Fluoride Biomonitoring around a Large Aluminium Smelter Using Foliage from Different Tree Species

In order to study the pollution gradient in the vicinity of a large aluminium production facility in Patagonia (Argentina), a passive biomonitoring was performed employing foliage from three tree species. Primary scope was to identify pollution gradients and to select suitable tree species which can be used as biomonitor plants in the study area. Therefore, leaves of Eucalyptus rostrata, Populus hybridus and different needle ages of Pinus radiata were collected at different distances from the industry and the fluoride concentration was analysed in washed and unwashed samples in order to determine the amount of external fluoride. Washing reduced the F‐concentrations by 24, 39 and 51% on average in E. rostrata, P. hybridus and P. radiata, respectively, indicating that species‐specific characteristics determine the accumulation and wash‐off of dust‐associated fluorine. F‐concentrations varied from 6 to 3652 ppm F in unwashed samples indicating a steep pollution gradient in the study area. The influence of F‐emissions was discernible in all samples up to a distance of 3500 m from the smelter. E. rostrata accumulated more fluorine than the other species at equal distance from the emission source. The present study confirms that aluminium smelting results in high F deposition in the study area. Establishing a biomonitor network around large emitters is suitable and feasible to evaluate the efficiency of air control measures.     

A deformation-based seismic design method for 3D R/C irregular buildings using inelastic dynamic analysis

A new deformation-based design method concerning 3D reinforced concrete (R/C) buildings is presented, which involves the use of advanced analysis tools, i.e. response-history analysis for appropriately scaled input motions, for multiple levels of earthquake action. The critical issues concerning the inelastic response-history analysis used for the design, namely the definition of the appropriate input, the set up of the analytical model that should account for post-yield behaviour of plastic hinge zones, and the direction of loading, are discussed. The proposed method is based on a partially inelastic model, while the design of structural members is carried out for different performance levels related to their inelastic behaviour. The aforementioned method builds on previous proposals by the first author and his co-workers, nevertheless a new procedure for the design of members that are expected to develop inelastic behaviour for the serviceability earthquake is proposed; its aim is the reduction of member design forces and the a-priori definition of their inelastic performance, by exploiting the deformation limits for the specific performance level, which are related to the damage level of the structural members. The proposed method was applied to irregular multistorey R/C 3D frame buildings with setbacks, and their performance for several levels of earthquake action was assessed using a fully inelastic model and additional ground motions not used at the design phase. The same buildings were designed according to the provisions of Eurocode 8. Comparison of the two methods of seismic design, revealed the advantages of the proposed design method, in particular the more economic detailing of transverse reinforcement in the members that develop very little inelastic behaviour even for very strong earthquakes.     

Chondritic Mg isotope composition of the Earth

The processes of planetary accretion and differentiation have potentially been recorded as variations in the stable isotope ratios of the major elements between planetary objects. However, the magnitude of observed isotopic variations for several elements (Mg, Fe, Si) is at the limit of what current analytical precision and accuracy are able to resolve. Here, we present a comprehensive data set of Mg isotope ratios measured in ocean island and mid-ocean ridge basalts, peridotites and chondrites. The precision and accuracy were verified by isotopic standard addition for two samples, one carbonaceous chondrite (Murchison) and one continental flood basalt (BCR-1). In contrast with some previous studies, our data from terrestrial and chondritic materials have invariant Mg isotope ratios within the uncertainty of the method (0.1‰ for the ²⁶Mg/²⁴Mg ratio, 2SD). Although isotopic variations of less than about 0.1‰ could still be present, the data demonstrate that, at this level of uncertainty, the bulk silicate Earth and chondritic Mg reservoir have a homogeneous δ²⁶Mg = −0.23‰ (²⁶Mg/²⁴Mg ratio of the sample relative to the DSM3 standard set to zero by definition). This implies that neither planetary accretion processes nor partial mantle melting and subsequent shallow-level differentiation have fractionated Mg isotope ratios. These observations imply in particular that the formation of the Earth cannot stem from preferential sorting of chondrite constituents that would have been fractionated in their Mg isotope composition. It also implies that unlike oxygen isotopes, there was no zonation in Mg isotopes in the inner solar system.     

