Geochemistry of diffuse low-temperature hydrothermal fluids in the North Fiji basin

Low-temperature (<13°C) diffuse hydrothermal fluids were sampled directly at the seafloor with a specially designed Hydro Bottom Station in the North Fiji Basin and analyzed for gases, major and minor elements, and a large number of trace metals. The fluids were significantly enriched in CO₂, Si, Li, Rb, Cs, Ba, Mn, and several trace metals compared to ambient seawater, had high CH₄ and H₂S concentrations, and had a slightly decreased salinity. Calculated end-member concentrations of the low-temperature fluids show a strong similarity to the neighboring hot vents, implying that the diffuse fluids are hot vent waters diluted by seawater. According to the chemical composition, the sampled fluids derive from vapor-phase fluids produced by subseafloor boiling and phase separation. Compared to hot vents from other regions, Mn, Fe, and other trace metal concentrations are low. Subsurface metal sulfide precipitation during cooling and dilution with seawater has further decreased the dissolved metal contents of the diffuse fluids, thus creating a very favorable environment for the hydrothermal fauna, as indicated by a very low Fe/H₂S ratio. Therefore, the fluids support high bioproductivity but no hydrothermal mineral precipitation. The emanation of the condensed vapor phase appears to have been stable during the past 10 years; however, the occurrence of metal sulfide particles in some fluid and sediment samples and small areas of dead fauna indicate that the hydrothermal system may be evolving toward the emanation of the stored brine phase.     

The Magnuson-Stevens act (1976) and its reauthorizations: Failure or success for the implementation of fishery sustainability and management in the US?

The Magnuson-Stevens Fishery Conservation and Management Act (1976), opened a new era of federal fishery management in the United States. It was enacted primarily to establish a system for conserving and managing fisheries in the new 200-mile (EEZ). The US assumed exclusive authority for managing all fisheries within the EEZ, except for highly migratory species such as tunas and billfishes. Within the framework of the Act, eight Regional Fishery Management Councils (Regional Councils) were created, which are responsible for preparing Fisheries Management Plans (FMPs) in federal waters under their jurisdiction. Each FMP must meet a series of National Standards (NSs) for conservation and management. The Act was reauthorized in 1996 with the passage of the Sustainable Fisheries Act (SFA), which aimed at fine tuning the fishery regulatory apparatus that was established under the original Act. This "fine tuning" involved increased attention to biological concerns, and removal of ambiguities within it. The Act was reauthorized again in 2007, mainly to provide for more clear directives and regulations to end overfishing. After more than thirty years since the Act was passed into law, the debate among conservationists, commercial and recreational fishery representatives, and politicians on the effectiveness of the Act in achieving its purported goals it still continues. Is the Act delivering on its promises? Do NSs reflect the most important priorities for the US fishery resources, conservation and sustainable exploitation? Do the Regional Councils represent all parties that should be involved in the fisheries resources management? The aim of this paper is to provide a critical analysis to answer these questions. This paper begins with a review of the Act and its background, followed by discussion and analysis of the Act's benefits and flaws. Finally, suggestions for the implementation of its structure and future directions in fishery management strategies are made.     

Effect of varying sediment organic carbon content upon the dermal bioavailability and disposition of benzo(a)pyrene in the catfish, Ictalurus punctatus

The dermal absorption of ³H-benzo(a) pyrene (BaP) from sediments of varying organic carbon content was examined in the catfish (Ictalurus punctatus). Test sediments of differing organic carbon concentrations were formulated from natural sediments with the addition of quartz sand to provide organic carbon content of 1.8, 3.7 and 6.1%. Sediments (1.0 g dry wt), spiked with BaP to provide 20.4 μCi at a BaP dose of 75 ng/g, were applied for 6 h to the skin surface (12 cm²) of anesthetized fish. Dermal exposure to BaP in formulated sediments at 6.1, 3.7 and 1.8% resulted in 6-h mass balance bioavailability values of 19.4, 21.9 and 23.2%, respectively. In all treatments, skin in direct contact with sediments had the highest concentration followed by the corresponding muscle layer. Muscle and skin not in direct contact with the labeled sediment had values which averaged 7–580 times lower than the corresponding exposed tissues. Other tissue values ranged from 0.44 pg/g in the heart to 64.21 pg/g in blood. These findings demonstrate appreciable uptake of BaP from surface applied sediments. Within the range examined, varying organic carbon content had a small, but inverse effect upon the dermal bioavailability of BaP.     

