A photoelectric detector for the measurement of photolysis frequencies of ozone and other atmospheric molecules

Photoelectric detectors for the measurement of photolysis frequencies of different trace gases in the atmosphere are described. They exhibit uniform response characteristics over one hemisphere (2 sr) and wavelength characteristics closely matched to those of the photolysis frequencies J _O1D, J _NO2, and J _NO3, respectively. Absolute calibration of the J _O1D detector was performed by chemical actinometry with an accuracy of ±16 percent. Simultaneous measurements of J _NO2 and J _O1D are presented.     

Extended regional climate model projections for Europe until the mid-twentyfirst century: combining ENSEMBLES and CMIP3

This study aims at sharpening the existing knowledge of expected seasonal mean climate change and its uncertainty over Europe for the two key climate variables air temperature and precipitation amount until the mid-twentyfirst century. For this purpose, we assess and compensate the global climate model (GCM) sampling bias of the ENSEMBLES regional climate model (RCM) projections by combining them with the full set of the CMIP3 GCM ensemble. We first apply a cross-validation in order to assess the skill of different statistical data reconstruction methods in reproducing ensemble mean and standard deviation. We then select the most appropriate reconstruction method in order to fill the missing values of the ENSEMBLES simulation matrix and further extend the matrix by all available CMIP3 GCM simulations forced by the A1B emission scenario. Cross-validation identifies a randomized scaling approach as superior in reconstructing the ensemble spread. Errors in ensemble mean and standard deviation are mostly less than 0.1 K and 1.0 % for air temperature and precipitation amount, respectively. Reconstruction of the missing values reveals that expected seasonal mean climate change of the ENSEMBLES RCM projections is not significantly biased and that the associated uncertainty is not underestimated due to sampling of only a few driving GCMs. In contrast, the spread of the extended simulation matrix is partly significantly lower, sharpening our knowledge about future climate change over Europe by reducing uncertainty in some regions. Furthermore, this study gives substantial weight to recent climate change impact studies based on the ENSEMBLES projections, since it confirms the robustness of the climate forcing of these studies concerning GCM sampling.     

Climatology of Ozone, PAN, CO, and NMHC in the Free Troposphere Over the Southern North Atlantic

Free tropospheric measurements of ozone, peroxyacetylnitrate andprecursors (CO, NMHC) that were made within the framework of the EUROTRACsub-project TOR (Tropospheric Ozone Research) between 1990 and 1995 at theGAW station Izana, Tenerife (28°18N, 16°30W) arediscussed. The average annual cycles reveal the importance of transport fromnorthern mid-latitudes and the role of photo-chemistry. According toair-mass trajectories, which were supplied to us from AEROCE(Atmosphere/Ocean Chemistry Experiment), transport from northernmid-latitudes is associated with high precursor concentrations in winter,whereas ozone concentrations in winter are not much influenced by transportpatterns, suggesting a rather uniform distribution over the northern part ofthe Northern Hemisphere around mean value of 43 ± 5 ppb. In summer,high ozone concentrations of up to 90 ppb are often encountered duringtransport from north, while the levels of precursors are much lower than inwinter, because of photochemical destruction. Trajectories from southerlylatitudes and the Sahara usually have the lowest ozone concentrationsassociated with them.     

A theory for the scalar roughness and the scalar transfer coefficients over snow and sea ice

Although the bulk aerodynamic transfer coefficients for sensible (C _H ) and latent (C _E ) heat over snow and sea ice surfaces are necessary for accurately modeling the surface energy budget, they have been measured rarely. This paper, therefore, presents a theoretical model that predicts neutral-stability values of C _H and C _E as functions of the wind speed and a surface roughness parameter. The crux of the model is establishing the interfacial sublayer profiles of the scalars, temperature and water vapor, over aerodynamically smooth and rough surfaces on the basis of a surface-renewal model in which turbulent eddies continually scour the surface, transferring scalar contaminants across the interface by molecular diffusion. Matching these interfacial sublayer profiles with the semi-logarithmic inertial sublayer profiles yields the roughness lengths for temperature and water vapor. When coupled with a model for the drag coefficient over snow and sea ice based on actual measurements, these roughness lengths lead to the transfer coefficients. C _E is always a few percent larger than CH. Both decrease monotonically with increasing wind speed for speeds above 1 m s^–1, and both increase at all wind speeds as the surface gets rougher. Both, nevertheless, are almost always between 1.0 × 10^–3 and 1.5 × 10^–3.     

