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151.
José Antonio Cuchí David Chinarro José Luis Villarroel 《Environmental Earth Sciences》2014,71(3):1049-1060
Black box identification techniques are very useful tools to study the relationship between rainfall and the discharge of karst aquifers. Autocorrelation, cross-correlation, cross-spectral, impulse response identification (Wiener–Hopf and error minimization methods) and parametric identification of transfer functions techniques have been used by different authors. A review of these techniques has been realized to assess the possibilities and limitations. The reviewed techniques are applied to a time rainfall–discharge series of Fuenmayor karst spring, (southern central Pyrenees, Spain) to establish the relative quality of the obtained models. The quality is evaluated with the Nash–Sutcliffe model efficiency coefficient. In addition, effective rainfall has been used to improve the performance of every model. The whitening technique has been used in the cross-correlation technique with good results. The studied spring shows a Fontestorbes type behavior. The linearity of the system has been analyzed by the coherence function. Fuenmayor has an acceptable linear response, except for high frequency events. The parametric identification provides the best efficiency value E = 0.8164 and provides a proper transfer function, with five parameters (one zero, two poles, the gain and the delay). The prediction power of this transfer function is validated with another time series, with an efficiency value of E = 0.7904. 相似文献
152.
Juana María Sanz Ángel de Miguel Irene de Bustamante Alberto de Tomás José Luis Goy 《Environmental Earth Sciences》2014,71(1):13-21
Conventional water treatments when downsized to cover the demands of small and scattered populations are costly and ineffective. In fact, many small towns cannot afford the high average treatment costs nor provide the skill and complex management requirements. Even when these facilities are available, waste water might not be properly treated. Land application system treatments (LAST) have been shown to be preferable on the basis of their technical effectiveness and financial viability. The recently approved Spanish regulations (RDL 1620/2007, pp 50369–50661) represent an opportunity for the implementation of well-designed LASTs. This paper presents an assessment methodology for the design of LASTs by combining technical, financial and location criteria. The method is applied to the design of LASTs to cover the water disposal demand of twelve municipalities located within the protected natural landscape, and surrounding areas of ‘El Rebollar’, Salamanca, Spain. 相似文献
153.
154.
Irrigated agriculture is a clear source of non-point pollution by salts and nitrogen species. The impact of such pollution should be quantified according to specific cases. The case of the Malfarás creek basin, a sprinkler irrigation district located in the semiarid Ebro valley in northeast Spain, has been evaluated. The main crops in the district were corn, barley and alfalfa, occupying 93 % of the irrigated area. The fate of water, salts and nutrients was evaluated by a daily water balance developed at a field scale for the natural year 2010. The yearly data of the whole set of 101 irrigated fields plus the non-irrigated area compared to the measured drainage produced a basin water balance with a low degree of error. The basin consumed 90 % of the total water input of which 68 % was used for crop evapotranspiration and the rest was lost due to non-productive uses. 16 % of the incoming water left the irrigation area as drainage water. The irrigated area was responsible for 87 % of the drainage. The average volume of drained water was 152 mm year?1 for the whole basin area. The irrigated area drained 183 mm year?1. The basin exported 473 kg of salt per hectare during 2010. This value was the lowest of the sprinkler irrigation areas in the Ebro valley, mainly due to the lower soil salinity. All the crops except barley received a nitrogen surplus of 10–50 % above their needs. The extra nitrogen entered the water cycle increasing the nitrate concentration in the aquifer water (150 mg L?1) and drainage water (98 mg L?1). In 2010 the mass of nitrogen exported by drainage was 49 kg per irrigated hectare. This value is too high for this type of irrigation system and implies that 17 % of nitrogen applied as a fertilizer was lost to drainage water. The key to decreasing the nitrogen leaching and pollution that it causes could be appropriate time-controlled fertigation along with better irrigation scheduling. 相似文献
155.
Miguel A. García José A. Alloza Ángeles G. Mayor Susana Bautista Francisco Rodríguez 《Central European Journal of Geosciences》2014,6(1):112-120
Moderate resolution remote sensing data, as provided by MODIS, can be used to detect and map active or past wildfires from daily records of suitable combinations of reflectance bands. The objective of the present work was to develop and test simple algorithms and variations for automatic or semiautomatic detection of burnt areas from time series data of MODIS biweekly vegetation indices for a Mediterranean region. MODIS-derived NDVI 250m time series data for the Valencia region, East Spain, were subjected to a two-step process for the detection of candidate burnt areas, and the results compared with available fire event records from the Valencia Regional Government. For each pixel and date in the data series, a model was fitted to both the previous and posterior time series data. Combining drops between two consecutive points and 1-year average drops, we used discrepancies or jumps between the pre and post models to identify seed pixels, and then delimitated fire scars for each potential wildfire using an extension algorithm from the seed pixels. The resulting maps of the detected burnt areas showed a very good agreement with the perimeters registered in the database of fire records used as reference. Overall accuracies and indices of agreement were very high, and omission and commission errors were similar or lower than in previous studies that used automatic or semiautomatic fire scar detection based on remote sensing. This supports the effectiveness of the method for detecting and mapping burnt areas in the Mediterranean region. 相似文献
156.
