1934(4) Å, and they show a significant Al-Mg disorder between the Y and the Z sites (R1?=?0.013–0.015). There is a positive correlation between the Ca content and?<?Y-O?>?distance for all investigated tourmalines (r?≈?1.00), which may reflect short-range order configurations including Ca and Fe²⁺, Mg, and Li. The tourmalines have X_Mg (X_Mg?=?Mg/Mg?+?Fe_total) values in the range 0.84–0.95. The REE patterns show more or less pronounced negative Eu and positive Yb anomalies. In comparison to tourmalines from highly-evolved pegmatites, the tourmaline samples from the border zone of the pegmatites of the Rappold Complex contain relatively low amounts of total REE (~8–36 ppm) and Th (0.1–1.8 ppm) and have low La_N/Yb_N ratios. There is a positive correlation (r?≈?0.91) between MgO of the tourmalines and the MgO contents of the surrounding mica schists. We conclude that the pegmatites formed by anatectic melting of mica schists and paragneisses in Permian time. The tourmalines crystallized from the pegmatitic melt, influenced by the metacarbonate and metapelitic host rocks.     

Zircon texture and chemical composition as a guide to magmatic processes and mixing in a granitic environment and coeval volcanic system

This study documents the chemical and textural responses of zircon in the Elba igneous complex, with particular reference to the 7- to 7.8-Ma-old Monte Capanne pluton in relation to its coeval volcanic counterpart (Capraia), using BSE imaging and quantitative electron microprobe analyses. The Monte Capanne pluton displays multiple field and geochemical evidence for magma mixing. The samples we have investigated (including monzogranitic, mafic enclave and dyke samples) display similar zircon textures and are associated with an extremely large range of trace and minor element (Hf, Y, HREE, Th, U) compositions, which contrast with relatively simple textures and zoning patterns in zircons from a Capraia dacite. We have used a relatively simple textural classification (patchy zoning, homogenous cores, oscillatory zoning and unzoned zircon) as the basis for discussing the chemical composition and chemical variation within zircons from the Monte Capanne pluton. Based on these data and other works (Dini et al. 2004 in Lithos 78:101–118, 2004) , it is inferred that mixing between metaluminous and peraluminous melts occurred early in the evolution of the Monte Capanne magma chamber. In particular, mixing was responsible for the development of the patchy-zoning texture in the zircon cores, which was associated with reactions between other accessory phases (including monazite, apatite, allanite), which we infer to have significantly affected the Th distribution in zircon. Zircons from the MC pluton displaying “homogeneous cores” have chemical affinities with zircons in the coeval Capraia volcanic system, consistent with the participation of a Capraia-like mantle end-member during mixing. Further zircon growth in the MC pluton produced the oscillatory zoning texture, which records both long-term (crystal fractionation) and transient (recharge with both silicic and mafic magmas) events in a hybrid magma chamber. It is inferred that Hf and the Th/U ratio cannot be used alone to infer magmatic processes due to their dependency on temperature, nor are they a diagnostic feature of xenocrystic grains. This study shows that zircon chemistry coupled with detailed textural analysis can provide a powerful tool to elucidate the complex evolution of a magma system.     

CO2 sequestration and extreme Mg depletion in serpentinized peridotite clasts from the Devonian Solund basin, SW-Norway

The conglomerates of the Solund Devonian basin of SW-Norway contain numerous (locally up to 20 vol.%) peridotitic clasts with concentric mm- to 10-cm thick zones of varying red to black color. The peridotite clasts show a clear, alteration-related textural evolution. The least-altered rocks are partly serpentinized peridotites, showing a typical mesh texture with veins of serpentine, magnesite and Ni-rich magnetite surrounding olivine (Fo₉₁) relicts and its Mg-depleted, clay-like alteration product (deweylite assemblage). In the more advanced ophicarbonate stage, the mesh cells contain calcite, silica and are surrounded by talc. In the final stage, quartz, calcite, and hematite dominate the mineralogy and occur together with minor amounts of chromite, talc, Cr-chlorite, and Cr-hydroandradite. In tandem with this textural evolution is a decrease in MgO from 40 to 2.5 wt% and a CaO increase from 1 to 35 wt%. All peridotite clasts are characterized by high Cr and Ni concentrations. The chemistry and the textural evolution show that the clasts formed by an extreme Mg-mobilization from the peridotite, with development of secondary porosity and subsequent precipitation of calcite. MgO removed from the clasts after burial is in part consumed by replacement reactions in the sediment matrix around the clasts where Mg-free minerals (e.g., almandine) are replaced by Mg-bearing minerals (e.g., talc). Calculated apparent ⁸⁷Sr/⁸⁶Sr ratios of the clasts at 385 Ma (0.7124-0.7139), corresponding to the inferred age of sediment deposition and incipient clast alteration, indicate interaction with diagenetic basinal fluids. We explain the reaction history as a three stage process involving (a) partial serpentinization of olivine in an oceanic environment (b) breakdown of olivine relicts to the deweylite assemblage resulting in mobilization of MgO under (near-) surface conditions in a tropical Devonian climate and (c) further Mg-mobilization and replacement of the deweylite assemblage by calcite and quartz after diagenesis. Sedimentary basins with abundant weathered peridotite represent potential sites for a permanent CO₂ storage by formation of calcite in a low-temperature environment.     

