Southern hemispheric westerlies control the spatial distribution of modern sediments in Laguna Potrok Aike,Argentina

We studied the internal lake processes that control the spatial distribution and characteristics of modern sediments at the ICDP (International Continental Scientific Drilling Program) deep drilling site in Laguna Potrok Aike, southern Patagonia, Argentina. Sediment distribution patterns were investigated using a dense grid of 63 gravity cores taken throughout the lake basin and 40 additional shoreline samples. Analysis of the surficial sediment distribution points to distinct internal depositional dynamics induced by wind-driven lake internal currents. Distribution maps illustrate that the spatial characteristics of analysed variables are linked to high erosional wave activity. Persistent wave action and littoral erosion along all shores, especially the eastern shore, is caused by prevailing Southern Hemispheric Westerlies. Several sediment variables (grain size, benthic diatoms, total inorganic carbon and calcium) indicate re-suspension of littoral sediment followed by re-distribution to profundal accumulation areas near the eastern shore. Variations within the catchment influence sediment characteristics in the north-eastern bay. That area is characterized by different mineralogical and sedimentological conditions as well as greater accumulation of pollen, inorganic carbon and diatoms. These findings are related to the influence of episodic inflow into this bay. Spatial differences in stable isotope values throughout the lake suggest that ephemeral tributaries around the lake basin may also contribute to the detected spatial sediment variations.     

Lake Van, Eastern Anatolia, Hydrochemistry and History

Saline, 450-m-deep Lake Van (Eastern Anatolia, Turkey) is, with 576 km³, the third largest closed lake on Earth and its largest soda lake. In 1989 and 1990, we investigated the hydrochemistry of the lake’s water column and of the tributary rivers. We also cored the Postglacial sediment column at various water depths. The sediment is varved throughout, allowing precise dating back to ca. 15 ka BP. Furthermore, lake terrace sediments provided a 606-year-long floating chronology of the Glacial high-stand of the lake dating to 21 cal. ka BP. The sediments were investigated for their general mineralogical composition, important geochemical parameters, and pore water chemistry as well. These data allow reconstructing the history of the lake level that has seen several regressions and transgressions since the high-stand at the end of the Last Glacial Maximum. Today, the lake is very alkaline, highly supersaturated with Ca-carbonate and has a salt content of about 22 g kg^?1. In summer, the warmer epilimnion is diluted with river water and forms a stable surface layer. Depth of winter mixing differs from year to year but during time of investigation the lake was oxygenated down to its bottom. In general, the lake is characterized by an Na–CO₃–Cl–(SO₄)-chemistry that evolved from the continuous loss of calcium as carbonate and magnesium in the form of Mg-silica-rich mineral phases. The Mg cycle is closely related to that of silica which in turn is governed by the production and dissolution of diatoms as the dominant phytoplankton species in Lake Van. In addition to Ca and Mg, a mass balance approach based on the recent lake chemistry and river influx suggests a fractional loss of potassium, sodium, sulfur, and carbon in comparison to chloride in the compositional history of Lake Van. Within the last 3 ka, minor lake level changes seem to control the frequency of deep water renewal, the depth of stratification, and the redox state of the hypolimnion. Former major regressions are marked by Mg-carbonate occurrences in the otherwise Ca-carbonate dominated sediment record. Pore water data suggest that, subsequent to the major regression culminating at 10.7 ka BP, a brine layer formed in the deep basin that existed for about 7 ka. Final overturn of the lake, triggered by the last major regression starting at about 3.5 ka BP, may partly account for the relative depletion in sulfur and carbon due to rapid loss of accumulated gases. An even stronger desiccation phase is proposed for the time span between about 20 and 15 ka BP following the LGM, during which major salts could have been lost by precipitation of Na-carbonates and Na-sulfates.     

Turbulent measurements in the stable atmospheric boundary layer during SHEBA: ten years after

This paper surveys results of the comprehensive turbulent measurements in the stable boundary layer (SBL) made over the Arctic pack ice during the Surface Heat Budget of the Arctic Ocean experiment (SHEBA) in the Beaufort Gyre from October 1997 through September 1998. Turbulent fluxes and mean meteorological data were continuously measured and reported hourly at five levels on a 20-m main SHEBA tower. Eleven months of measurements during SHEBA cover a wide range of stability conditions, from the weakly unstable regime to very stable stratification, and allow studying the SBL in detail. A brief overview of the SBL regimes, the flux-profile relationships, the turbulent Prandtl number, and other parameters obtained during SHEBA is given. The traditional Monin—Obukhov approach, z-less scaling, and gradient-based scaling are evaluated and discussed based on the data from SHEBA.     