José María González-Jiménez Carlos Villaseca William L. Griffin Suzanne Y. O’Reilly Elena Belousova Eumenio Ancochea Norman J. Pearson 《Contributions to Mineralogy and Petrology》2014,168(2):1-24
Spinel lherzolite and wehrlite xenoliths from the Cenozoic Calatrava volcanic field carry the geochemical imprint of metasomatic agents that have affected the subcontinental lithospheric mantle beneath Central Iberia. Some xenoliths (mainly wehrlites) were enriched in REE, Sr, P, and CO2 by silicic-carbonate-rich metasomatic melts/fluids, while others record the effects of subduction-related hydrous silicate fluids that have precipitated amphibole and induced high Ti/Eu in primary clinopyroxene. The petrographic observations and geochemical data suggest that interstitial glass in the xenoliths represent the quenched products of Si-rich melts that infiltrated the mantle peridotite shortly before the entrainment of the xenoliths in the host magmas that erupted ca 2 million years ago. During their infiltration, the metasomatic melts reacted with peridotite, resulting in silica enrichment, while remobilizing grains of iron-rich monosulfide solid solution (Fe-rich Mss) initially enclosed in, or intergranular to, primary olivine and pyroxenes. In situ laser ablation inductively coupled plasma-mass spectrometry analysis of single sulfide grains reveals that the Fe-rich Mss in glass shows platinum-group element (PGE) patterns and 187Os/188Os compositions identical to the Fe-rich Mss occurring as inclusions in, or at grain boundaries of primary silicates. Moreover, independent of its microstructural position, Fe-rich Mss exhibits PGE and 187Os/188Os signatures typical of Mss either residual after partial melting or crystallized directly from sulfide melts. Our findings reveal that young metasomatic melt(s)/fluid(s) may carry remobilized sulfides with PGE and Os-isotopic signatures identical to those of texturally older sulfides in the peridotite xenolith. These sulfides thus still provide useful information about the timing and nature of older magmatic events in the subcontinental mantle. 相似文献
157.
FTIR spectroscopy of Ti-chondrodite,Ti-clinohumite,and olivine in deeply subducted serpentinites and implications for the deep water cycle 总被引:1,自引:0,他引:1
Tingting Shen Jőrg Hermann Lifei Zhang José Alberto Padrón-Navarta Jing Chen 《Contributions to Mineralogy and Petrology》2014,167(4):1-15
Separated olivine grains from a deeply subducted serpentinized wehrlite (Changawuzi in the western Tianshan ultrahigh-pressure belt, China) were analysed with unpolarized transmission FTIR and the Ti contents were determined using LA-ICP-MS. The major bands in the olivine spectra display striking similarities to Ti-clinohumite and are interpreted as OH in lamellae. The quantification of the water content in lamellae requires calibration of the IR-absorption for such bands. We have obtained a new absorption coefficient for Ti-clinohumite of 0.125+/?0.017 ppm cm2 based on polarized FTIR measurements on three orthogonal sections through a large single crystal of Ti-clinohumite from Val Malenco, which has a known water content of 1.53 wt%. The resulting water content in olivine using this calibration factor ranges from 440 to 2,600 ppm and correlates positively with the Ti content that ranges from 130 to 1,400 ppm. For the quantification of the water content in Ti-chondrodite and Ti-clinohumite that are associated with olivine, we developed a new method using attenuated total reflectance FTIR spectroscopy. Ti-chondrodite and Ti-clinohumite display similar IR bands at ~3,562, 3,525 and ~3,583–3,586 cm?1. As in olivine, the water content and Ti content correlate in both Ti-clinohumite and Ti-chondrodite, indicating an intergrowth of these minerals, which has been confirmed by TEM analyses. Our results confirm previous suggestions that there is a strong correlation between the Ti content of ultramafic rocks and their capacity to transport water to the deeper mantle in subduction zones beyond conditions where hydrous phases are stable. 相似文献
158.
Non-linear stability of the equilibria in the gravity field of a finite straight segment 总被引:1,自引:0,他引:1
Andrés Riaguas Antonio Elipe Teodoro López-Moratalla 《Celestial Mechanics and Dynamical Astronomy》2001,81(3):235-248
We study the non-linear stability of the equilibria corresponding to the motion of a particle orbiting around a finite straight segment. The potential is a logarithmic function and may be considered as an approximation to the one generated by elongated celestial bodies. By means of the Arnold's theorem for non-definite quadratic forms we determine the orbital stability of the equilibria, for all values of the parameter k of the problem, resonant cases included. 相似文献
159.
This paper investigates how using different regional climate model (RCM) simulations affects climate change impacts on hydrology in northern Europe using an offline hydrological model. Climate change scenarios from an ensemble of seven RCMs, two global climate models (GCMs), two global emissions scenarios and two RCMs of varying resolution were used. A total of 15 climate change simulations were included in studies on the Lule River basin in Northern Sweden. Two different approaches to transfer climate change from the RCMs to hydrological models were tested. A rudimentary estimate of change in hydropower potential on the Lule River due to climate change was also made. The results indicate an overall increase in river flow, earlier spring peak flows and an increase in hydropower potential. The two approaches for transferring the signal of climate change to the hydrological impacts model gave similar mean results, but considerably different seasonal dynamics, a result that is highly relevant for other types of climate change impacts studies. 相似文献
160.
A two-dimensional global climate model is used to assessthe climatic changes associated with the new IPCC SRES emissions scenarios and to determine which kind of changes in total solar irradiance and volcanic perturbations could mask the projected anthropogenic global warming associated to the SRES scenarios. Our results suggest that only extremely unlikely changes in total solar irradiance and/or volcanic eruptions would be able to overcome the simulated anthropogenic global warming over the century. Nevertheless, in the critical interval of the next two decades the externally-driven natural climate variability might possibly confuse the debate about temperature trends and impede detection of the anthropogenic climate change signal. 相似文献