Factors influencing the daily behaviour of dissolved gaseous mercury concentration in the Mediterranean Sea

Mercury evasional fluxes from the sea surface into the atmosphere play an important role in the Hg biogeochemical cycle, especially in the Mediterranean basin, which is characterized by the presence of large cinnabar deposits, intense solar radiation and high temperatures for many months of the year. Since the available experimental methodologies to measure mercury flux can be used only in good weather conditions, at present it is necessary to make use of exchange models that require the knowledge of the dissolved gaseous mercury (DGM) concentration in seawater. In this paper, the main factors affecting DGM levels are discussed considering the determination of the DGM daily behaviour in different meteo-marine and weather conditions at coastal and offshore locations of the Mediterranean basin. A fully automatic device for continuous analyses of DGM concentration with a high time resolution was used. Results show that the daily trend of DGM concentration tracks that of the solar radiation intensity, often mapping the movement of the clouds. DGM levels can be decreased by the presence of high winds that increase mercury evasion from the water surface, as well as by the mixing of the surface water layer. The presence of high levels of dissolved organic matter favours the photo-induced reduction of mercury as observed by the measurements performed in a lagoon water.     

Drones as tools for monitoring beach topography changes in the Ligurian Sea (NW Mediterranean)

The aim of this study was to evaluate topographic changes along a stretch of coastline in the Municipality of Borghetto Santo Spirito (Region of Liguria, Italy, north-western Mediterranean) by means of a remotely piloted aircraft system coupled with structure from motion and multi-view stereo techniques. This sector was surveyed three times over 5 months in the fall–winter of 2013–2014 (1 November 2013, 4 December 2013, 17 March 2014) to obtain digital elevation models and orthophotos of the beach. Changes in beach topography associated with storm action and human activities were assessed in terms of gain/loss of sediments and shifting of the wet–dry boundary defining the shoreline. Between the first and second surveys, the study area was hit by two storms (10–11 November 2013 and 21–22 November 2013) with waves approaching from the E–NNE, causing a shoreline retreat which, in some sectors, reached 7 m. Between the second and third surveys, by contrast, four storms (25–27 December 2013, 5–6 January 2014, 17–18 January 2014 and 6–10 February 2014) with waves propagating from the SE produced a general advancement of the shoreline (up to ~5 m) by deposition of sediments along some parts of the beach. The data also reflect changes in beach topography due to human activity during the 2013 fall season, when private beach managers quarried ~178 m³ of sediments on the emerged beach near the shoreline to accumulate them landwards. The results show that drones can be used for regular beach monitoring activities, and that they can provide new insights into the processes related to natural and/or human-related topographic beach changes.     

Deglaciation of the western margin of the Barents Sea Ice Sheet — A swath bathymetric and sub-bottom seismic study from the Kveithola Trough

Kveithola Trough, an E–W trending glacial trough in the NW Barents Sea, was surveyed for the first time during the EGLACOM cruise of R/V OGS-Explora in summer 2008. Swath bathymetry shows that the seafloor is characterized by E–W trending mega-scale glacial lineations (MSGL) that record a fast flowing ice stream draining the Svalbard/Barents Sea Ice Sheet (SBIS) during the Last Glacial Maximum (LGM). MSGL are overprinted by transverse sediment ridges about 15 km apart which give rise to a staircase axial profile of the trough. Such transverse ridges are interpreted to be grounding-zone wedges (GZWs) formed by deposition of subglacial till during episodic ice stream retreat. Sub-bottom (CHIRP) and multi-channel reflection seismic data show that the present-day morphology is largely inherited from the palaeo-seafloor topography at the time of deposition of the transverse ridges, overlain by a draping glaciomarine unit which in places is over 15 m thick. Our data allow the reconstruction of depositional processes which accompanied deglaciation of the Spitsbergen Bank area. The sedimentary drape deposited on top of the GZWs is suggested to have accumulated at a very high rate, (on average in the order of 1–1.5 m ka^?1) and therefore may potentially preserve a high-resolution palaeoclimatic record of deglaciation and post-glacial conditions in this sector of the Barents Sea.     