Synthetic stellar and SSP libraries as templates for Gaia simulations

ESA’s Gaia mission will collect low resolution spectroscopy in the optical range for ～10⁹ objects. Complete and up-to-date libraries of synthetic stellar spectra are needed to built algorithms aimed to automatically derive the classification and the parametrization of this huge amount of data. In addition, libraries of stellar spectra are one of the main ingredients of stellar population synthesis models, aiming to derive the properties of unresolved stellar populations from their integrated light. We present (a) the newly computed libraries of synthetic spectra built by the Gaia community, covering the whole optical range (300–1100 nm) at medium-high resolution of (0.3 nm) for stars spanning the most different types, from M to O, from A-peculiar to Emission lines to White Dwarfs, and (b) the implementation of those libraries in our SSP code (Tantalo in The Initial Mass Function 50 Years Later, 327:235 2005), exploring different stellar evolution models.     

Spectral study of the Eunomia asteroid family Part II: The small bodies

Reflectance spectra in visible and near-infrared wavelengths of 97 nominal members of the Eunomia asteroid family have been obtained and analyzed. According to these investigations, 94% of the observed dynamic family members belong to the Tholen S-class, only 4% to the C-class and 2% to the M-class. The S-asteroids are believed to be “genetic” members of the Eunomia family and thus are fragments of 15 Eunomia. The fragments show different 1- and 2-μm absorption band characteristics, which are likely attributed to their place of origin within the parent body. The major volume fraction of the investigated members seems to originate from the “crust” of the parent body while the volume fraction of “mantle” material is less. Previous spectral investigations (Nathues, A., Mottola, S., Kaasalainen, M., Neukum, G. [2005], Icarus 175 (2), 452-463) of the family’s main body, 15 Eunomia, revealed variations of olivine and pyroxene on a hemispherical scale. These findings, together with the conclusion that the major mineral component of 15 Eunomia and its fragments is olivine, suggest that a large fraction of the original pyroxene-enriched crust layer has been lost due to a major collision that created the asteroid family. Significant spectral evidences consistent with high concentrations of metals have not been found in the rotational resolved spectra of 15 Eunomia and in its fragments. This led to the conclusion that either a core, which consists mainly of metals, does not exist or that an eventual one has not yet been unearthed by an impact. The absence of V-type asteroids, the low number of M-types among the dynamic family members and the lack of distinct feldspar absorption features in the S-asteroid spectra suggest that the parent body of the Eunomia family was partially differentiated rather than fully differentiated.     

Compositional heterogeneity of Asteroid 4 Vesta’s southern hemisphere: Implications for the Dawn mission

High signal-to-noise, rotationally-resolved spectra of Asteroid 4 Vesta’s southern hemisphere from the 2007 opposition were used to constrain its compositional and mineralogical variations. The spectra were rotationally-phased using closely timed HST observations of Vesta by Li et al. (Li, J.-Y., McFadden, L.A., Thomas, P.C., Mutchler, M.J., Parker, J.Wm., Young, E.F., Russell, C.T., Sykes, M.V., Schmidt, B.E. [2010]. Icarus 208, 238–251). The average surface of Vesta’s southern hemisphere is analogous to a howardite or polymict eucrite assemblage similar to the northern hemisphere, although the band parameters are distinctly shifted towards the diogenite zone on the Band–Band plot. A few distinct compositional units were detected and they might be related to albedo features detected by Hubble Space Telescope (Li et al., 2010). We have identified two compositionally distinct regions overlaying the background surface. The first unit is a polymict eucrite and/or low-Ca eucrite compositional unit at 143° longitude that border the eucrite zone on the Band–Band plot and the second is a diogenite unit at 159°. While we did not detect any distinct olivine units as suggested by Gaffey (Gaffey, M.J. [1997]. Icarus 127, 130–157), we cannot rule out the possibility of smaller olivine-rich units that are below the detection limit of the instrumentation we used. Based on the analysis and the limitations of the data, we do not suggest that Vesta’s surface is olivine-free. Mean pyroxene chemistry estimates for both hemispheres broadly agree with one another (to within one-sigma) with the northern hemisphere ferrosilite (Fs) and wollastonite (Wo) values being slightly higher than southern hemisphere.     

