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41.
Meng-Dawn Cheng 《Journal of Atmospheric Chemistry》2018,75(1):1-16
Although a large volume of monitoring and computer simulation data exist for global coverage of HF, study of HF in the troposphere is still limited to industry whose primary interest is the safety and risk assessment of HF release because it is a toxic gas. There is very limited information on atmospheric chemistry, emission sources, and the behavior of HF in the environment. We provide a comprehensive review on the atmospheric chemistry of HF, modeling the reactions and transport of HF in the atmosphere, the removal processes in the vertical layer immediately adjacent to the surface (up to approximately 500 m) and recommend research needed to improve our understanding of atmospheric chemistry of HF in the troposphere. The atmospheric chemistry, emissions, and surface boundary layer transport of hydrogen fluoride (HF) are summarized. Although HF is known to be chemically reactive and highly soluble, both factors affect transport and removal in the atmosphere, the chemistry can be ignored when the HF concentration is at a sufficiently low level (e.g., 10 ppmv). At a low concentration, the capability for HF to react in the atmosphere is diminished and therefore the species can be mathematically treated as inert during the transport. At a sufficiently high concentration of HF (e.g., kg/s release rate and thousands of ppm), however, HF can go through a series of rigorous chemical reactions including polymerization, depolymerization, and reaction with water to form molecular complex. As such, the HF species cannot be considered as inert because the reactions could intimately influence the plume’s thermodynamic properties affecting the changes in plume temperature and density. The atmospheric residence time of HF was found to be less than four (4) days, and deposition (i.e., atmosphere to surface transport) is the dominant mechanism that controls the removal of HF and its oligomers from the atmosphere. The literature data on HF dry deposition velocity was relatively high compared to many commonly found atmospheric species such as ozone, sulfur dioxide, nitrogen oxides, etc. The global average of wet deposition velocity of HF was found to be zero based on one literature source. Uptake of HF by rain drops is limited by the acidity of the rain drops, and atmospheric particulate matter contributes negligibly to HF uptake. Finally, given that the reactivity of HF at a high release rate and elevated mole concentration cannot be ignored, it is important to incorporate the reaction chemistry in the near-field dispersion close to the proximity of the release source, and to incorporate the deposition mechanism in the far-field dispersion away from the release source. In other words, a hybrid computational scheme may be needed to address transport and atmospheric chemistry of HF in a range of applications. The model uncertainty will be limited by the precision of boundary layer parameterization and ability to accurately model the atmospheric turbulence. 相似文献
42.
Thomas K. Flesch Lowry A. Harper Raymond L. Desjardins Zhiling Gao Brian P. Crenna 《Boundary-Layer Meteorology》2009,132(1):11-30
Inverse-dispersion calculations can be used to infer atmospheric emission rates through a combination of downwind gas concentrations
and dispersion model predictions. With multiple concentration sensors downwind of a compound source (whose component positions
are known) it is possible to calculate the component emissions. With this in mind, a field experiment was conducted to examine
the feasibility of such multi-source inferences, using four synthetic area sources and eight concentration sensors arranged
in different configurations. Multi-source problems tend to be mathematically ill-conditioned, as expressed by the condition
number κ. In our most successful configuration (average κ = 4.2) the total emissions from all sources were deduced to within 10% on average, while component emissions were deduced
to within 50%. In our least successful configuration (average κ = 91) the total emissions were calculated to within only 50%, and component calculations were highly inaccurate. Our study
indicates that the most accurate multi-source inferences will occur if each sensor is influenced by only a single source.
A “progressive” layout is the next best: one sensor is positioned to “see” only one source, the next sensor is placed to see
the first source and another, a third sensor is placed to see the previous two plus a third, and so on. When it is not possible
to isolate any sources κ is large and the accuracy of a multi-source inference is doubtful. 相似文献
43.
Shovan Lal Chattoraj Santanu Banerjee P. K. Saraswati 《Journal of the Geological Society of India》2009,73(4):567-574
Glauconitic minerals are considered as one of the valuable input parameters in sequence stratigraphic analysis of a basin.
In the present study glauconitic minerals are reported from subtidal green shale facies in the lower part of the Late Paleocene-Early
Eocene Naredi Formation of western Kutch. On the basis of the foraminiferal assemblage the glauconite bearing beds are interpreted
to have formed in a mid shelf depositional settings of an unstable marine conditions. XRD studies confirm the glauconite mineralogy
of the green pellets and provide an estimation of glauconite maturity. Textural attributes of the glauconites confirm their
derivation by different degrees of alteration of precursor feldspar grains. Because of the authigenic origin and autochthonous
nature, these glauconites hold promise for understanding sequence stratigraphy of the Palaeogene succession of the western
Kutch. 相似文献
44.