A 1D P-wave velocity model of the Gargano promontory (south-eastern Italy)

We investigate the elastic properties of the crust in the Gargano promontory, located in the northern part of the Apulia region (Southeastern Italy). Starting on April, 2013, a local-scale seismic network, composed of 12 short-period (1 Hz) seismic stations, was deployed on the Gargano promontory. Starting on October, 2013, the network was integrated with the recordings of nine seismic stations managed by the Italian Institute of Geophysics and Volcanology (INGV). The network recorded more than 1200 seismic events in about 15 months of data acquisition, with more than 700 small magnitude events localized in the Gargano promontory and surrounding areas. A Wadati-modified method allowed us to infer V_P/V_S = 1.73 for the area. A subset of about 400 events having a relatively smaller azimuthal gap (<200°) was selected to calibrate a 1D P-wave velocity model of the area, using the VELEST inversion code. The preferred model was obtained from the average of ten velocity models, each of them representing the inversion result from given initial velocity models, calibrated on previous geological and geophysical studies in the area. The results obtained under the assumption that V_P could decrease with depth are unstable, with very different depths of the top of low-velocity layers. Therefore, the velocity model was obtained from the average of the results obtained under the assumption that V_P cannot decrease with depth. A strong reduction of both RMS (about 58%) and errors on the location of the events was obtained with respect to the starting model. The final velocity model shows a strong velocity gradient in the upper 5 km of the crust and a small increase (from 6.7 to 7 km) at 30 km of depth. The epicenters of relocated events do not show clear correlations with the surface projection of known seismic faults. A cluster of the epicenters of the relocated events intersects almost perpendicularly the Candelaro fault trace at the surface.     

Lagrangian model of zooplankton dispersion: numerical schemes comparisons and parameter sensitivity tests

This paper presents two comparisons or tests for a Lagrangian model of zooplankton dispersion:numerical schemes and time steps.Firstly,we compared three numerical schemes using idealized circulations.Results show that the precisions of the advanced Adams-Bashfold-Moulton(ABM) method and the Runge-Kutta(RK) method were in the same order and both were much higher than that of the Euler method.Furthermore,the advanced ABM method is more efficient than the RK method in computational memory requirements and time consumption.We therefore chose the advanced ABM method as the Lagrangian particle-tracking algorithm.Secondly,we performed a sensitivity test for time steps,using outputs of the hydrodynamic model,Symphonie.Results show that the time step choices depend on the fluid response time that is related to the spatial resolution of velocity fields.The method introduced by Oliveira et al.in 2002 is suitable for choosing time steps of Lagrangian particle-tracking models,at least when only considering advection.     

Cretaceous-Eocene compression in the central Southern Alps (N Italy) inferred from Ar/Ar dating of pseudotachylytes along regional thrust faults

The integration of structural analyses with ⁴⁰Ar/³⁹Ar dating of fault-related pseudotachylytes provides time constraints for the reconstruction of the Alpine evolution of the central portion of the South Alpine orogenic wedge. In the northern sector of the belt a Variscan basement is stacked southward on the Permian to Mesozoic cover along regional faults (Orobic and Porcile thrusts). Fault zones, slightly postdating a first folding event of Alpine age, experienced a complex evolution through the ductile and brittle deformation regime, showing greenschist facies mylonites overprinted by a penetrative cataclastic deformation. Generation of fault-related pseudotachylyte veins marks the onset of brittle conditions, lasting up to the youngest episodes of fault activity. ⁴⁰Ar/³⁹Ar dating of the pseudotachylyte matrix of 9 samples give two separated age clusters: Late Cretaceous (80–68 Ma) and latest Palaeocene to Middle Eocene (55–43 Ma). These new data provide evidence that the pre-Adamello evolution of the central Southern Alps was characterised by the superposition of different tectonic events accompanying the exhumation of the deepest part of the belt through the brittle–ductile transition. The oldest pseudotachylyte ages demonstrate that south-verging regional thrusting in the central Southern Alps was already active during the Late Cretaceous, concurrently with the development of a synorogenic foredeep basin where the Upper Cretaceous Lombardian Flysch was deposited.