PCBs in Central Vietnam coastal lagoons: levels and trends in dynamic environments

PCBs were analysed in surficial sediments and selected sediment cores collected between 2002 and 2008 in Central Vietnam coastal lagoons. The aim was to determine contamination levels and trends, and to evaluate the effects of anthropogenic pressures and natural events. Samples were mostly fine-grained with low total PCB concentrations (0.367-44.7 μg kg⁻¹). Atmospheric transport and post depositional processes modify to some degree the fingerprint of PCB inputs to the environment favouring the predominance of 3, 4 and 5 chlorinated congeners. The similarity of congener distributions in contemporary surficial samples also suggests the presence of a unique source over the entire study area, probably connected to mobilisation and long range transports from land-based stocks. The removal of consistent sediment layers is hypothesised based on repeated samplings of the same area. Natural meteorological events (such as typhoons) are suspected to be responsible for these sediment losses.     

2012 Emilia earthquake,Italy: reinforced concrete buildings response

Data of the Italian National Institute of Statistics are collected aimed at characterizing Reinforced Concrete (RC) building stock of the area struck by the 2012 Emilia earthquake (number of storeys, age of construction, structural typology). Damage observations, collected right after the event in reconnaissance reports, are shown and analyzed emphasizing typical weaknesses of RC buildings in the area. The evolution of seismic classification for Emilia region and RC buildings’ main characteristics represent the input data for the assessment of non-structural damage of infilled RC buildings, through a simplified approach (FAST method), based on EMS-98 damage scale. Peak Ground Acceleration (PGA) capacities for the first three damage states of EMS-98 are compared with registered PGA in the epicentral area. Observed damage and damage states evaluated for the PGA of the event, in the epicentral area, are finally compared. The comparison led to a fair agreement between observed and numerical data.     

Linking foraging behavior and diet in a diving seabird

Foraging behavior and diet of breeding seabirds may be analysed simultaneously with the combined use of remote sensing devices and stable isotope analysis. Imperial shag, Phalacrocorax atriceps, breeding at Punta León colony, Argentina, were equipped with global positioning system (GPS) loggers to record foraging trips and blood samples were taken after removal of the devices in order to analyse their nitrogen and carbon stable isotope composition in whole blood and plasma. Whole blood was correlated to plasma isotopic composition for each individual (n = 35), linking diet in the short and medium term. Sexes did not differ in isotopic signatures. The maximum distance reached and the total number of dives that individuals made on two consecutive foraging trips were correlated to their plasma nitrogen isotopic signature. Individuals that went further from the colony and dived fewer times presented more positive signatures, indicative of benthic prey consumption (e.g. Raneya brasiliensis). Diet was predominantly benthic with some individuals incorporating pelagic prey (Engraulis anchoita) and even cephalopods (Octopus tehuelchus). Within breeding pairs (n = 9), different combinations of foraging and prey preferences were observed. Estimated trophic levels of these individuals were similar to those of the same species in other colonies further south along the Patagonian coast.     

An aromatase inhibitor and tamoxifen decrease plasma levels of o,p'-DDT and its metabolites in Nile tilapia (Oreochromis niloticus)

The objective of this study was to determine if tamoxifen or an aromatase inhibitor (4-hydroxyandrostenedione; 4-OHA) affected plasma concentrations of o,p' -DDT and its metabolites, o,p'-DDD and o,p'-DDE, in mature tilapia. Male and female tilapia were injected 6 times intraperitoneally with o,p'-DDT (40 mg/kg) alone or in combination with 4-OHA (2 mg/kg) over a 12 day period. An additional group of male fish was injected with tamoxifen (5 mg/kg) plus o,p'-DDT. At the end of the treatment period, plasma samples were extracted and analyzed by GC/ECD. Females injected only with o,p'-DDT had significantly higher levels of o,p'-DDT compared with males. Interestingly, females and males treated concomitantly with o,p'-DDT and 4-OHA or tamoxifen had significantly lower concentrations of plasma o,p'-DDT (about 50%) compared with fish treated with only o,p'-DDT. These initial results suggest that an interaction between endocrine-active compounds occurs in vivo in tilapia and may involve alterations in metabolism of o,p'-DDT.     