Lin-gun Liu C.-C. Lin Y. J. Yung T. P. Mernagh T. Irifune 《Physics and Chemistry of Minerals》2009,36(3):143-149
K-lingunite is a high-pressure modification of K-feldspar that possesses the tetragonal hollandite structure. Variations of
the Raman spectra of K-lingunite were studied up to ~31.5 GPa at room temperature, and in the range 79–823 K at atmospheric
pressure. The Raman frequencies of all bands were observed to increase with increasing pressure, and decrease with increasing
temperature for K-lingunite. This behavior is in line with those observed for most of other materials. New sharp Raman bands
appear at pressures greater than 13–15 GPa, suggesting a phase transition in K-lingunite with increasing pressure. The transition
is reversible when pressure was released. The appearance of these new Raman bands may correspond to the phase transition revealed
earlier at around 20 GPa by X-ray diffraction studies. Instead of transforming back to its stable minerals, such as orthoclase,
microcline or sanidine, K-lingunite became amorphous in the temperature range 803–823 K at atmospheric pressure. 相似文献
45.
Nicola Nocilla Aldo Evangelista Anna Scotto di Santolo 《Rock Mechanics and Rock Engineering》2009,42(5):815-833
In recent years, rock fall phenomena in Italy have received considerable attention for risk mitigation through in situ observations
and experimental data. This paper reports the study conducted at Camaldoli Hill, in the urban area of Naples, and at Monte
Pellegrino, Palermo, Italy. The rocks involved are volcanic Neapolitan yellow tuff (NYT) in the former area and dolomitic
limestone in the latter. Both rocks, even though with different strength characteristics, have shown a significant tendency
towards rock fragmentation during run out. This behavior was first investigated by comparing the volumes of removable blocks
on the cliff faces (V
0) and fallen blocks on the slopes (V
f). It was assumed that the ratio V
f/V
0 decreases with the distance (x
f) from the detachment area by an empirical law, which depends on a coefficient α, correlated with the geotechnical properties of the materials involved in the rock fall. Finally, this law was validated
by observation of well-documented natural rock falls (Palermo) and by in situ full-scale tests (Naples). From the engineering
perspective, consideration of fragmentation processes in rock fall modeling provides a means for designing low-cost mitigation
measures. 相似文献
46.
The climate–population relationship has long been conceived. Although the topic has been repeatedly investigated, most of
the related works are Eurocentric or qualitative. Consequently, the relationship between climate and population remains ambiguous.
In this study, fine-grained temperature reconstructions and historical population data sets have been employed to statistically
test a hypothesized relationship between temperature change and population growth (i.e., cooling associated with below average
population growth) in China over the past millennium. The important results were: (1) Long-term temperature change significantly
determined the population growth dynamics of China. However, spatial variation existed, whilst population growth in Central
China was shown to be responsive to both long- and short-term temperature changes; in marginal areas, population growth was
only sensitive to short-term temperature fluctuations. (2) Temporally, the temperature–population relationship was obscured
in some periods, which was attributable to the factors of drought and social buffers. In summary, a temperature–population
relationship was mediated by geographic factors, the aridity threshold, and social factors. Given the upcoming threat posed
by climate change to human societies, this study seeks to improve our knowledge and understanding of the climate–society relationship. 相似文献
47.
María Charco José Fernández Francisco Luzón Kristy F. Tiampo John B. Rundle 《Pure and Applied Geophysics》2007,164(4):865-878
Surface displacements and gravity changes due to volcanic sources are influenced by medium properties. We investigate topographic,
elastic and self-gravitation interaction in order to outline the major factors that are significant in data modelling. While
elastic-gravitational models can provide a suitable approximation to problems of volcanic loading in areas where topographic
relief is negligible, for prominent volcanoes the rough topography could affect deformation and gravity changes to a greater
extent than self-gravitation. This fact requires the selection, depending on local relief, of a suitable model for use in
the interpretation of surface precursors of volcanic activity. We use the three-dimensional Indirect Boundary Element Method
to examine the effects of topography on deformation and gravity changes in models of magma chamber inflation/deflation. Topography
has a significant effect on predicted surface deformation and gravity changes. Both the magnitude and pattern of the geodetic
signals are significantly different compared to half-space solutions. Thus, failure to account for topographic effects in
areas of prominent relief can bias the estimate of volcanic source parameters, since the magnitude and pattern of deformation
and gravity changes depend on such effects. 相似文献
48.