Performance of the Nuclear Compton Telescope

On 1 June 2005, the prototype Nuclear Compton Telescope (NCT) flew on a high altitude balloon from Fort Sumner, New Mexico. NCT is a balloon-borne soft γ-ray (0.2–10 MeV) telescope for studying astrophysical sources of nuclear line emission and γ-ray polarization. Our program is designed to develop and test technologies and analysis techniques crucial for the Advanced Compton Telescope; however, our detector design and configuration is also well matched to the focal plane requirements for focusing Laue lenses. The NCT prototype utilizes two, 3D imaging germanium detectors (GeDs) in a novel, ultra-compact design optimized for nuclear line emission in the 0.5–2 MeV range. Our prototype flight provides a critical test of the novel detector technologies, analysis techniques, and background rejection procedures developed for high resolution Compton telescopes.     

Great Microwave Bursts and hard X-rays from solar flares

The microwave and hard X-ray characteristics of 13 solar flares that produced microwave fluxes greater than 500 solar flux units have been analyzed. These Great Microwave Bursts were observed in the frequency range from 3 to 35 GHz at Bern, and simultaneous hard X-ray observations were made in the energy range from 30 to 500 keV with the Hard X-Ray Burst Spectrometer on the Solar Maximum Mission spacecraft. The principal aim of this analysis is to determine whether or not the same distribution of energetic electrons can explain both emissions. The temporal and spectral behaviors of the microwaves as a function of frequency and the X-rays as a function of energy were tested for correlations, with results suggesting that optically thick microwave emission, at a frequency near the peak frequency, originates in the same electron population that produces the hard X-rays. The microwave emission at lower frequencies, however, is poorly correlated with emission at the frequency which appears to characterize this common source. A single-temperature and a multitemperature model were tested for consistency with the coincident X-ray and microwave spectra at microwave burst maximum. Four events are inconsistent with both of the models tested, and neither of the models attempts to explain the high-frequency part of the microwave spectrum. A source area derived on the basis of the single-temperature model agrees to within the uncertainties with the observed area of the one burst for which spatially resolved X-ray images are available.Swiss National Science Foundation Fellow from the University of Bern.Also Energy/Environmental Research Group, Incorporated, Tucson, Arizona, and Department of Physics and Astronomy, University of North Carolina, Chapel Hill. Present address: Johns Hopkins University Applied Physics Laboratory, Laurel, Maryland.     

Hydrogen incorporation in enstatite in the system MgO–SiO2–H2O–NaCl

The incorporation of hydrogen in enstatite in a hydrous system containing various amounts of NaCl was investigated at 25 kbar. The hydrogen content in enstatite shows a clear negative correlation to the NaCl-concentration in the system. The most favourable explanation is the reduction of water fugacity due to dilution. Other reasons for the limited hydrogen incorporation at high NaCl levels, such as a significant influence of Na⁺ on the defect chemistry or an exchange between OH^- and Cl⁻in enstatite, appear much less important. A partition coefficient D _Na ^En/Fluid = 0.0013 could be determined, demonstrating that Na is less incompatible in enstatite than H. The new results support the idea that dissolved components have to be considered when the total hydrogen storage capacity in nominally anhydrous minerals is estimated, especially in geological settings with high levels of halogens, such as subduction zones.     

Self-diffusion of water and its dependence on temperature and ionic strength in highly compacted montmorillonite, illite and kaolinite

The effect of temperature and ionic strength on the diffusion of HTO parallel to the direction of compaction through 5 highly compacted clay minerals (bulk dry density, ρ_b,d = 1.90 ± 0.05 Mg/m³), namely montmorillonite (Na- and Ca-form), illite (Na- and Ca-form), and kaolinite, was studied. The diffusion experiments were carried out at temperatures between 0 °C and 60 °C and at ionic strengths of 0.01 M and 1 M NaCl for the Na-form clays and kaolinite, and of 0.005 M and 0.5 M CaCl₂ for the Ca-form. The ionic strength had an insignificant influence on the values of the effective diffusion coefficient (variation by less than 10%) for the clays under study at this degree of compaction. The effective diffusion coefficients followed the order Na-montmorillonite < Ca-montmorillonite < Ca-illite < Na-illite  kaolinite. It is thought that the differences between Na- and Ca-montmorillonite originate from the larger size particles, and thus the lower tortuosity of the latter; whereas the differences between Na- and Ca-illite are related to the different degree of solvation of the Na and Ca cations. The activation energies were successfully calculated using the Arrhenius law. Swelling clays (Na- and Ca-montmorillonite) had slightly larger activation energy values (20 kJ/mol) compared to bulk water (17 kJ/mol); Ca-illite (16 kJ/mol), Na-illite (13 kJ/mol) and kaolinite (14.4 kJ/mol) lower values than that of bulk water. The low activation energies of the last three clays may be related to weaker H-bonds between water and the clay surfaces compared to those in bulk water.