Compactional behavior of fine-grained sediments — examples from Deep Sea Drilling Project cores

Laboratory experiments, statistical analysis of field data and theoretical models are combined in the attempt to derive standard compaction curves for various deep-sea sediments which are in compaction equilibrium with the overburden. A revised and generalized version of Athy's law together with laboratory experiments allows the classification of sediments in terms of the amount of porewater structurally bound to the particles' surfaces. Especially suction pressure experiments are useful in quantifying the forces that bind water on the particle surfaces. The sediments analyzed almost range from systems of »suspended grains« to nearly perfect »colloidal systems«. The methods and equations required to derive the relevant parameters are given for both, downhole porosity/density measurements and laboratory experiments.

---

Zusammenfassung Die Synthese experimenteller Labordaten, statistischer Analysen von Messungen an Kernen und theoretischer Modellierung der Kompaktion im Gleichgewicht mit der Auflast ermöglicht die Definition von Typ-Kurven für das Kompaktionsverhalten von verschiedenen Tiefsee-Sedimenten. Eine erweiterte und verbesserte Form der Athy'schen Gleichung erlaubt zusammen mit Laborexperimenten, Sedimente entsprechend des Anteils an strukturell gebundenem Porenwasser zu klassifizieren. Anhand von Saugspannungsexperimenten können die Bindungskräfte zwischen Wasser und Partikeloberflächen abgeschätzt werden. Die untersuchten Sedimente reichen von »suspendierten Körnern« bis zu einem »kolloidalen System«. Die notwendigen Methoden und Gleichungen zur Bestimmung der relevanten Parameter aus Bohrlochdaten und Laborexperimenten werden diskutiert.

---

Résumé A partir d'une synthèse de résultats d'expériences de laboratoires, d'analyses statistiques de données de terrain et d'une modélisation théorique, il est possible d'établir des courbes standard du processus de compaction pour divers types de sédiments de mer profonde, pour lesquels la compaction est en équilibre avec la charge. Une version revue et généralisée de la loi d'Athy permet, en accord avec les résultats expérimentaux, de classer les sédiments selon la quantité d'eau intersticielle liée structuralement à la surface des particules. Les sédiments analysés correspondent à des systèmes qui vont du type à «grains suspendus» à des colloïdes presque parfaits. Les auteurs présentent une discussion détaillée des méthodes et des équations néssaires à l'obtention des paramètres significatifs tant à partir des expériences de laboratoire qu'à partir des mesures de porosité/densité effectuées dans les forages.

---

, , . Athy , , . . . .

     

High resolution time series of lead and zinc in sediments of Lake Constance

Sediments in Lake Constance have been dated by radiometric methods and lamination counting. Investigations into the concentrations of lead and zinc in the sediments were carried out to get detailed information about environmental history. Maximum concentrations were found at the beginning of the 1960's. The lead maximum contamination occurred 3 years before the zinc maximum and has an unidentified source. The use of coal, leaded gasoline or the remobilization within the sediment could be excluded to result in the lead maximum. The fluctuations in zinc contamination could be explained with increasing and decreasing pollution (industry, coal burning, building of sewage plants). The greatest fluctuations of both metals occur during periods of great change in the economic history of Germany.     

Deep structure of the bohemian massif from phase velocities of Rayleigh and Love waves

Summary Phase velocities of Rayleigh and Love waves have been measured between the broadband seismic stations KHC (Kaperské Hory, South Bohemia) and KSP (Ksi, Lower Silesia), a profile that nearly coincides with the Interactional DSS Profile VII. The data for both wave types were separately inverted into models of shear-wave velocity versus depth. Novotný's model KHKS 82[1] for the DSS Profile VII was used as a start model. While the crustal section of Novotný's model is compatible with both of our data sets, our Rayleigh-wave data require smaller shear-wave velocities, on the average by 0.24 km/s, in the top 180 km of the mantle. The average difference between Novotný's model and our Love-wave model in that depth range is only 0.06 km/s. If our identification of the observed Love waves as the fundamental mode is correct, this result indicates the presence of polarization anisotropy in the uppermost mantle.

---

u a mu u a ¶rt; unu uuu mauu (an , a u) u S (, ua uu). u - S nuuum mmmm ¶rt;a¶rt; nu VII . a ¶rt; u mun m¶rt; umua ¶rt;u auumu mu nn mu. am mam¶rt;u a unaa ¶rt; S 82 m[1] ¶rt; nu VII . a am ¶rt;u m aua uu aau au ¶rt;a, ¶rt;a au ¶rt;a ¶rt; mm uu m nn — ¶rt; a 0,24 / 180 uma amuu. ¶rt;a aua ¶rt; ¶rt; m u a ¶rt; ¶rt; a m ¶rt;uanau n¶rt;mam 0,06 /. u aa u¶rt;muuau a¶rt;a a a ¶rt;ama ¶rt;a m nau, m mm mam u¶rt;ummm numuu nuau aumnuu amuu.

