Energy flow and elemental concentrations in the Steina River ecosystem (Black Forest, Germany)

Considering food web energetics and elemental cycling together allows the testing of hypotheses about the coevolution of biological systems and their physical environment. We investigated the energy flow and the distribution of 25 elements in the Steina River.¶We constructed an annual energy flow network and estimated the emergy ("embodied energy" that includes all the energy involved in a process) contributions of resources sustaining the system. Furthermore, we measured the concentration of various macronutrients, essential elements, and heavy metals in the physical environment and trophic compartments. Finally, we examined the hypothesis of a positive relationship between the "rarity" of an element and its tendency to bioaccumulate. To do so, we used transformity, the relative energy input required to sustain a compartment's net production or the concentration differential of an element between the living community and the physical environment.¶The resulting energy flow network is one of the most complete available for streams. In the Steina, over 99% of the energy input is transported through the system without being processed. Dissolved inorganic matter and sunlight are the largest inputs, but uptake efficiency is much higher for dissolved and particulate organic matter. Transformities of trophic compartments and elements span 6 to 7 orders of magnitude.¶The tendency to bioaccumulate was as predicted for most elements, with macronutrients showing no accumulation and heavy elements accumulating in high-transformity compartments. However, Na and K were found at highest concentrations in consumers, and Pb, Ga, and Cd in algae. Improved estimates may become possible as more knowledge is available on ecosystem flows. We suggest further ways of testing hypotheses about strategies of element processing.     

The effect of chlorite interlayering on <Superscript>40</Superscript>Ar–<Superscript>39</Superscript>Ar biotite dating: an <Superscript>40</Superscript>Ar–<Superscript>39</Superscript>Ar laser-probe and TEM investigations of variably chloritised biotites

Biotite is one of the most common minerals dated by the ⁴⁰Ar–³⁹Ar method. It frequently shows K contents below the expected stoichiometric value, suggesting the presence of low-K impurities. The most common low-K alteration product of biotite is chlorite. Therefore, it is important to understand the effects of chlorite interlayering on ⁴⁰Ar–³⁹Ar ages in order to correctly interpret ⁴⁰Ar–³⁹Ar data. This study examines the outcome of ⁴⁰Ar–³⁹Ar dating analyses on variably chloritised biotites from Ordovician intrusive rocks. The infrared (IR) laser-probe technique and different gas extraction methods were adopted. Incremental laser-heating data on bulk samples yielded hump-shaped age profiles with meaningless young and old age steps. Both the extent of anomalous old age steps and the degree of discordance of the age spectra were much more pronounced in the more chloritised biotite samples. In contrast, in situ data on rock chips and total-fusion ages on single biotite flakes yielded ages concordant with, or younger than, the inferred emplacement ages. Transmission electron microscopy (TEM) was used to texturally characterise biotite samples at the nanometre scale. It was also used to document the complex decomposition-transformation process affecting interlayered biotite–chlorite during in-vacuo IR-laser heating to temperatures ranging from ~600 to >1,000 °C. TEM results suggest that hump-shaped age profiles result from an interplay between ³⁹Ar_K redistribution by recoil during sample irradiation and differential release of argon isotopes hosted in three main reservoirs. These reservoirs are (from least to most retentive): extended defects, chlorite and biotite. The final descending age segment is attributed to the progressive release of argon with increasing temperature from large biotite domains for which ³⁹Ar_K recoil loss was less important. ⁴⁰Ar–³⁹Ar data support previous findings, which suggest that ⁴⁰Ar–³⁹Ar ages when recoil effects are minimised, provide minimum estimates that approach the true biotite age, when the pristine domains are analysed. The most effective approach for obtaining meaningful ⁴⁰Ar–³⁹Ar ages was using individual total-fusion analyses on carefully selected, single flakes previously split along the basal cleavage by wet-grinding and corresponding to a sample mass of a few micrograms.Editorial responsibility: I Parsons     

Natural contribution of harmful elements in thermal groundwaters of Ischia Island (southern Italy)

