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981.
The bicyclic terpanes reported to be present in numerous petroleums have been detected in the saturate fraction of the Athabasca oil sand bitumen. This series of compounds has been found to extend from C15 to at least C24 and their structures have been established by means of comparisons with synthetic C18 and C20 samples of known stereochemistry. 相似文献
982.
983.
Charles R. Stern Wuu-Liang Huang Peter J. Wyllie 《Earth and Planetary Science Letters》1975,28(2):189-196
Three rocks representing the calc-alkaline rock series gabbro-tonalite-granite or basalt-andesite-rhyolite were reacted with varying percentages of water in sealed capsules between 600 and 1300°C and pressures to 36 kbars, corresponding to depths of more than 120 km within the earth. For each rock we present complete P-T diagrams with excess water, and the water-undersaturated liquids surface projected from P-T-XH2O space mapped with contours for constant H2O contents and with the fields for near-liquidus minerals. All changes in liquidus and solidus slopes can be correlated with changes in mineralogy from less dense to more dense, or with expansion of crystallization fields, without appeal to changes in molar volume of H2O in liquid and vapor phases. The results indicate that tholeiites and andesites of the calc-alkaline series with compositions similar to the rocks studied are not primary magmas from mantle peridotite at depths greater than about 50 km. Primary andesitic magmas from shallower levels would require very high water contents and we do not believe such magmas could normally reach the surface. The liquids results are consistent with the derivation of andesites with little dissolved water as primary magmas from subducted ocean crust (quartz eclogite), but multi-stage models are preferred. Temperatures required for the generation of andesites by fusion of continental crust are higher than considered reasonable. The evidence precludes the generation of primary rhyolites or granites from the mantle of subducted oceanic crust at mantle depths. Primary rhyolite or granite magmas with moderate water contents (saturated or undersaturated) can be generated in the crust at reasonable temperatures, and could reach near-surface levels before vesiculation. Water-undersaturated granite liquid with residual crustal minerals could constitute plutonic magmas of intermediate composition. 相似文献
984.
Andreas Junge 《Pure and Applied Geophysics》1990,134(4):589-598
The measurement of the telluric field's long-time variations requires stable instruments in the period range above 1 day. Obviously, most problems arise from drifting voltages between the telluric probes. Good results have been achieved using a three chamber Hempfling KCl probe together with Filloux's AgAgCl electrode. However, a one chamber probe of 0.6 m length and 0.06 m diameter filled with saturated KCl solution may be sufficient for some applications and additionally allows permanent control of the electrolyte's salt concentration. In a field test the telluric field at a single site was simultaneously observed using one and three chamber probes separated by 25 and 55 m resp. For periods shorter than 1 hour the noise level of the electrodes was found to be less than 1 (mV)2/Hz whereas in the period range between 1 hour and 1 day it increases to 100 (mV)2/Hz. Consequently, surveys investigating long periods of the telluric field can be carried out using small electrode separations of a few tens of meters. Furthermore, the stability of this probe negates the need to interrupt the time series for servicing of the probe. However, the one chamber probe is somewhat inferior to the three chamber probe with regard to temperature dependence at long periods. 相似文献
985.