Late Holocene tsunami traces on the western and southern coastlines of the Peloponnesus (Greece)

Greece, in particular the western and southern parts close to the subduction zone of the Hellenic Trench, experiences strong earthquakes and subsequent tsunamis. Nevertheless, field evidence of tsunamis from the late Holocene is extremely rare. Our research along the coastlines of the western and southern Peloponnesus resulted in new findings of tsunami impacts in the form of clusters and ridges of large boulders and thick tsunamigenic sand layers encountered in vibracores. Many boulders contained attached marine organisms, which prove that they were transported from the foreshore environment against gravity by extreme wave events. The attached organisms, which have been dated by ¹⁴C-AMS, suggest that historical tsunami events of great energy occurred around 1300 cal AD. A wood fragment found at the base of tsunami deposits in a vibracore from Cape Punta was dated to ~ 250 cal AD.     

Ab initio study of the composition dependence of the pressure-induced spin crossover in perovskite (Mg1 − x,Fex)SiO3

We present ab initio calculations of the zero-temperature iron high- to low-spin crossover in (Mg_1 ? xFe_x)SiO₃ perovskite at pressures relevant to Earth's lower mantle. Equations of state are fit for a range of compositions and used to predict the Fe spin transition pressure and associated changes in volume and bulk modulus. We predict a dramatic decrease in transition pressure as Fe concentration increases. This trend is contrary to that seen in ferropericlase, and suggests the energetics for spin crossover is highly dependent on the structural environment of Fe. Both Local Density Approximation (LDA) and Generalized Gradient Approximation (GGA) exchange-correlation methods are used, and both methods reproduce the same compositional trends. However, GGA gives a significantly higher transition pressure than LDA. The spin transition is made easier by the decreasing spin-flip energy with pressure but is also driven by the change in volume from high to low spin. Volume trends show that high-spin Fe²⁺ is larger than Mg²⁺ even under pressure, but low-spin Fe²⁺ is smaller at ambient conditions and approximately the same size as Mg²⁺ under high pressure, indicating that low-spin Fe²⁺ is less compressible than high-spin Fe²⁺. We find large changes between high- and low-spin in the slope of volume with Fe concentration. Although these changes are small in absolute magnitude for small Fe content, they are still important when measured per Fe and could be relevant for calculating partitioning coefficients in the lower mantle.     

A 20 ka sediment record from the Hajar Mountain range in N-Oman,and its implication for detecting arid–humid periods on the southeastern Arabian Peninsula

Playa-like sediments from the Hajar Mountain range in northern Oman (22.83°N, 59.00°E; 1050 m asl) document variations of the paleoenvironmental and paleoclimate conditions over the last 20 ka. Based on high-resolution sediment sampling and their OSL dating, sedimentation rates were calculated and used as a proxy for paleorainfall. The results show that the Glacial to Lateglacial was characterized by arid conditions with a following transitional period of even less rainfall. At 10.5 ka, sedimentation rates increases abruptly, indicating the onset of the early Holocene humid period (EHHP). Rainfall reaches its maximum at 9–8 ka (EHHP-2) and a decreasing sedimentation rate after 8 ka characterizes the arid period of the middle to late Holocene. Variations of the hydrological regime are associated with the intensity of the boreal summer Indian monsoon and its related position of the ITCZ. For the onset of the EHHP, a northerly shift of the ITCZ is postulated, thus confirming earlier results from the southern Arabian Peninsula.     

Spectral study of the Eunomia asteroid family : I. Eunomia

We present color ratio curves of the S-Asteroid 15 Eunomia, which have been extracted from high-precision photometric lightcurves obtained in three different VNIR wavelength bands at the Bochum Telescope, La Silla. The measured color ratio curves and near infrared spectra were used to derive a detailed surface composition model whose shape has been computed by V-lightcurve inversions. According to this analysis, the asteroid shows on one hemisphere a higher concentration of pyroxene, which causes an increased 440/700 nm and a reduced 940/700 nm reflectance ratio as well as a pronounced 2-μm absorption band. The remaining surface shows a higher concentration of olivine, leading to a reduced 440/700 nm and slightly increased 940/700 nm color ratio. In addition, we found that the maximum of the 440/700 nm color ratio curve coincide with the minimum of the 940/700 nm color ratio curve and vice versa. We demonstrate on the basis of USGS laboratory spectra that this anti-cyclical behavior can be explained by choosing Fe-rich olivine and a pyroxene with moderate Fe content as varying mineral phases. Furthermore, our observations confirm that 15 Eunomia is an irregular elongated and at least partially differentiated body. Previous spectral investigations of several smaller fragments of the Eunomia asteroid family revealed that the amount of fragments showing an increased pyroxene content exceeds the amount of pyroxene-poor fragments (Nathues, 2000, DLR Forschungsbericht, ISSN 1434-8454). This finding together with the observation that the major fraction of Eunomia's surface is enriched in olivine let us claim that a large fraction of the original pyroxene-enriched crust layer has been lost due to a major collision that created the Eunomia asteroid family. Significant spectral evidences, consistent with high concentrations of metals have been found neither in the rotational resolved spectra of 15 Eunomia nor in its fragments. This led to the conclusion that either no core consisting mainly of metals exists or that an eventual one has not been unearthed by the impact.