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91.
Comparison of ladderane phospholipid and core lipids as indicators for anaerobic ammonium oxidation (anammox) in marine sediments 总被引:2,自引:0,他引:2
Andrea Jaeschke Christine Rooks Joanna C. Nicholls Stefan Schouten 《Geochimica et cosmochimica acta》2009,73(7):2077-2088
We investigated anaerobic ammonium oxidation (anammox) in continental shelf and slope sediments of the Irish and Celtic Seas by using anammox specific ladderane biomarker lipids. We used the presence of an intact ladderane phospholipid as a direct indicator for living anammox bacteria, and compared it with the abundance of ladderane core lipids derived from both living and dead bacterial biomass. All investigated sediments contained ladderane core lipids as well as the intact ladderane phospholipid, in agreement with 15N-labeling experiments, which revealed anammox activity at all sites. Ladderane core lipid and intact ladderane phospholipid concentrations were significantly correlated (R2 = 0.957 and 0.464, respectively) with anammox activity over the transect of the continental shelf and slope sediments. In the Irish Sea (50-100 m water depth) highest abundances of the intact ladderane phospholipid were found in the upper 2 cm of the sediment, indicating a zone of active anammox. A sharp decline further down-core suggested a strong decrease in anammox biomass and rapid degradation of the intact lipids. In comparison, ladderane core lipids were 1-2 orders of magnitude higher in concentration than the intact ladderane phospholipid and accumulated as dead cell remnants with depth. In the slope sediments of the Celtic Sea both ladderane core lipids and the intact ladderane phospholipid were found in sediments at water depths ranging from 500 to 2000 m. Here, anammox seemed to be active at greater depths of the sediment (>2 cm). Mean abundances of both intact and core ladderane lipids in whole sediment cores increased downslope, indicating an increasing importance of anammox in deeper slope sediments. 相似文献
92.
Severe weather affecting European transport systems: the identification,classification and frequencies of events 总被引:1,自引:0,他引:1
Andrea Vajda Heikki Tuomenvirta Ilkka Juga Pertti Nurmi Pauli Jokinen Jenni Rauhala 《Natural Hazards》2014,72(1):169-188
Severe weather can have serious repercussions in the transport sector as a whole by increasing the number of accidents, injuries and other damage, as well as leading to highly increased travel times. This study, a component of the EU FP7 Project EWENT, delineates a Europe-wide climatology of adverse and extreme weather events that can be expected to affect the transport network. We first define and classify the relevant severe weather events by investigating the effects of hazardous conditions on different transportation modes and the infrastructure. Consideration is given to individual phenomena such as snowfall, heavy precipitation, heat waves, cold spells, wind gusts; a combined phenomenon, the blizzard, is also considered. The frequency of severe weather events, together with the changes in their spatial extension and intensity, is analyzed based on the E-OBS dataset (1971–2000) and the ERA-Interim reanalysis dataset (1989–2010). Northern Europe and the Alpine region are the areas most impacted by winter extremes, such as snowfall, cold spells and winter storms, the frequency of heavy snowfall. The frequency of hot days is highest in Southern Europe. Severe winds and blizzards are the most common over the Atlantic and along its shores. Although heavy rainfall may affect the whole continent on an annual basis, extreme precipitation events are relative sparse, affecting particularly the Alps and the Atlantic coastline. A European regionalization covering similar impacts on the transport network is performed. 相似文献
93.
Andrea Wolter Doug Stead Brent C. Ward John J. Clague Monica Ghirotti 《Landslides》2016,13(5):1067-1081
Although the 1963 Vajont Slide in Italy has been extensively studied for over 50 years, its regional geological and geomorphological context has been neglected. In this paper, we use field observations and remote sensing data to elucidate the interaction between endogenic and exogenic processes that brought the north slope of Monte Toc to failure. We present the first detailed pre- and post-failure engineering geomorphology maps of the slide area. The maps delineate two main landslide blocks, several sub-blocks, compressional and extensional zones, and secondary failures in the deposit. The maps provide new insights into the kinematics, dynamics and evolution of the slide. Finally, we discuss the origin of Vajont Gorge and a prehistoric failure that occurred at the same location as the 1963 slide. We propose, as part of a newly developed multi-stage landscape evolution sequence, that the prehistoric failure was a deep-seated gravitational slope deformation (sackung) that initiated during deglaciation and continued to slowly move until the catastrophic failure in 1963. We argue that the gorge was created by these deep-seated slow movements. 相似文献
94.
