Late Pleistocene dust deposition in the Patagonian steppe - extending and refining the paleoenvironmental and tephrochronological record from Laguna Potrok Aike back to 55 ka

Paleoenvironmental records extending well into the last glacial period are scarce in the steppe regions of southern South America. Here, we present a continuous record for the past 55 ka from the maar lake Laguna Potrok Aike (51°58′ S, 70°23′ W, southern Patagonia, Argentina). Previous studies on a sedimentary core from a lake level terrace near the northern margin of the lake covered parts of Oxygen Isotope Stage (OIS) 3 (59–29 ka) whereas a second core from the centre of the basin comprised the last 16 ka. Tephrostratigraphical constraints and OSL ages from a third core located below the lake level terrace provide the crucial piece to close the gap between the previous coring sites. High-resolution XRF and magnetic susceptibility as well as grain size data indicate a positive hydrological balance alongside with relatively high aeolian activity during the glacial which is contemporaneous with increased dust fluxes in Antarctica. This is therefore the first evidence for contemporaneity of aeolian deposition in both the target area (Antarctica) and in the major source area of Patagonia. During the Holocene climatic conditions driving sediment deposition seem to have been more variable and less dominated by wind compared to glacial times. The identification of a minor lake level lowering at approximately 4 cal ka BP allows to refine earlier paleoenvironmental reconstructions for the Holocene. Within error margins the OSL ages are consistent with published radiocarbon-dated records offering hence a valuable tool for further studies of the sediments from Laguna Potrok Aike. The new chronology confirms the age of three tephra layers up to now only found in Laguna Potrok Aike sediments and ascribed to OIS 3.     

Korallen,Fischer und Touristen

Ocean Dynamics - Als Folge von natürlichen und anthropogenen Störungen sind Korallenriffe weltweit gefährdet. Im vorliegenden Vortrag wird von zwei sehr wesentlichen menschlichen...     

Characterization of regional hydrological drought using improved precipitation records under multi-auxiliary information

Theoretical and Applied Climatology - Drought is a complex natural hazard that has been recurrently occurred in many regions across the globe. Therefore, precise drought characterization and its...     

Planetary scientific target detection via deep learning: A case study for finding shatter cones in Mars rover images

Past, present, and forthcoming planetary rover missions to Mars and other planetary bodies are equipped with a large number of scientific cameras. The very large number of images resulting from this, combined with tight time constraints for navigation, measurements, and analyses, pose a major challenge for the mission teams in terms of scientific target evaluation. Shatter cones are the only macroscopic evidence for impact-induced shock metamorphism and therefore impact craters on Earth. The typical features of shatter cones, such as striations and horsetail structures, are particularly suitable for machine learning methods. The necessary training images do not exist for such a case; therefore, we pursued the approach of producing them artificially. Using PRo3D, a viewer developed for the interactive exploration and geologic analysis of high-resolution planetary surface reconstructions, we virtually placed shatter cones in 3-D background scenes processed from true Mars rover imagery. We use PRo3D-rendered images of such scenes as training data for machine learning architectures. Terrestrial analog studies in Ethiopia supported our lab work and were used to test the resulting neural network of this feasibility study. The result showed that our approach with shatter cones in artificial Mars rover scenes is suitable to train neural networks for automatic detection of shatter cones. In addition, we have identified several aspects that can be used to improve the training of the neural network and increase the recognition rate. For example, using background data with a higher resolution in order to have equal resolution of object (shatter cone) and Martian background and increase the number of objects that can be placed in the training data set. Also using better lighting reconstructions and a better radiometric adaption between object and Martian background would further improve the results.     

Silver-rich telluride mineralization at Mount Charlotte and Au–Ag zonation in the giant Golden Mile deposit,Kalgoorlie, Western Australia

