9000 years of geochemical evolution of lithogenic major and trace elements in the sediment of an alpine lake – the role of climate, vegetation, and land-use history

A 9000cal. year record of geochemistry was analysed in a sediment core obtained from a Swiss alpine hard-water lake (1937 ma.s.l.) that is located at the present-day tree-line. Geochemical stratigraphies are compared to changes in mineralogy, grain-size, pollen, and macrofossil records. This allows the reconstruction of the effects of changes in vegetation and of 3500 years of land-use in the catchment area on sediment geochemistry. Using principal component analysis, two major geochemical groups are distinguished: (i) Changes in concentrations of Rb, Ti, Zr, Fe, As, and Pb are closely related to corresponding changes in the concentrations of quartz and clay. They are thus considered to represent the silicate fraction which shows an increase from the oldest to the youngest core section. (ii) In contrast, Ca and Sr concentrations are positively correlated with changes in silt, sand, and calcite. They are therefore considered to represent the carbonate fraction which gradually decreased. Based on constrained cluster analysis, the core is divided into two major zones. The oldest zone (A; 9000–6400 cal.BP) is characterised by high concentrations of detrital carbonates. The more open catchment vegetation at that time promoted the physical weathering of these carbonates. The second major zone (B, 6400 cal.BP–1996 AD) is divided into four subsections with boundaries at ca. 3500, 2400, and 160cal. BP. The lower part of this zone, B1, is characterized by a gradual decrease in the carbonate-silt fraction and a pronounced increase in the silicate-clay fraction. This is concurrent with the expansion of Picea in the catchment area, which probably stabilized the soil. The middle part, B2 and B3 (3500–160cal. BP), comprises pronounced fluctuations in all elements, especially Ca, Sr, Mn, and Rb, but also in clay and silt. These changes are related to varying intensities of alpine farming. In the same section, Mn/Fe ratios are highly variable, suggesting changes in the mixing regime of the lake with phases of anoxic bottom water. The uppermost section, B4 (since 160cal. BP), is characterized by a steep decline in the silicate fraction and an increase in Ca and Sr. Despite the decrease in the silicate fraction, Pb increases, due to elevated atmospheric input resulting from early metal pollution, are masked by the high natural variability. Generally, changes in vegetation, which correspond to climate changes in the early Holocene and to human activities since ca. 3700cal. BP, are the controlling factor for variations in the geochemical composition of the sediment of Sägistalsee.     

Evaluating foreland basin partitioning in the northern Andes using Cenozoic fill of the Floresta basin,Eastern Cordillera,Colombia

This paper addresses foreland basin fragmentation through integrated detrital zircon U–Pb geochronology, sandstone petrography, facies analysis and palaeocurrent measurements from a Mesozoic–Cenozoic clastic succession preserved in the northern Andean retroarc fold‐thrust belt. Situated along the axis of the Eastern Cordillera of Colombia, the Floresta basin first received sediment from the eastern craton (Guyana shield) in the Cretaceous–early Palaeocene and then from the western magmatic arc (Central Cordillera) starting in the mid‐Palaeocene. The upper‐crustal magmatic arc was replaced by a metamorphic basement source in the middle Eocene. This, in turn, was replaced by an upper‐crustal fold‐thrust belt source in the late Eocene which persisted until Oligocene truncation of the Cenozoic section by the eastward advancing thrust front. Sedimentary facies analysis indicates minimal changes in depositional environments from shallow marine to low‐gradient fluvial and estuarine deposits. These same environments are recorded in coeval strata across the Eastern Cordillera. Throughout the Palaeogene, palaeocurrent and sediment provenance data point to a uniform western or southwestern sediment source. These data show that the Floresta basin existed as part of a laterally extensive, unbroken foreland basin connected with the proximal western (Magdalena Valley) basin from mid‐Paleocene to late Eocene time when it was isolated by uplift of the western flank of the Eastern Cordillera. The Floresta basin was also connected with the distal eastern (Llanos) basin from the Cretaceous until its late Oligocene truncation by the advancing thrust front.     