Acoustic core logging in blast-damaged rock

Thill, R.E. and D' Andrea, D. V., 1975. Acoustic core logging in blast-damaged rock. Eng. Geol., 10: 13–36.The Bureau of Mines, in cooperation with the Duval Corp., conducted a blast-fragmentation experiment to determine the feasibility of preparing a porphyry copper-molybdenum deposit for in-situ leaching. The blast was designed with ten 9-inch-diameter blastholes to depths of 110 feet in an equilateral triangle configuration; spacings between blastholes were 15, 20, and 25 ft. One of the major problems in the experiment was in assessing blast damage. Acoustic core-logging equipment and methods were devised and used as one approach in solving this problem. Ultrasonic pulse travel-times were determined in four diametral directions at 2-ft intervals of depth to a final depth of 120 ft in three preblast and six postblast drill cores at the Duval test site. The acoustic logging program provided compressional wave travel-time at 0°, 45°, 90°, and 135° around the core circumference, maximum travel-time difference, mean compressional-wave velocity, and an anisotropy factor. Other acoustic parameters introduced in the analyses were stiffness modulus, seismic quality designation (SQD), and a compensated velocity to account for portions of the core that were nonrecoverable or too highly fractured to permit diametral travel-time measurements.The acoustic parameters all indicated the deterioration in structural quality from the preblast condition, in which the rock already was badly fractured and weathered, to the more highly fractured postblast condition. Because of the highly fragmented, poor structural condition of the rock after blasting, the rock was indicated to be suitable for in-situ leaching, at least at the 20- and 15-ft blasthole spacings, and even in some zones in the rock at the 25-ft blasthole spacing.     

Bromine cycle in subduction zones through in situ Br monitoring in diamond anvil cells

The geochemical partitioning of bromine between hydrous haplogranitic melts, initially enriched with respect to Br and aqueous fluids, has been continuously monitored in situ during decompression. Experiments were carried out in diamond anvil cells from 890 °C to room temperature and from 1.7 GPa to room pressure, typically from high P, T conditions corresponding to total miscibility (presence of a supercritical fluid). Br contents were measured in aqueous fluids, hydrous melts and supercritical fluids. Partition coefficients of bromine were characterized at pressure and temperature between fluids, hydrous melts and/or glasses, as appropriate: D^Br_fluid/melt = (Br)_fluid/(Br)_melt, ranges from 2.18 to 9.2 ± 0.5 for conditions within the ranges 0.66-1.7 GPa, 590-890 °C; and D^Br_fluid/glass = (Br)_fluid/(Br)_glass ranges from 60 to 375 at room conditions. The results suggest that because high pressure melts and fluids are capable of accepting high concentrations of bromine, this element may be efficiently removed from the slab to the mantle source of arc magmas. We show that Br may be highly concentrated in subduction zone magmas and strongly enriched in subduction-related volcanic gases, because its mobility is strongly correlated with that of water during magma degassing. Furthermore, our experimental results suggest that a non negligible part of Br present in the subducted slab may remain in the down-going slab, being transported toward the transition zone. This indicates that the Br cycle in subduction zones is in fact divided in two related but independent parts: (1) a shallower one where recycled Br may leave the slab with a water and silica-bearing “fluid” leading to enriched arc magmas that return Br to the atmosphere. (2) A deeper cycle where Br may be recycled back to the mantle maybe to the transition zone, where it may be present in high pressure water-rich metasomatic fluids.     