The gold deposits at Kalgoorlie in the 2.7-Ga Eastern Goldfields Province of the Yilgarn Craton, Western Australia, occur adjacent to the D2 Golden Mile Fault over a strike of 8 km within a district-scale zone marked by porphyry dykes and chloritic alteration. The late Golden Pike Fault separates the older (D2) shear zone system of the Golden Mile (1,500 t Au) in the southeast from the younger (D4) quartz vein stockworks at Mt Charlotte (126 t Au) in the northwest. Both deposits occur in the Golden Mile Dolerite sill and display inner sericite–ankerite alteration and early-stage gold–pyrite mineralization replacing the wall rocks. Late-stage tellurides account for 20 % of the total gold in the first, but for <1 % in the second deposit. In the Golden Mile, the main telluride assemblage is coloradoite?+?native gold (898–972 fine)?+?calaverite?+?petzite?±?krennerite. Telluride-rich ore (>30 g/t Au) is characterized by Au/Ag?=?2.54 and As/Sb?=?2.6–30, the latter ratio caused by arsenical pyrite. Golden Mile-type D2 lodes occur northwest of the Golden Pike Fault, but the Hidden Secret orebody, the only telluride bonanza mined (10,815 t at 44 g/t Au), was unusually rich in silver (Au/Ag?=?0.12–0.35) due to abundant hessite. We describe another array of silver-rich D2 shear zones which are part of the Golden Mile Fault exposed on the Mt Charlotte mine 22 level. They are filled with crack-seal and pinch-and-swell quartz–carbonate veins and are surrounded by early-stage pyrite?+?pyrrhotite disseminated in a sericite–ankerite zone more than 6 m wide. Gold grade (0.5–0.8 g/t) varies little across the zone, but Au/Ag (0.37–2.40) and As/Sb (1.54–13.9) increase away from the veins. Late-stage telluride mineralization (23 g/t Au) sampled in one vein has a much lower Au/Ag (0.13) and As/Sb (0.48) and comprises scheelite, pyrite, native gold (830–854 fine), hessite, and minor pyrrhotite, altaite, bournonite, and boulangerite. Assuming 250–300 °C, gold–hessite compositions indicate a fluid log f _Te2 of ?11.5 to ?10, values well below the stability of calaverite. The absence of calaverite and the dominance of hessite in the D2 lodes of the Mt Charlotte area point to a kilometer-scale mineral and Au/Ag zonation along the Golden Mile master fault, which is attributed to a lateral decrease in peak tellurium fugacity of the late-stage hydrothermal fluid. The As/Sb ratio may be similarly zoned to lower values at the periphery. The D4 gold–quartz veins constituting the Mt Charlotte orebodies represent a younger hydrothermal system, which did not contribute to metal zonation in the older one.     

Impacts of subsurface heat storage on aquifer hydrogeochemistry

The use of shallow aquifers for subsurface heat storage in terms of energy management and building climatisation can lead to a temperature rise in the aquifer to 70 °C and above. The influence of temperature changes on individual mineral and sorption equilibria, reaction kinetics and microbial activity is largely known. However, the impact of heating to temperatures as high as 70 °C on the aquifer overall system has not been quantified yet. Temperature-related changes in sediment ion exchange behaviour, dimension and rates of mineral dissolution and precipitation as well as microbially enhanced redox processes were studied in column experiments using aquifer sediment and tap water at 10, 25, 40, and 70 °C. At 70 °C, a change in sediment sorption behaviour for cations and organic acids was postulated based on temporal changes in pH, magnesium, and potassium concentration in the experimental solution. No clear changes of pH, TIC and major cations were found at 10–40 °C. Redox zoning shifted from oxic conditions towards nitrate and iron(III) reducing conditions at 25 and 40 °C and sulphate reducing conditions at 70 °C. This was attributed to (a) a temperature-related increase in microbial reduction activity, and (b) three times higher release of organic carbon from the sediment at 70 °C compared to the lower temperatures. The findings of this study predict that a temperature increase in the subsurface up to 25 °C and above can impair the usability of ground water as drinking and process water, by reducing metal oxides and thus possibly releasing heavy metals from the sediment. Generally, at 70 °C, where clear cation and organic carbon desorption processes were observed and sulphate reducing conditions could be achieved, a site-specific assessment of temperature effects is required, especially for long-term operations of subsurface heat storage facilities.     

Neoproterozoic ophiolitic peridotites along the Allaqi-Heiani suture, South Eastern Desert, Egypt

The Wadi Allaqi ophiolite along the Egyptian-Sudanese border defines the southernmost ophiolitic assemblage and suture zone in the Eastern Desert. Ophiolite assemblages comprise nappes composed mainly of mafic and ultramafic rocks that were tectonically emplaced and replaced by serpentine and carbonates along shear zones probably due to CO₂-metasomatism. Serpentinites, altered slices of the upper mantle, represent a distinctive lithology of dismembered ophiolites of the western YOSHGAH suture. Microscopically, they are composed of more than 90 % serpentine minerals with minor opaque minerals, carbonate, brucite and talc. The mineral chemistry and whole-rock chemical data reported here indicate that the serpentinized peridotites formed as highly-depleted mantle residues. They show compositions consistent with formation in a suprasubduction zone environment. They are depleted in Al₂O₃ and CaO similar to those in fore-arc peridotites. Also, high Cr# (Cr/ (Cr+Al)) in the relict chrome spinels (average ~0.72) indicates that these are residual after extensive partial melting, similar to spinels in modern fore-arc peridotites. Therefore, the studied serpentinites represent fragments of an oceanic lithosphere that formed in a fore-arc environment, which belongs to an ophiolitic mantle sequence formed in a suprasubduction zone.