Enriched back-arc basin basalts from the northern Mariana Trough: implications for the magmatic evolution of back-arc basins 总被引:1,自引:0,他引:1
Robert J. Stern Ping-Nan Lin Julie D. Morris Michael C. Jackson Patricia Fryer Sherman H. Bloomer Emi Ito 《Earth and Planetary Science Letters》1990,100(1-3)
The composition of basalts erupted at the earliest stages in the evolution of a back-arc basin permit unique insights into the composition and structure of the sub-arc mantle. We report major and trace element chemical data and O-, Sr-, Nd-, and Pb- isotopic analyses for basalts recovered from four dredge hauls and one ALVIN dive in the northern Mariana Trough near 22°N. The petrography and major element chemistry of these basalts (MTB-22) are similar to tholeiites from the widest part of the Trough, near 18°N (MTB-18), except that MTB-22 have slightly more K2O and slightly less TiO2. The trace element data exhibit a very strong arc signature in MTB-22, including elevated K, Rb, Sr, Ba, and LREE contents; relatively lowK/Ba and highBa/La andSr/Nd. The Sr- and Nd- isotopic data plot in a field displaced from that of MTB-18 towards Mariana arc lavas, and the Pb-isotopic composition of MTB-22 is indistinguishable from Mariana arc lavas and much more homogeneous than MTB-18. Mixing of 50–90% Mariana arc component with a MORB component is hypothesized. We cannot determine whether this resulted from physical mixing of arc mantle and MORB mantle, or whether the arc component is introduced by metasomatism of MORB-like mantle by fluids released from the subducted lithosphere. The strong arc signature in back-arc melts from the Mariana Trough at 22°N, where the back-arc basin is narrow, supports general models for back-arc basin evolution whereby early back-arc basin basalts have a strong arc component which diminishes in importance relative to MORB as the back-arc basin widens. 相似文献
986.
Andreas J. Kappos 《地震工程与结构动力学》1991,20(2):167-176
Criteria to be used for the analytical prediction of collapse of R/C buildings subjected to earthquake excitation are suggested. It is attempted to include in the criteria as many of the parameters involved as possible, while keeping the complexity, as well as the cost of analysis reasonably low. Two combined collapse criteria are finally suggested, corresponding to member failure and storey failure. Using these criteria, quantitative estimations can be obtained of the actual values of behaviour factors (q-factors) used in modern seismic codes. The ground motion dependence of these factors, as well as the sensitivity of their calculated values to the assumption made about the stiffness of R/C members, is illustrated with reference to two typical structures. 相似文献
987.
Edgar L Andreas 《Boundary-Layer Meteorology》1991,54(1-2):167-182
Local free convection scaling is one of the obvious triumphs of boundary-layer similarity theory. In free convection, there is no dynamic velocity scale; the sensible and latent heat fluxes, therefore, scale directly with the temperature and humidity structure parameters C
t
2 and C
q
2. By using scintillation to measure the refractive index structure parameter C
n
2 at two electromagnetic (EM) wavelengths, we can obtain C
t
2 and C
q
2 and, thus, in effect, measure path-averaged values of the sensible and latent heat fluxes. Here I describe this so-called two-wavelength method for free convection, derive quantitative guidelines for optimizing the method, and evaluate its potential accuracy. I show that the two-wavelength method works best when one EM wavelength is in the visible or infrared region and the other is in the millimeter or radio region. When the Bowen ratio is between -5 and -0.1 or between 0.1 and 5, the expected accuracy of the measured fluxes is ±10–20% — typical of what is possible with eddy-correlation measurements. With the two-wavelength method, however, the fluxes represent spatial averages. 相似文献
988.
Transport of ammonium (NH4 +), nitrate + nitrite (NO3 ?), total Kjeldahl nitrogen (TKN), soluble reactive phosphate (SRP), and total suspended solids (TSS) was measured in a freshwater tidal bayou located in a marsh system near the mouth of the Atchafalaya River in Louisiana. Sampling was conducted six times over one year and was timed to assess effects of seasonal variation in river flow and mean sea level of the Gulf of Mexico on material fluxes. Net fluxes of all materials were large and ebb directed in all seasons except fall, when net transport was 2 to 3 orders-of-magnitude smaller than in any other season. These results demonstrate that riverine forcing was the primary influence on materials transport in all seasons except fall when tidal forcing was most important. The range of net fluxes (g s?1) for each nutrient was as follows (a negative sign indicates a net export toward the Gulf): NO3 ?, ?0.006 to ?6.69; TKN, 0.09 to ?10.41; NH4 +, ?0.02 to ?1.36; SRP, ?0.001 to ?0.53; TSS, ?2 to ?81. Analysis of nutrient concentrations indicated the marsh/aquatic system removed NO3 ?, SRP, and TSS from the water column from late spring through early fall and released NH4 + and TKN in summer. The results of this study show that net materials export per unit cross section channel area increased as riverine influence increased. 相似文献
989.
990.