GPCC's new land surface precipitation climatology based on quality-controlled in situ data and its role in quantifying the global water cycle

In 1989, the need for reliable gridded land surface precipitation data sets, in view of the large uncertainties in the assessment of the global energy and water cycle, has led to the establishment of the Global Precipitation Climatology Centre (GPCC) at Deutscher Wetterdienst on invitation of the WMO. The GPCC has calculated a precipitation climatology for the global land areas for the target period 1951–2000 by objective analysis of climatological normals of about 67,200 rain gauge stations from its data base. GPCC's new precipitation climatology is compared to several other station-based precipitation climatologies as well as to precipitation climatologies derived from the GPCP V2.2 data set and from ECMWF's model reanalyses ERA-40 and ERA-Interim. Finally, how GPCC's best estimate for terrestrial mean precipitation derived from the precipitation climatology of 786 mm per year (equivalent to a water transport of 117,000 km³) is fitting into the global water cycle context is discussed.     

Effect of KCl on melting in the Mg<Subscript>2</Subscript>SiO<Subscript>4</Subscript>–MgSiO<Subscript>3</Subscript>–H<Subscript>2</Subscript>O system at 5 GPa

To examine the effect of KCl-bearing fluids on the melting behavior of the Earth’s mantle, we conducted experiments in the Mg₂SiO₄–MgSiO₃–H₂O and Mg₂SiO₄–MgSiO₃–KCl–H₂O systems at 5 GPa. In the Mg₂SiO₄–MgSiO₃–H₂O system, the temperature of the fluid-saturated solidus is bracketed between 1,200–1,250°C, and both forsterite and enstatite coexist with the liquid under supersolidus conditions. In the Mg₂SiO₄–MgSiO₃–KCl–H₂O systems with molar Cl/(Cl + H₂O) ratios of 0.2, 0.4, and 0.6, the temperatures of the fluid-saturated solidus are bracketed between 1,400–1,450°C, 1,550–1,600°C, and 1,600–1,650°C, respectively, and only forsterite coexists with liquid under supersolidus conditions. This increase in the temperature of the solidus demonstrates the significant effect of KCl on reducing the activity of H₂O in the fluid in the Mg₂SiO₄–MgSiO₃–H₂O system. The change in the melting residues indicates that the incongruent melting of enstatite (enstatite = forsterite + silica-rich melt) could extend to pressures above 5 GPa in KCl-bearing systems, in contrast to the behavior in the KCl-free system.     

Blood metal levels and metal-influenced immune functions of harbour seals in captivity

Immunological blood parameters and the effects of environmental pollutants on the immune system are important to assess the health status of seals. Animals living permanently in seal centres are useful for development and validation of diagnostic tools for free-ranging animals. In this study, parameters of cellular immunity as well as metal concentrations in blood and metal influence on cell proliferation of seven seals from a seal centre were investigated repeatedly using multi-element analysis and a lymphocyte proliferation assay. The metal concentrations, except for tin and chromium, were in general comparable to those of free-ranging animals of the North Sea. The unstimulated and mitogen-stimulated lymphocyte proliferation showed strong intra- and inter-individual variability, which reflected variability in activation of the immune status. Furthermore, both immunosuppressive and stimulative influences of metals on lymphocytes were found. Summarising, the methods used in this investigation provided useful information on these animals, and their application to free-ranging animals can be recommended.     

Wet Fault or Dry Fault? A Laboratory Approach to Remotely Monitor the Hydro-Mechanical State of a Discontinuity Using Controlled-Source Seismics

Stress variation and fluid migration occur in deformation zones, which are expected to affect seismic waves reflected off or propagating across such structures. We developed a basic experimental approach to monitor the mechanical coupling with respect to seismic coupling across a single discontinuity between a granite sample in contact with a steel platen. Piezoceramics located on the platen were used to both generate and record the P and S wave fields reflected off the discontinuity at normal incidence. This way, normal (B _n ) and tangential (B _t ) compliances were calculated using Schoenberg’s linear slip theory (Schoenberg, J Acoust Soc Am 68:1516–1521, 1980) when the roughness, the effective pressure (P _eff, up to 200 MPa), and the nature of the filling (gas or water) vary. We observe that increasing the effective pressure decreases B _n and B _t , which is interpreted as the effect of the closure of the voids at the interface, permitting more seismic energy to be transmitted across the interface. Values of B _n are significantly higher than those of B _t at low P _eff (<60–80 MPa) in dry conditions, and significantly drop under water-saturated conditions. The water filling the voids therefore helps to transmit the seismic energy of compressional waves across the interface. These results show that the assumption B _n  ≈ B _t commonly found in some theoretical approaches does not always stand. The ratio B _n /B _t actually reflects the type of saturating fluids and the effective pressure, in agreement with other experimental studies. However, we illustrate that only the relative variations of this ratio seem to be relevant, not its absolute value as suggested in previous studies. Consequently, the use of B _n against B _t plots may allow effective pressure variation and the nature of the pore fluid to be inferred. In this respect, this experimental approach at sample scale helps to pave the way for remotely monitoring in the field the hydro-mechanical state of deformation zones, such as seismogenic faults, fractured reservoirs, or lava conduits.     