From Tethys to Eastern Paratethys: Oligocene depositional environments, paleoecology and paleobiogeography of the Thrace Basin (NW Turkey)

The Oligocene depositional history of the Thrace Basin documents a unique paleogeographic position at a junction between the Western Tethys and the Eastern Paratethys. As part of the Tethys, shallow marine carbonate platforms prevailed during the Eocene. Subsequently, a three-staged process of isolation started with the Oligocene. During the Early Rupelian, the Thrace Basin was still part of the Western Tethys, indicated by typical Western Tethyan marine assemblages. The isolation from the Tethys during the Early Oligocene is reflected by oolite formation and endemic Eastern Paratethyan faunas of the Solenovian stage. The third phase reflects an increasing continentalisation of the Thrace Basin with widespread coastal swamps during the Late Solenovian. The mollusc assemblages are predominated by mangrove dwelling taxa and the mangrove plant Avicennia is recorded in the pollen spectra. The final continentalisation is indicated by the replacement of the coastal swamps by pure freshwater swamps and fluvial plains during the Late Oligocene (mammal zone MP 26). This paleogeographic affiliation of the Thrace Basin with the Eastern Paratethys after ~32 Ma contrasts all currently used reconstructions which treat the basin as embayment of the Eastern Mediterranean basin.     

Validation of climate-mode MM5-simulations for the European Alpine Region

Climate mode simulations using MM5 have been conducted over Western Europe on a 45-km grid driven by ECMWF’s ERA40 reanalysis data. We focus our validation on the Alpine region and the Alpine foreland. A reference experiment comprising the years of 1991 to 2000 shows reasonable correspondence to station measurements and a gridded precipitation climatology of the Alps. Also, the mean monthly diurnal cycle of near-surface temperature and dew point temperature verified in the Alpine foreland compares quite well to station data showing some minor discrepancies mainly in the afternoon that seem to be common to regional models. Furthermore, a set of sensitivity experiments was conducted for the years of 1996 to 1999. This set was spanned on the one hand by three convection schemes to get an estimate of the possible range of simulated precipitation amounts inherent to the MM5-system. On the other hand, two different formulations of the horizontal numerical diffusion were investigated with respect to their influence on simulated precipitation in mountainous terrain. It was found that the impact of the formulation of numerical diffusion is similarly large as the sensitivity to the convection scheme, with computing diffusion along the terrain-following coordinate surfaces being clearly worse than computing it in a truly horizontal manner.     

Further development of a multimodal pushover analysis procedure for seismic assessment of bridges

An improvement is first suggested to the modal pushover analysis (MPA) procedure for bridges initially proposed by the writers (Earthquake Engng Struct. Dyn. 2006; 35 (11):1269–1293), the key idea being that the deformed shape of the structure responding inelastically to the considered earthquake level is used in lieu of the elastic mode shape. The proposed MPA procedure is then verified by applying it to two actual bridges. The first structure is the Krystallopigi bridge, a 638 m‐long multi‐span bridge, with significant curvature in plan, unequal pier heights, and different types of pier‐to‐deck connections. The second structure is a 100 m‐long three‐span overpass bridge, typical in modern motorway construction in Europe, which, although ostensibly a regular structure, is found to exhibit a rather unsymmetric response in the transverse direction, mainly due to torsional irregularity. The bridges are assessed using response spectrum, ‘standard’ pushover (SPA), and MPA, and finally using non‐linear response history analysis (NL‐RHA) for a number of spectrum‐compatible motions. The MPA provided a good estimate of the maximum inelastic deck displacement for several earthquake intensities. The SPA on the other hand could not predict well the inelastic deck displacements of bridges wherever the contribution of the first mode to the response of the bridge was relatively low. Copyright © 2009 John Wiley & Sons, Ltd.     

Determinants of corporate adaptation to climate change in winter tourism: An econometric analysis

While corporate adaptation strategies in response to climate change have been characterized, the determinants of adaptation have not been comprehensively analyzed. Knowledge of these determinants is particularly useful for policy makers to provide favorable conditions in support of corporate adaptation measures. Based on unique data from a survey of Swiss ski lift operators, this paper empirically examines such determinants at the business level. Our econometric analysis with linear regression and count data models finds a positive influence of the awareness of possible climate change effects on the scope of corporate adaptation. Surprisingly, no significant influence of the vulnerability to climate change effects on the scope of adaptation could be found. Finally, the dependency on the affected business and the ability to adapt influence the specific strategic directions of corporate adaptation.