     

Beitrag zur Gliederung des Präkambriums in Minas Gerais

Zusammenfassung Aufnahmen im Kristallin südostwärts und südlich der EsphinhaÇo-Zone, ausgedehnt bis an die Südgrenze des Staates Minas Gerais, ergaben eine neue stratigraphische und tektonische Gliederung. Große Gebiete, die bisher als tiefstes Archaikum galten, erhielten ihre metamorphe Überprägung erst in der assyntischen Phase. Auch die vormetamorphe sedimentäre Substanz ist weithin algonkischen, wahrscheinlich neo-algonkischen Alters. Im Inneren besitzen diese Sedimente nur schwache epizonale Metamorphose und erlauben weitgehende stratigraphische Gliederung (Formationen Tiradentes, Carandaí, Barroso, Prados). Sie sind Überwiegend klastisch. Küstenwärts folgen die sedimentär-lithologisch gleichen, aber stärker (mesozonal) metamorphe Andrelandia-Serie und die katazonalen Juiz de Fora- bzw. Paraíba-Serien (Metamorphose charnockitisch bzw. mikroklingranitisch). Die Küstenzone stellt daher eine kristalline Zentralzone dar, von der aus die Bewegungen binnenwärts gerichtet sind. An der Westgrenze des Arbeitsgebietes erfolgt eine Virgation der Faltenzüge in Araxaiden und Paraibiden. Das ordovizische Alter der Füllung des Beckens des Rio SÃo Francisco (Bambuí) ist zu bezweifeln. Die EsphinhaÇo-Zone ist algomisch konsolidiert, die alt-algonkische Minas-Serie auf diese Zone beschränkt. Sie bildet, zusammen mit dem Bambuí-Becken, das Vorland der assyntischen Faltenzüge. Eine Aufgliederung des Archaikums ist begonnen; im bisher untersuchten Gebiet sind die archäischen Strukturen co-axial den jüngeren.     

Manifestation and measurement of the fractal characteristics of karst hydrogeological formations

A new method of estimating the fractal dimension of the percolation backbone of karst systems, which are discharged through karst springs, is presented. This method is based on the simulation of the spring by the MODKARST deterministic mathematical model. Application has been made to the Psiloritis karst formation in Crete, which feeds the periodically brackish karst spring “Almiros” in Crete. Furthermore, the estimated dimension justifies an independently determined power law that quantifies the sea intrusion into the karst system.     

The effect of mountainous topography on moisture exchange between the “surface” and the free atmosphere

Typical numerical weather and climate prediction models apply parameterizations to describe the subgrid-scale exchange of moisture, heat and momentum between the surface and the free atmosphere. To a large degree, the underlying assumptions are based on empirical knowledge obtained from measurements in the atmospheric boundary layer over flat and homogeneous topography. It is, however, still unclear what happens if the topography is complex and steep. Not only is the applicability of classical turbulence schemes questionable in principle over such terrain, but mountains additionally induce vertical fluxes on the meso-γ scale. Examples are thermally or mechanically driven valley winds, which are neither resolved nor parameterized by climate models but nevertheless contribute to vertical exchange. Attempts to quantify these processes and to evaluate their impact on climate simulations have so far been scarce. Here, results from a case study in the Riviera Valley in southern Switzerland are presented. In previous work, measurements from the MAP-Riviera field campaign have been used to evaluate and configure a high-resolution large-eddy simulation code (ARPS). This model is here applied with a horizontal grid spacing of 350 m to detect and quantify the relevant exchange processes between the valley atmosphere (i.e. the ground “surface” in a coarse model) and the free atmosphere aloft. As an example, vertical export of moisture is evaluated for three fair-weather summer days. The simulations show that moisture exchange with the free atmosphere is indeed no longer governed by turbulent motions alone. Other mechanisms become important, such as mass export due to topographic narrowing or the interaction of thermally driven cross-valley circulations. Under certain atmospheric conditions, these topographical-related mechanisms exceed the “classical” turbulent contributions a coarse model would see by several times. The study shows that conventional subgrid-scale parameterizations can indeed be far off from reality if applied over complex topography, and that large-eddy simulations could provide a helpful tool for their improvement.