Multi-metal contaminant dynamics in temporarily flooded soil under sulfate limitation

In many river basins, floodplain soils have accumulated a variety of metal contaminants, which might be released during periods of flooding. We investigated the dynamics of copper, cadmium, lead, zinc, and nickel in a contaminated freshwater floodplain soil under a realistic sulfate-limited flooding regime in microcosm experiments. We found that most contaminants were initially mobilized by processes driven by the reductive dissolution of Fe(III) and Mn(IV, III) (hydr)oxides. Subsequently, bacterial sulfate respiration resulted in the transformation of the entire available sulfate (2.3 mmol/kg) into chromous reducible sulfur (CRS). Cu K-edge X-ray absorption fine structure (XAFS) spectroscopy revealed that the soil Cu speciation changed from predominantly Cu(II) bound to soil organic matter (SOM) intermittently to 14% metallic Cu(0) and subsequently to 66% copper sulfide (Cu_xS). These Cu_xS precipitates accounted for most of the formed CRS, suggesting that Cu_xS was the dominant sulfide phase formed in the flooded soil. Sequential metal extractions, in agreement with CRS results, suggested that easily mobilizable Cd was completely and Pb partially sequestered in sulfide precipitates, controlling their dissolved concentrations to below detection limits. In contrast, Zn and Ni (as well as Fe) were hardly sequestered into sulfide phases, so that micromolar levels of dissolved Zn and Ni (and millimolar dissolved Fe(II)) persisted in the reduced soil. The finding that Cu, Cd, and Pb were sequestered (but hardly any Zn, Ni, and Fe) is consistent with the thermodynamically predicted sulfide ladder following the increasing solubility products of the respective metal sulfides. The observation that Cd and Pb were sequestered in sulfides despite the presence of remaining SOM-bound Cu(II) suggested that the kinetics of Cu(II) desorption, diffusion, and/or Cu_xS precipitation interfered with the sulfide ladder. We conclude that the dynamics of multiple metal contaminants are intimately coupled under sulfate limitation by the relative thermodynamic stabilities and formation kinetics of the respective metal sulfides.     

Development of a seismic damage and loss scenario for contemporary and historical buildings in Thessaloniki, Greece

The methodologies used in Greece for estimating direct losses in both reinforced concrete (R/C) and masonry buildings (also including monuments) are summarised, the critical issue of data collection is addressed, and practical solutions that have been tried are discussed. The development of a seismic risk scenario for contemporary and historical buildings in Thessaloniki is then presented and some key results are given, including the expected geographical distribution of building damage (due to the scenario earthquake) in the municipality of Thessaloniki; damage is described both in structural and in economic terms.     

Seismic damage analysis including inelastic shear–flexure interaction

The paper focusses on seismic damage analysis of reinforced concrete (R/C) members, accounting for shear–flexure interaction in the inelastic range. A finite element of the beam-column type recently proposed by the writers for the seismic analysis of R/C structures is first briefly described. The analytical model consists of two distributed flexibility sub-elements which interact throughout the analysis to simulate inelastic flexural and shear response. The finite element accounts for shear strength degradation with inelastic curvature demand, as well as coupling between inelastic flexural and shear deformations after flexural yielding. Based on this model, a seismic damage index is proposed taking into account both inelastic flexural and shear deformations, as well as their interaction. The finite element and the seismic damage index are used to analyse the response of R/C columns tested under cyclic loading and failing either in shear or in flexure. It is shown that the analytical model and damage index can predict and describe well the hysteretic response of R/C columns with different types of failure.     

Transport of salt and freshwater in the Atlantic Subpolar Gyre

Transport of salt in the Irminger Current, the northern branch of the Atlantic Subpolar Gyre coupling the eastern and western subpolar North Atlantic, plays an important role for climate variability across a wide range of time scales. High-resolution ocean modeling and observations indicate that salinities in the eastern subpolar North Atlantic decrease with enhanced circulation of the North Atlantic subpolar gyre (SPG). This has led to the perception that a stronger SPG also transports less salt westward. In this study, we analyze a regional ocean model and a comprehensive global coupled climate model, and show that a stronger SPG transports more salt in the Irminger Current irrespective of lower salinities in its source region. The additional salt converges in the Labrador Sea and the Irminger Basin by eddy transports, increases surface salinity in the western SPG, and favors more intense deep convection. This is part of a positive feedback mechanism with potentially large implications for climate variability and predictability.     

GETEMME—a mission to explore the Martian satellites and the fundamentals of solar system physics

GETEMME (Gravity, Einstein??s Theory, and Exploration of the Martian Moons?? Environment), a mission which is being proposed in ESA??s Cosmic Vision program, shall be launched for Mars on a Soyuz Fregat in 2020. The spacecraft will initially rendezvous with Phobos and Deimos in order to carry out a comprehensive mapping and characterization of the two satellites and to deploy passive Laser retro-reflectors on their surfaces. In the second stage of the mission, the spacecraft will be transferred into a lower 1500-km Mars orbit, to carry out routine Laser range measurements to the reflectors on Phobos and Deimos. Also, asynchronous two-way Laser ranging measurements between the spacecraft and stations of the ILRS (International Laser Ranging Service) on Earth are foreseen. An onboard accelerometer will ensure a high accuracy for the spacecraft orbit determination. The inversion of all range and accelerometer data will allow us to determine or improve dramatically on a host of dynamic parameters of the Martian satellite system. From the complex motion and rotation of Phobos and Deimos we will obtain clues on internal structures and the origins of the satellites. Also, crucial data on the time-varying gravity field of Mars related to climate variation and internal structure will be obtained. Ranging measurements will also be essential to improve on several parameters in fundamental physics, such as the Post-Newtonian parameter ?? as well as time-rate changes of the gravitational constant and the Lense-Thirring effect. Measurements by GETEMME will firmly embed Mars and its satellites into the Solar System reference frame.