Spectrometric analyses in comparison to the physiological condition of heavy metal stressed floodplain vegetation in a standardised experiment

Floodplain ecosystems are affected by flood dynamics, nutrient supply as well as anthropogenic activities. Heavy metal pollution poses a serious environmental challenge. Pollution transfer from the soil to vegetation is still present at the central location of Elbe River, Germany. The goal of this study was to assess and separate the current heavy metal contamination of the floodplain ecosystem, using spectrometric field and laboratory measurements. A standardized pot experiment with floodplain vegetation in differently contaminated soils provided the basis for the measurements. The dominant plant types of the floodplains are: Urtica dioica, Phalaris arundinacea and Alopecurus pratensis, these were also chemically analysed. Various vegetation indices and methods were used to estimate the red edge position, to normalise the spectral curve of the vegetation and to investigate the potential of different methods for separating plant stress in floodplain vegetation. The main task was to compare spectral bands during phenological phases to find a method to detect heavy metal stress in plants. A multi-level algorithm for the curve parameterisation was developed. Chemo-analytical and ecophysiological parameters of plants were considered in the results and correlated with spectral data. The results of this study show the influence of heavy metals on the spectral characteristics of the focal plants. The developed method (depth CR1730) showed significant relationship between the plants and the contamination.     

Multiple generation magmatic and hydrothermal processes in a Martian subvolcanic environment based on the analysis of Yamato-000593 nakhlite meteorite

We studied the occurrence of secondary minerals and inferred their formation in the Yamato-000593 Martian meteorite using multiple technological approaches such as electron probe micro analysis, optical microscope, Raman spectroscopy, scanning electron microscopy, as well as Fourier transform-infrared microscopy and spectroscopy. Two separate hydrothermal alteration events and their sequence of formation (based on superpositional relationship) can be identified: an elevated temperature phase producing high-temperature sulfidic hydrothermal alteration and a lower temperature hydrothermal alteration phase by iron-rich fluids. This meteorite shows signatures more compatible with magmatic effects, rather than impact-induced hydrothermal alteration, as has been proposed earlier. The sulfidic alteration probably formed by magmatic hydrothermal fluids, whereas iron-rich hydrothermal fluid circulation after a possible early impact event has also been proposed, when the fluids cooled down to 50 °C. Most of the secondary minerals formed at alkaline-neutral conditions, and the few observed signatures (clay–silica-bearing veins, siderite-iron-oxide veins) of briny conditions are probably from local spatial effects in larger cavities. The ferrous minerals (hematite and siderite) along the fractures could be crystallized from Fe-HCO₃-bearing fluids. Alternatively, the primary magmatic minerals could have been oxidized easily (Fe-rich olivines, magnetite) during the cooling to iron oxides (hematite, goethite). The results suggest the possible existence of at least ephemerally habitable environments on Mars, mainly at volcanically heated locations. Following published geochemical models, the carbonates formed within acidic-circumneutral condition, which was followed by formation of phyllosilicates in alkaline condition.     

Micro-XCT chondrule classification for subsequent isotope analysis

Chondrules are microscopic, recrystallized melt droplets found in chondritic meteorites. High-resolution isotope analyses of minor elements require large enough element quantities which are obtained by dissolving entire chondrules. This work emphasizes the importance of X-ray computed tomography (XCT) to detect features that can significantly affect the bulk chondrule isotope composition. It thereby expands on other works by looking into chondrules from a wide range of chondrites including CR, CV, CB, CM, L, and EL samples before turning toward complex and time-consuming chemical processing. The features considered are metal and igneous rims, compound chondrules, matrix remnants, and metal contents. In addition to the identification of these features, computed tomography prevents the inclusion of non-chondrule samples (pure matrix or metal) as well as samples where two different chondrule fragments with potentially different isotope compositions are held together by matrix. Matrix surrounding chondrules is also easily detected and the affected chondrules can be omitted or reprocessed. The results strongly encourage to perform XCT before dissolution of chondrules for isotope analysis as a non-invasive method.     

Mushroom production as an alternative for rural development in a forested mountainous area

Wild mushrooms are recognized as important non-wood forest products in mountainous ecosystems, but their real potential for generating rural economies has not been fully evaluated due to the difficulties in obtaining reliable productivity data, minimizing their true potential as contributor to rural economies. Mushroom yield models based on large data series from Pinus forest ecosystems in the region of Catalonia(Spain), combined with data from the Spanish National Forest Inventory allow us to estimate the potential mushroom productivity by forest ecosystems. The results of 24,500 tons/yr of mushrooms of which 16,300 tons are classified as edible and 7,900 tons are commonly marketed demonstrate the importance of mushroom productions in Catalonian pine forests, mostly located in mountainous areas where the development of agricultural activities is limited. Economic mushroom value is estimated at 48 million € for the edible mushroom and 32 million € for those corresponding to marketable yields, confirming the potential of this non-wood forest product. These production results and corresponding economic values provide a basis for the incorporation of wild mushrooms as significant non-wood forest products in the development of forest policies in mountainous areas.     