Holocene climate variability in Sicily from a discontinuous stalagmite record and the Mesolithic to Neolithic transition 总被引:2,自引:0,他引:2
Silvia Frisia Andrea Borsato Augusto Mangini Christoph Sptl Giuliana Madonia Ugo Sauro 《Quaternary Research》2006,66(3):388-400
Fabric and stable isotopic composition of a Holocene stalagmite (CR1) from a cave in northern Sicily record changes in paleorainfall in the early Holocene. High δ13C stable isotope values in the calcite deposited from ca. 8500 to ca. 7500 yr ago are interpreted as reflecting periods of high rainfall. The wet phase was interrupted by two periods of multi-century duration characterized by relatively cool and dry winters centered at ca. 8200 and ca. 7500 yr ago, highlighted by low δ13C and δ18O values. A high variability of δ13C values is recorded from ca. 7500 to ca. 6500 yr ago and indicates that the transition from a pluvial early Holocene to the present-day climate conditions was punctuated by decadal-scale periods of relatively dry winters. In northern Sicily, the traditional elements of the Neolithic appear at ca. 7700 yr ago. It is possible that changes in rainfall influenced the passage from hunter-gathering to farming and sheep-herding economies. 相似文献
95.
Exploring the impact of diagenesis on (isotope) geochemical and microstructural alteration features in biogenic aragonite 下载免费PDF全文
Ann‐Christine Ritter Vasileios Mavromatis Martin Dietzel Ola Kwiecien Felix Wiethoff Erika Griesshaber Laura A. Casella Wolfgang W. Schmahl Jennifer Koelen Rolf D. Neuser Albrecht Leis Dieter Buhl Andrea Niedermayr Sebastian F. M. Breitenbach Stefano M. Bernasconi Adrian Immenhauser 《Sedimentology》2017,64(5):1354-1380
For the Quaternary and Neogene, aragonitic biogenic and abiogenic carbonates are frequently exploited as archives of their environment. Conversely, pre‐Neogene aragonite is often diagenetically altered and calcite archives are studied instead. Nevertheless, the exact sequence of diagenetic processes and products is difficult to disclose from naturally altered material. Here, experiments were performed to understand biogenic aragonite alteration processes and products. Shell subsamples of the bivalve Arctica islandica were exposed to hydrothermal alteration. Thermal boundary conditions were set at 100°C, 175°C and 200°C. These comparably high temperatures were chosen to shorten experimental durations. Subsamples were exposed to different 18O‐depleted fluids for durations between two and twenty weeks. Alteration was documented using X‐ray diffraction, cathodoluminescence, fluorescence and scanning electron microscopy, as well as conventional and clumped isotope analyses. Experiments performed at 100°C show redistribution and darkening of organic matter, but lack evidence for diagenetic alteration, except in Δ47 which show the effects of annealing processes. At 175°C, valves undergo significant aragonite to calcite transformation and neomorphism. The δ18O signature supports transformation via dissolution and reprecipitation, but isotopic exchange is limited by fluid migration through the subsamples. Individual growth increments in these subsamples exhibit bright orange luminescence. At 200°C, valves are fully transformed to calcite and exhibit purple‐blue luminescence with orange bands. The δ18O and Δ47 signatures reveal exchange with the aqueous fluid, whereas δ13C remains unaltered in all experiments, indicating a carbonate‐buffered system. Clumped isotope temperatures in high‐temperature experiments show compositions in broad agreement with the measured temperature. Experimentally induced alteration patterns are comparable with individual features present in Pleistocene shells. This study represents a significant step towards sequential analysis of diagenetic features in biogenic aragonites and sheds light on reaction times and threshold limits. The limitations of a study restricted to a single test organism are acknowledged and call for refined follow‐up experiments. 相似文献
96.
Lasse Hjuler Christiansen Andrea Capolei John Bagterp Jørgensen 《Computational Geosciences》2017,21(3):411-426
The uncertainties related to long-term forecasts of oil prices impose significant financial risk on ventures of oil production. To minimize risk, oil companies are inclined to maximize profit over short-term horizons ranging from months to a few years. In contrast, conventional production optimization maximizes long-term profits over horizons that span more than a decade. To address this challenge, the oil literature has introduced short-term versus long-term optimization. Ideally, this problem is solved by a posteriori multi-objective optimization methods that generate an approximation to the Pareto front of optimal short-term and long-term trade-offs. However, such methods rely on a large number of reservoir simulations and scale poorly with the number of objectives subject to optimization. Consequently, the large-scale nature of production optimization severely limits applications to real-life scenarios. More practical alternatives include ad hoc hierarchical switching schemes. As a drawback, such methods lack robustness due to unclear convergence properties and do not naturally generalize to cases of more than two objectives. Also, as this paper shows, the hierarchical formulation may skew the balance between the objectives, leaving an unfulfilled potential to increase profits. To promote efficient and reliable short-term versus long-term optimization, this paper introduces a natural way to characterize desirable Pareto points and proposes a novel least squares (LS) method. Unlike hierarchical approaches, the method is guaranteed to converge to a Pareto optimal point. Also, the LS method is designed to properly balance multiple objectives, independently of Pareto front’s shape. As such, the method poses a practical alternative to a posteriori methods in situations where the frontier is intractable to generate. 相似文献
97.