Semantic and syntactic interoperability in online processing of big Earth observation data

ABSTRACT

The challenge of enabling syntactic and semantic interoperability for comprehensive and reproducible online processing of big Earth observation (EO) data is still unsolved. Supporting both types of interoperability is one of the requirements to efficiently extract valuable information from the large amount of available multi-temporal gridded data sets. The proposed system wraps world models, (semantic interoperability) into OGC Web Processing Services (syntactic interoperability) for semantic online analyses. World models describe spatio-temporal entities and their relationships in a formal way. The proposed system serves as enabler for (1) technical interoperability using a standardised interface to be used by all types of clients and (2) allowing experts from different domains to develop complex analyses together as collaborative effort. Users are connecting the world models online to the data, which are maintained in a centralised storage as 3D spatio-temporal data cubes. It allows also non-experts to extract valuable information from EO data because data management, low-level interactions or specific software issues can be ignored. We discuss the concept of the proposed system, provide a technical implementation example and describe three use cases for extracting changes from EO images and demonstrate the usability also for non-EO, gridded, multi-temporal data sets (CORINE land cover).     

Changes in Venice Lagoon dynamics due to construction of mobile barriers

The MoSE project (construction of mobile barrier to safeguard the Lagoon of Venice) entails changes to the structure of the lagoon's inlets. This could have consequences for the areas near the inlets and for the dynamics of the lagoon ecosystem as a whole. In order to predict the effects of the proposed alterations on the hydrodynamics of the lagoon, a well-tested hydrodynamic-dispersion model was applied. Simulations were carried out considering both idealised and realistic tide and wind scenarios.     

Comparison of ladderane phospholipid and core lipids as indicators for anaerobic ammonium oxidation (anammox) in marine sediments

We investigated anaerobic ammonium oxidation (anammox) in continental shelf and slope sediments of the Irish and Celtic Seas by using anammox specific ladderane biomarker lipids. We used the presence of an intact ladderane phospholipid as a direct indicator for living anammox bacteria, and compared it with the abundance of ladderane core lipids derived from both living and dead bacterial biomass. All investigated sediments contained ladderane core lipids as well as the intact ladderane phospholipid, in agreement with ¹⁵N-labeling experiments, which revealed anammox activity at all sites. Ladderane core lipid and intact ladderane phospholipid concentrations were significantly correlated (R² = 0.957 and 0.464, respectively) with anammox activity over the transect of the continental shelf and slope sediments. In the Irish Sea (50-100 m water depth) highest abundances of the intact ladderane phospholipid were found in the upper 2 cm of the sediment, indicating a zone of active anammox. A sharp decline further down-core suggested a strong decrease in anammox biomass and rapid degradation of the intact lipids. In comparison, ladderane core lipids were 1-2 orders of magnitude higher in concentration than the intact ladderane phospholipid and accumulated as dead cell remnants with depth. In the slope sediments of the Celtic Sea both ladderane core lipids and the intact ladderane phospholipid were found in sediments at water depths ranging from 500 to 2000 m. Here, anammox seemed to be active at greater depths of the sediment (>2 cm). Mean abundances of both intact and core ladderane lipids in whole sediment cores increased downslope, indicating an increasing importance of anammox in deeper slope sediments.     

Land tenure and REDD+: The good,the bad and the ugly

A number of international donors, national governments and project proponents have begun to lay the groundwork for REDD+, but tenure insecurity – including the potential risks of land grabbing by outsiders and loss of local user rights to forests and forest land – is one of the main reasons that many indigenous and other local peoples have publicly opposed it. Under what conditions is REDD+ a threat to local rights, and under what conditions does it present an opportunity? This article explores these issues based on available data from a global comparative study on REDD+, led by the Center for International Forestry Research, which is studying national policies and processes in 12 countries and 23 REDD+ projects in 6 countries. The article analyses how tenure concerns are being addressed at both national and project level in emerging REDD+ programs. The findings suggest that in most cases REDD+ has clearly provided some new opportunities for securing local tenure rights, but that piecemeal interventions by project proponents at the local level are insufficient in the absence of broader, national programs for land tenure reform. The potential for substantial changes in the status quo appear unlikely, though Brazil – the only one with such a national land tenure reform program – offers useful insights. Land tenure reform – the recognition of customary rights in particular – and a serious commitment to REDD+ both challenge the deep-rooted economic and political interests of ‘business as usual’.