Satellite Data for a Rapid Assessment of Tsunami Inundation Areas after the 2011 Tohoku Tsunami

The M _w = 9.0 earthquake that occurred off the coast of Japan’s Tohoku region produced a great tsunami causing catastrophic damage and loss of life. Within hours of the tsunami event, satellite data were readily available and massive media coverage immediately circulated thousands of photographs and videos of the tsunami. Satellite data allow a rapid assessment of inundated areas where access can be difficult either as a result of damaged infrastructure (e.g., roads, bridges, ports, airports) or because of safety issues (e.g., the hazard at Nuclear Power Plant at Fukushima). In this study, we assessed in a day tsunami inundation distances and runup heights using satellite data (very high-resolution satellite images from the GeoEye1 satellite and from the DigitalGlobe worldview, SRTM and ASTER GDEM) of the Tohoku region, Northeast Japan. Field survey data by Japanese and other international scientists validated our results. This study focused on three different locations. Site selection was based on coastal morphologies and the distance to the tsunami source (epicenter). Study sites are Rikuzentakata, Oyagawahama, and Yagawahama in the Oshika Peninsula, and the Sendai coastal plain (Sendai City to Yamamoto City). Maximum inundation distance (6 km along the river) and maximum runup (39 m) at Rikuzentakata estimated from satellite data agree closely with the 39.7 m inundation reported in the field. Here the ria coastal morphology and horn shaped bay enhanced the tsunami runup and effects. The Sendai coastal plain shows large inundation distances (6 km) and lower runup heights. Natori City and Wakabayashi Ward, on the Sendai plain, have similar runup values (12 and 16 m, respectively) obtained from SRTM data; these are comparable to those obtained from field surveys (12 and 9.5 m). However, at Yagawahama and Oyagawahama, Miyagi Prefecture, both SRTM and ASTER data provided maximum runup heights (41 to 45 m and 33 to 34 m, respectively), which are higher than those measured in the field (about 27 m). This difference in DEM and field data is associated with ASTER and SRTM DEM’s pixel size and vertical accuracy, the latter being dependent on ground coverage, slope, aspect and elevation. Countries with less access to technology and infrastructure can benefit from the use of satellite imagery and freely available DEMs for an initial, pre-field surveys, rapid estimate of inundated areas, distances and runup, and for assisting in hazard management and mitigation after a natural disaster.     

Cost and Co<Subscript>2</Subscript>-Emission Reduction of Biomass Cascading: Methodological Aspects and Case Study of SRF Poplar

This study presents and applies a coherent methodological framework to compare biomass cascading chains, i.e. the subsequent use of biomass for materials, recycling and energy recovery, considering land use, CO₂ emission reduction and economic performance. Example cascading chains of short rotation poplar wood are compared with each other on the basis of literature data. Results for these chains vary strongly, namely, from CO₂ mitigation benefits of 200 /Mg CO₂ to CO₂ mitigation costs of 2200 /Mg CO₂, and from net CO₂ emission reductions per hectare of biomass production of 28 Mg CO₂/(ha yr) to net CO₂ emissions of 8 Mg CO₂/(ha yr). Using a present-value approach to determine CO₂ emissions and costs affects the performance of long-term cascading chains significantly, i.e. cost and CO₂ emission reduction are decreased. In general, cascading has the potential to improve both CO₂ emission reduction per hectare and CO₂ mitigation costs of biomass usage. However, this strongly depends on the biomass applications combined in the cascading chain. Parameters that significantly influence the results are market prices and gross energy requirements of substituted materials and energy carriers, and the efficiency of biomass production. The method presented in this study is suitable to quantify land use, CO₂ emission reduction and economic performance of biomass cascading systems, and highlights the possible impact of time on the attractiveness of specific cascading chains.     

Changes in European greenhouse gas and air pollutant emissions 1960–2010: decomposition of determining factors

This paper analyses factors that contributed to the evolution of SO₂, NO_x and CO₂ emissions in Europe from 1960 to 2010. Historical energy balances, along with population and economic growth data, are used to quantify the impacts of major determinants of changing emission levels, including energy intensity, conversion efficiency, fuel mix, and pollution control. Time series of emission levels are compared for countries in Western and Eastern Europe, throwing light on differences in the importance of particular emission-driving forces. Three quarters of the decline in SO₂ emissions in Western Europe resulted from a combination of reduced energy intensity and improved fuel mix, while dedicated end-of-pipe abatement measures played a dominant role in the reduction of NO_x emissions. The increase in atmospheric emissions in Eastern Europe through the mid-1990s was associated with the growth of energy-intensive industries, which off-setted the positive impact of better fuel quality and changes in fuel mix. A continuous decrease in energy intensity and higher conversion efficiencies have been the main factors responsible for the moderate rate of growth of European CO₂ emissions.