Species richness,diversity and density of understory vegetation along disturbance gradients in the Himalayan conifer forest

We investigated whether species richness, diversity and density of understory herbaceous plants differed along logging(gap) and grazing(primarily by cattle) disturbance gradients, and sought to identify drivers of richness, diversity and density of understory vegetation of logged sites. A factorial experiment was conducted in the mixed conifer forest of Gidakom in Western Bhutan. Levels of the logging treatment included small(0.15 – 0.24 ha), medium(0.25 – 0.35 ha) and large(0.36 – 1.31 ha) gaps. The grazing treatment included grazed(primarily by cattle) and ungrazed(where herbivores were excluded by a fence) plots nested within each gap. Data were collected from 12 gaps(4 replicates at each level of logging) using the point intercept method. Shannon Weaver Diversity and Margalef's indices were used to estimate species diversity and describe species richness, respectively. Soil samples were analyzed for pH and nutrients. The interaction effect of logging and grazing was significant(p≤0.001) only on species diversity. Relative to ungrazed areas, species diversity was significantly higher(0.01≤p≤0.05) in medium grazed gaps. Under grazed conditions, soil P was negatively correlated with gap size and species diversity. While species diversity was positivelycorrelated(0.01≤p≤0.05) with soil N in grazed plots species richness was positively correlated(0.001≤p≤0.01) with soil N in ungrazed plots. Relative density of Yushania microphylla and Carex nubigena were higher under ungrazed conditions. Our study suggests that the combined effect of cattle grazing and logging results in higher species diversity of understory vegetation in medium and grazed gaps in mixed conifer forests of Bhutan,whereas increase or decrease in relative density of major species is determined primarily by the independent effects of grazing and logging. From management perspective, forest managers must refrain from creating large gaps to avoid loss of nutrients(mainly P and N), which may eventually affect tree regeneration. Managers intending to maintain understory vegetation diversity must consider the combined effects of grazing and logging, ensuring low to moderate grazing pressure.     

Making a Mark: a computational and visual analysis of one researcher’s intellectual domain

Dr. David Mark is widely regarded as a path-breaking researcher in geographic information science. What are the structural and temporal characteristics of his intellectual contributions, as seen through the eyes of the broader academic community? Aiming to answer that question, this article presents a scientometric analysis of publications that have been cited alongside David Mark’s papers. In deliberate contrast to the widespread focus on using citation data to condense scientific impact into a handful of indicators, the methodological contribution of this study lies in its mix of computational and visualization approaches. In the search for latent domain structures, state-of-the-art practices in information science, bibliometrics, and network visualization are combined and extended. An initial network of 50,000+ publications and 4,000,000+ document co-citations undergoes a series of transformations reducing it to 9000 publications that are then clustered in a two-stage process, leading to 678 communities whose co-citation linkages are used to delineate 19 super-communities. To enable replication of this approach for other studies, much focus in this article is on detailed discussion of that workflow as well as on highlighting the reasoning behind the choices made among data sources and analytical methods. The topical evolution of David Mark’s domain of influence is explored in some detail, based on tabular and graphic representations of extracted community structures. Results confirm not only the enormous overall breadth of his influence but also how lasting and recurrent it has been in some areas.     

The economics of boldness: equity,action, and hope

Equity is usually interpreted in terms of the concept of justice, such that an equitable share of the atmospheric space is understood in terms of past emissions. This emphasizes the collective nature of sharing the burden of mitigation and the duty to act for those who have emitted the most. An alternative is considered: the aggregate costs and benefits to all Parties that could result from both increasing the level of collective ambition and implementing a climate regime that supports bold actions across all Parties. The regional impacts and carbon flow costs across differentiated scenarios are assessed and it is argued that the majority of developing-country Parties would be better off if a high ambition outcome to which all contributed, but some more than others. Moreover, those with middle or low emissions would have proportionally more to gain (or lose) relative to the level of ambition compared to those that have had higher emissions. The climate regime should be built on the principle of common but differentiated responsibility and respective capabilities (CBDR&RC), in which all act early even if some do much more; one that accounts for justice but does not forget hope.