Minor and trace element investigations have been performed on groundwaters of Ischia Island, which is located at the western edge of the bay of Naples. Ischia is formed entirely of Quaternary volcanic rocks. Intense seismicity, widespread fumaroles and thermal springs witness the persistent state of activity of its magmatic system. Groundwater samples, 58 from shallow thermal wells and 15 from thermal springs, were analysed for 72 elements by ICP-MS; temperature, pH and electrical conductivity (EC) were measured at the sampling site. Analytical data indicate clearly that the concentrations in the water of some elements, such as As, Be, Cu, Fe, Mn, Sb, Se and Tl, are often higher and sometimes much higher than the intervention limits fixed by the Italian Law DM 471 (25/10/1999) for water. Worthy of mention are the very high As values, reaching >1,000 µg/l in some wells. By means of R-mode factor analysis, 30 of 72 analysed elements were grouped as elemental associations representative of lithological type, water composition and, possibly, mineralization. Ischia thermal groundwaters are the result of mixing, in variable amounts, of deep magmatic fluids that are rich in metallic elements, with marine and/or meteoric waters. R-mode factor analysis and elemental association factor score distributions of the four-factor model confirm the existence of flux of magmatic mineralised fluids with marine and/or meteoric waters. Recharge by seawater intrusions occurs mostly in the north-western area of the island whereas the influence and control of magmatic mineralised fluids is clearly accentuated in the areas of Panza-Citara, Porto di Forio-Fango and Citara-Lido dei Maronti fracture alignments. The observed compositional variability of the analysed groundwaters, even in wells lying close to one another, is due to the local hydrodynamic conditions, controlled mostly by complex fault and fracture systems, which may represent preferential thermal water outflow routes. In general, the average minor and trace element compositions of Ischia thermal waters, when compared with the composition of sea and river water, show an enrichment in metallic elements such as As, Sc, V, Cr, Zn, Mo, U, W, Au, Hg. This paper points out that, in addition to the anthropogenic source, natural contribution also plays an important role in determining the high concentrations of toxic elements in groundwaters, which create health and acceptability problems.     

Comparing palaeolimnological and instrumental evidence of climate change for remote mountain lakes over the last 200 years

This paper compares the palaeolimnological evidence for climate change over the last 200 years with instrumental climate data for the same period at seven European remote mountain lakes. The sites are Øvre Neådalsvatn (Norway), Saanajärvi (Finland), Gossenköllesee (Austria), Hagelseewli (Switzerland), Jezero v Ledvici (Slovenia), Estany Redó (Spain, Pyrenees), and Niné Terianske Pleso (Slovakia). We used multiple regression analysis to transfer homogenised lowland air temperature records to each of the sites, and these reconstructions were validated using data from on-site automatic weather stations. These data showed that mean annual temperature has varied over the last 200 years at each site by between 1 and 2 °C, typical of the high frequency variability found throughout the Holocene, and appropriate, therefore, to test the sensitivity of the various proxy methods used. Sediment cores from each site were radiometrically dated using ²¹⁰Pb, ¹³⁷Cs and ²⁴¹Am and analysed for loss-on-ignition, C, N, S, pigments, diatoms, chrysophytes, Cladocera and chironomids. Comparisons between the proxy data and the instrumental data were based on linear regression analysis with the proxy data treated as response variables and the instrumental data (after smoothing using LOESS regressions) as predictor variables. The results showed few clear or consistent patterns with generally low or very low r² values. Highest values were found when the data were compared after smoothing using a broad span, indicating that some of the proxy data were capturing climate variability but only at a relatively coarse time resolution. Probable reasons for the weak performance of the methods used include inaccurate dating, especially for earlier time periods, the influence of confounding forcing factors at some sites e.g., air pollution, earthquakes, and the insensitivity of some methods to low amplitude climate forcing. Nevertheless, there were trends in some proxy records at a number of sites that had a relatively unambiguous correspondence with the instrumental climate records. These included organic matter and associated variables (C and N) and planktonic diatom assemblages at the majority of sites and chrysophytes and chironomids at a few sites. Overall for longer term studies of the Holocene, these results indicate the need to be cautious in the interpretation of proxy records, the importance of proxy method validation, the continuing need to use reinforcing multi-proxy approaches, and the need for careful site and method selection.     

Contributions to the Ring Current Energy During Geomagnetic Storms

The purpose of this research was to study the complexity of the energization of the ring current during a geomagnetic storm, produced during southern Bz(IMF) by the injection of plasma sheet ions, accelerated by enhanced convective electric fields. This model assumes that the plasma sheet is continuously populated by H⁺ from the sun and the ionosphere, and sporadically by ionospheric O⁺, making the ring current a coupled system whose energy can hardly be expressed analytically. When Bz(IMF) turns north, the ring current becomes uncoupled, and the energy decays exponentially if the storm is weak, or can be expressed as a combination of exponentials during strong storms representing the quick decay of O⁺ and the slower decay of H⁺, as has been shown.     