Darci Rush Andrea Jaeschke Ellen C. Hopmans Stefan Schouten 《Geochimica et cosmochimica acta》2011,75(6):1662-1671
Anammox, the microbial anaerobic oxidation of ammonium by nitrite to produce dinitrogen gas, has been recognized as a key process in both the marine and freshwater nitrogen cycles, and found to be a major sink for fixed inorganic nitrogen in the oceans. Ladderane lipids are unique anammox bacterial membrane lipids that have been used as biomarkers for anammox bacteria in recent and past environmental settings. However, the fate of ladderane lipids during diagenesis is as of yet unknown. In this study, we performed oxic degradation experiments (at 20-100 °C) with anammox bacterial biomass to simulate early diagenetic processes occurring in the water column and at the sediment-water interface. Abundances of C18 and C20 ladderane lipids decreased with increasing temperatures, testifying to their labile nature. The most abundant products formed were ladderane lipids with a shorter alkyl side chain (C14 and C16 ladderane fatty acids), which was unambiguously established using two-dimensional NMR techniques on an isolated C14-[3]-ladderane fatty acid. The most pronounced production of these short-chain lipids was at 40 °C, suggesting that degradation of ladderane lipids was microbially mediated, likely through a β-oxidation pathway. An HPLC-MS/MS method was developed for the detection of these ladderane alteration products in environmental samples and positively tested on various sediments. This showed that the ladderanes formed during degradation experiments also naturally occur in the marine environment. Thus, short-chain ladderane lipids may complement the original longer-chain ladderane lipids as suitable biomarkers for the detection of anammox processes in past depositional environments. 相似文献
98.
Within the framework of a study of the seismicity of the Aniene Valley (Central Italy), we analysed the medieval earthquakes of Subiaco (1216, 1227, 1299), the largest events reported for the area. Our main goal was to investigate some doubtful events reported in earthquake catalogues and, as such, currently utilised for seismic hazard estimates. A careful screening of the oldest available sources and their filiation pattern up to the present pointed out the uncertainty on the date and nature of these phenomena. A multidisciplinary approach based on the joint analysis of archaeological, geomorphologic and historical evidence allowed us to propose new interpretations concerning these events and their significance for the assessment of seismic hazard in the Aniene Valley. The main conclusion is that the dates of the 1216 and 1227 events are fairly unsupported. In particular, the 1216 earthquake could be dated back to between AD 1159 and 1181. 相似文献
99.
The behavior of Gd-DTPA during bank filtration was simulated in a 30 m column filled with Pleistocene sand and flushed by surface water from a lakeside in Berlin, Germany. The surface water is about a 1:1 mixture of river water and effluents from a sewage treatment plant. Throughout 34 days this water was continuously spiked with Gd-DTPA at a level of 60 μg/L. The broad plateau of the Gd-DTPA pulse declined by 15.4% within 34 days by transmetallation. Nine percentage of the total decline is caused by Y and rare earth elements; the remaining part is attributed to Cu2+ which is the most influential metal in surface water. All other metals also contributing to transmetallation are combined with Cu to Cu equivalents because only the rate constant of transmetallation of Cu2+ is known. The analytical results of the column effluents prove the pseudo-first-order kinetics of transmetallation based on reversible sorption of metals by pools in the column sediment and disprove biodegradation at noticeable levels. The mass ratio of water to tracer is <1010. 相似文献
100.
János Kovács Szabolcs Á. Fábián Gábor Varga Karoly Németh Corina Risso Francisco Nullo Gabor Kereszturi Titusz Bugya Szabolcs Á. Fábián Noémi L. Görcs István P. Kovács Bertalan Radvánszky Gabriella Barta Rudolf Musil Alice Ghiselli Marzio Merazzi Andrea Strini Roberto Margutti Michele Mercuriali Rauf Gardashov Daria Gushchina Boris Dewitte Martin Michálek Marián Putiš Christoph A. Hauzenberger Jindřich Šancer Martin Štrejbar Aneta Maleňáková George Migiros George D. Bathrellos Hariklia D. Skilodimou Theodoros Karamousalis 《Central European Journal of Geosciences》2011,3(2):229-229