UV attenuation in the cloudy atmosphere 总被引:1,自引:0,他引:1
Jianhui Bai 《Journal of Atmospheric Chemistry》2009,62(3):211-228
Ultraviolet (UV) energy absorption plays a very important role in the Earth–atmosphere system. Based on observational data
for Beijing, we suggest that some atmospheric constituents utilize or transfer UV energy in chemical and photochemical (C&P) reactions, in addition to those which absorb UV energy directly. These constituents are primarily volatile organic compounds
(VOCs) emitted from both vegetative and anthropogenic sources. The total UV energy loss in the cloudy atmosphere for Beijing
in 1990 was 78.9 Wm−2. This attenuation was caused by ozone (48.3 Wm−2), other compounds in the atmosphere (26.6 Wm−2) and a scattering factor (4.0 Wm−2). Our results for a cloudy atmosphere in the Beijing area show that the absorption due to these other compounds occurs largely
through the mediation of water vapor. This fraction of energy loss has not been fully accounted for in previous models. Observations
and previous models results suggest that 1) a cloudy atmosphere absorbs 25∼30 Wm−2 more solar shortwave radiation than models predict; and 2) aerosols can significantly decrease the downward mean UV-visible
radiation and the absorbed solar radiation at the surface by up to 28 and 23 Wm−2, respectively. Thus, quantitative study of UV and visible absorption by atmospheric constituents involved in homogeneous
and heterogeneous C&P reactions is important for atmospheric models. 相似文献
49.
José Luís Argaín Miguel A. C. Teixeira Pedro M. A. Miranda 《Boundary-Layer Meteorology》2017,165(1):145-160
A method is proposed for estimating the surface-layer depth \((z_s)\) and the friction velocity \((u_*)\) as a function of stability (here quantified by the Obukhov length, L) over the complete range of unstable flow regimes. This method extends that developed previously for stable conditions by Argaín et al. (Boundary-Layer Meteorol 130:15–28, 2009), but uses a qualitatively different approach. The method is specifically used to calculate the fractional speed-up \((\varDelta S)\) in flow over a ridge, although it is suitable for more general boundary-layer applications. The behaviour of \(z_s \left( L\right) \) and \(u_*\left( L\right) \) as a function of L is indirectly assessed via calculation of \(\varDelta S\left( L\right) \) using the linear model of Hunt et al. (Q J R Meteorol Soc 29:16–26, 1988) and its comparison with the field measurements reported in Coppin et al. (Boundary-Layer Meteorol 69:173–199, 1994) and with numerical simulations carried out using a non-linear numerical model, FLEX. The behaviour of \(\varDelta S\) estimated from the linear model is clearly improved when \(u_*\) is calculated using the method proposed here, confirming the importance of accounting for the dependences of \(z_s\left( L \right) \) and \(u_*\left( L \right) \) on L to better represent processes in the unstable boundary layer. 相似文献
50.
Juan Huang Yanli Feng Jian Li Bin Xiong Jialiang Feng Sheng Wen Guoying Sheng Jiamo Fu Minghong Wu 《Journal of Atmospheric Chemistry》2008,61(1):1-20
The levels of carbonyl compounds in Shanghai ambient air were measured in five periods from January 2007 to October 2007 (covering
winter, high-air-pollution days, spring, summer and autumn). A total of 114 samples were collected and eighteen carbonyls
were identified. Formaldehyde, acetaldehyde and acetone were the most abundant carbonyls and their mean concentrations of
19.40 ± 12.00, 15.92 ± 12.07 and 11.86 ± 7.04 μg m−3 respectively, in the daytime for five sampling periods. Formaldehyde and acetaldehyde showed similar diurnal profiles with
peak mixing ratios in the morning and early afternoon during the daytime. Their mean concentrations were highest in summer
and lowest in winter. Acetone showed reversed seasonal variation. The high molecular weight (HMW, ≥C5) carbonyls also showed
obvious diurnal variations with higher concentrations in the daytime in summer and autumn, while they were all not detected
in winter. Formaldehyde and acetaldehyde played an important role in removing OH radicals in the atmosphere, but the contribution
of acetone was below 1%. The carbonyls levels in high-air-pollution days were reported. More carbonyl species with higher
concentrations were found in high-air-pollution days than in spring. These carbonyls were transported with other pollutants
from north and northwest in March 27 to April 2, 2007 and then mixed with local sources. Comparing with Beijing and Guangzhou,
the concentrations of formaldehyde and acetaldehyde in Shanghai were the highest, which indicated that the air pollution in
Shanghai was even worse than expected. 相似文献