Policy relevance

Differing interpretations of equity and the principles of the United Nations Framework Convention on Climate Change (UNFCCC) are discussed, with a focus on how these can enhance or hinder collective action. Whilst the climate change negotiations are usually taken as games in which one party gains and another loses, and interactions are dogged by continuous conflict, it is explored instead how negotiation responses can be framed in terms of cooperation. This would emphasize the gains that could be achieved by common but differentiated collective action, which could result in a collective avoidance of impacts. The possibilities that this shift of perspective could bring are explored by comparing costs under global cooperation (or lack of it). It is found that cooperation reduces the total costs for these regions. Thus, thinking in terms of cooperation focuses the options for negotiation on the means and interpretations of the UNFCCC principles that spur action and avoid climate impacts through collective action.     

Effects of substratum type on fish assemblages in shallow areas of a tropical estuary

While there is already a comprehensive understanding of the effects of environmental variables, such as dissolved oxygen, temperature and salinity, on the structure, biomass and metabolism of aquatic biota in estuarine habitats, the effect of sedimentation, a harmful underlying factor, remains unclear. The aim of this study was to assess the differences in fish assemblages along the freshwater to salt water gradient of a large tropical estuary, and to evaluate the effects on them of habitat disturbance associated with shallow water sedimentation in the intertidal areas. Fish and environmental variables were recorded in the upper, middle and lower salinity zones of the estuary at ebb tide in both the dry and wet seasons. Sediment samples associated with different levels of habitat disturbance were analysed using granulometry, and their organic content and dissolved oxygen levels were quantified. Water temperature, salinity, pH and dissolved oxygen levels were also measured. Habitat disturbance was found to be correlated with the density, biomass and richness of fish assemblages. A total of 77 species were recorded, forming two distinct fish assemblages, with the Eleotridae family dominating in the upper zone, and Gerreidae, Gobiidae and Tetraodontidae the most common in the middle and lower estuary. Changes in the structure of fish assemblages, including reductions in density, biomass and richness, were associated with disturbance to natural features, where muddy sediment was replaced by sandy sediment and the quantity of organic matter fell. Atherinella brasiliensis was the species which showed a preference for the disturbed areas in the middle and lower zones, while Dormitator maculatus showed a preference for them in the upper estuary. They may be taken as indicators of habitat disturbance due to shallow sedimentation.     

Climatological study of ionospheric irregularities over the European mid-latitude sector with GPS

High-frequency variability of the ionosphere, or irregularities, constitutes the main threat for real-time precise positioning techniques based on Global Navigation Satellite Systems (GNSS) measurements. Indeed, during periods of enhanced ionospheric variability, GNSS users in the field—who cannot verify the integrity of their measurements—will experience positioning errors that can reach several decimeters, while the nominal accuracy of the technique is cm-level. In the frame of this paper, a climatological analysis of irregularities over the European mid-latitude region is presented. Based on a 10 years GPS dataset over Belgium, the work analyzes the occurrence rate (as a function of the solar cycle, season and local time) as well as the amplitude of ionospheric irregularities observed at a single GPS station. The study covers irregularities either due to space weather events (solar origin) or of terrestrial origin. If space weather irregularities are responsible for the largest effects in terms of ionospheric error, their occurrence rate highly depends on solar activity. Indeed, the occurrence rate of ionospheric irregularities is about 9 % during solar maximum, whereas it drops to about 0 % during medium or low solar activity periods. Medium-scale ionospheric disturbances (MSTIDs) occurring during daytime in autumn/winter are the most recurrent pattern of the time series, with yearly proportions slightly varying with the solar cycle and an amplitude of about 10 % of the TEC background. Another recurrent irregularity type, though less frequent than MSTIDs, is the noise-like variability in TEC observed during summer nighttime, under quiet geomagnetic conditions. These summer nighttime irregularities exhibit amplitudes ranging between 8 and 15 % of the TEC background.     

Linear system techniques applied to the Fuenmayor Karst Spring, Huesca (Spain)

Black box identification techniques are very useful tools to study the relationship between rainfall and the discharge of karst aquifers. Autocorrelation, cross-correlation, cross-spectral, impulse response identification (Wiener–Hopf and error minimization methods) and parametric identification of transfer functions techniques have been used by different authors. A review of these techniques has been realized to assess the possibilities and limitations. The reviewed techniques are applied to a time rainfall–discharge series of Fuenmayor karst spring, (southern central Pyrenees, Spain) to establish the relative quality of the obtained models. The quality is evaluated with the Nash–Sutcliffe model efficiency coefficient. In addition, effective rainfall has been used to improve the performance of every model. The whitening technique has been used in the cross-correlation technique with good results. The studied spring shows a Fontestorbes type behavior. The linearity of the system has been analyzed by the coherence function. Fuenmayor has an acceptable linear response, except for high frequency events. The parametric identification provides the best efficiency value E = 0.8164 and provides a proper transfer function, with five parameters (one zero, two poles, the gain and the delay). The prediction power of this transfer function is validated with another time series, with an efficiency value of E = 0.7904.