Spatial distribution and bonding forms of heavy metals in sediments along the middle course of the River Elbe (km 287ċ390)

Sediments of eight groyne fields along the middle course of the River Elbe (river km 287?390) were geochemically studied. The 78 sediment samples were analysed for pH and grain size distribution. The grain size fraction < 2 μm was used for mineralogical and chemical analysis: semiquantitative clay mineral analysis; total element content (Al, Ca, Fe, K, Mn, Cd, Cr, Cu, Ni, Pb, Zn), total inorganic and organic C, and bonding form fractionation with a six‐step sequential chemical extraction. The latter was performed on selected samples (n = 32). The sediments along the Elbe's course are still contaminated with heavy metals far above the local geogenic background level. An enrichment factor of more than 15 was calculated for zinc. Cr and Ni are the elements with the lowest enrichment. The bonding form analysis of selected heavy metals shows a dominance of relatively immobile bonding forms, e. g. the moderately reducible and the residual fraction, which implies a relative low mobility potential. Only Zn poses a higher potential threat to the environment, since it has a higher percentage of the first three extracted phases: adsorbed, carbonate, and easily reducible fraction.     

Space-time soil wetness variations monitoring by a multi-temporal microwave satellite records analysis

In the last few years, remote sensing observations have become a useful tool for providing hydrological information, including the quantification of the main physical characteristics of the catchment, such as topography and land use, and of its variables, like soil moisture or snow cover. Moreover, satellite data have also been largely used in the framework of hydro-meteorological risk mitigation.Recently, an innovative Soil Wetness Variation Index (SWVI) has been proposed, using data acquired by the microwave radiometer AMSU (Advanced Microwave Sounding Unit) which flies aboard NOAA (National Oceanic and Atmospheric Administration) satellites.SWVI is based on a general approach for multi-temporal satellite data analysis (RAT - Robust AVHRR Techniques). This approach exploits the analysis of long-term multi-temporal satellite records in order to obtain a former characterization of the measured signal, in term of expected value and natural variability, providing a further identification of signal anomalies by an automatic, unsupervised change-detection step. Such an approach has already demonstrated, in several studies carried out on extreme flooding events which occurred in Europe in the past few years, its capability in reducing spurious effects generated by natural/observational noise. In this paper, the proposed approach is applied to the analysis of the flooding event which occurred in Europe (primarily in NW Spain) in June 2000. Results obtained, in terms of reliability as well as efficiency in space-time monitoring of soil wetness variation, are presented. Future prospects, in terms of exportability of the methodology on the new dedicated satellite missions, like ESA-SMOS and NASA-HYDROS, are also discussed.     

水文资料在水土保持中的应用研究

本文简要分析了我国水文资料的基本特点及其在水土保持中的应用情况,并结合水文资料在水土保持中的研究实例,探讨了加强水文资料在水土保持中应用范围与价值,在新一轮的站网调整建设中应与水土保持监测站网建设结合起来,避免重复建设,加强水文站网功能,发挥现有水文站网作用。     

Urban texture analysis with image processing techniques: winds and dispersion

Summary The focus is the analysis of urban Digital Elevation Models (DEMs) with image processing techniques. A brief review of existing methods to derive sky view factors, building energy consumption and space syntax shows how well established parameters that relate to airflow and dispersion (such as the height-to-width of urban canyons and the aerodynamic roughness length) can be calculated. Other measures of urban directionality and periodicity, inspired by traditional image processing, are also introduced, such as the Radon, Hough and Fourier transforms and the variance plot. Analyses of three case study sites in London, Toulouse and Berlin are compared, showing considerable variation in the chosen parameters. Results suggest that the DEM format is an extremely versatile tool to investigate the urban intermediate scale, allowing analyses that would be very difficult or impossible to carry out using traditional vectorial models.     

Sources of dissolved REE in mountainous streams draining granitic rocks, Sierras Pampeanas (Córdoba, Argentina)

Stream waters draining granitic terrains from the highest part (850 to 2200 m a.s.l.) of Sierras Pampeanas (Córdoba, Argentina, ∼32°S, ∼65°W) were sampled in order to define sources and distribution of dissolved rare earth elements (REE), and to describe the geochemical processes that govern their mobility. The contribution of the regional granite to the dissolved REE pool in stream water is limited due to the physical conditions predominating in the area (i.e., steep slopes and semiarid climate). Therefore, precipitation is considered a seasonally significant source controlling REE concentration in stream water. Dissolved REE concentrations are inversely correlated with monthly precipitation and rainfall frequency. During the rainy season (i.e., the austral summer) REE concentrations in stream water are lower than during the dry season (i.e., austral winter). Such low concentrations reflect the balance between the REE input from precipitation and their removal by adsorption. In contrast, during the dry season, the longer residence time of water within fractures and colluvium determines an increased REE concentration in the base flow. Lower pH values also contribute to raise REE concentration through desorption from mineral surfaces.