On the design and selection of polychlorinated biphenyls for use in biological test systems

The polychlorinated biphenyls (PCBs) consist of a large number of individual congeners with varying degree of chlorination and possible substitution patterns. No single congener can be used as a representative congener for the whole class of compounds. Multivariate chemical characterisation (principal component analysis) in combination with factorial design provide tools by which small sets of structurally representative congeners can be determined. These tools are suggested to be used in the design of biological experiments in order to introduce systematic structural variation in the congeners to be tested and to make it possible to construct quantitative structure-activity relationships (QSARs). A QSAR based on bioaccumulation factors (BAFs) in fish for 20 systematically selected PCBs made it possible to predict BAFs for all 134 non-tested tetra-through hepta-chlorinated congeners. The use of these systematic and balanced sets of congeners in the experimental protocol will provide increased knowledge of the environmental behaviour of the PCBs.     

Influence of biological and environmental factors on hepatic steroid and xenobiotic metabolism in fish: interaction with PCB and β-naphthoflavone

The degree of induction of hepatic cytochrome P-450 monooxygenases in fish by various chemicals may vary owing to many factors such as sex, sexual maturity, age, season and environmental temperature. In the present investigation the influences of gonadal steroids and water temperature on the inductive response were studied. The data indicate that gonadal steroids and water temperature modulate the response of the cytochrome P-450 system in rainbow trout to PCB and β-naphthoflavone.     

Modelling the dynamics of superfluid neutron stars

In this brief summary I describe our recent work on superfluid neutron star dynamics. I review results on shear viscosity, hyperon bulk viscosity, vortex mediated mutual friction and the modelling of multifluid systems in general. For each problem I provide a set of questions that need to be addressed by future work.     

Elemental and isotopic carbon and nitrogen records of organic matter accumulation in a Holocene permafrost peat sequence in the East European Russian Arctic

A peat deposit from the East European Russian Arctic, spanning nearly 10 000 years, was investigated to study soil organic matter degradation using analyses of bulk elemental and stable isotopic compositions and plant macrofossil remains. The peat accumulated initially in a wet fen that was transformed into a peat plateau bog following aggradation of permafrost in the late Holocene (～2500 cal a BP). Total organic carbon and total nitrogen (N) concentrations are higher in the fen peat than in the moss‐dominated bog peat layers. Layers in the sequence that have lower concentrations of total hydrogen (H) are associated with degraded vascular plant residues. C/N and H/C atomic ratios indicate better preservation of organic matter in peat material dominated by bryophytes as opposed to vascular plants. The presence of permafrost in the peat plateau stage and water‐saturated conditions at the bottom of the fen stage appear to lead to better preservation of organic plant material. δ¹⁵N values suggest N isotopic fractionation was driven primarily by microbial decomposition whereas differences in δ¹³C values appear to reflect mainly changes in plant assemblages. Positive shifts in both δ¹⁵N and δ¹³C values coincide with a local change to drier conditions as a result of the onset of permafrost and frost heave of the peat surface. This pattern suggests that permafrost aggradation not only resulted in changes in vegetation but also aerated the underlying fen peat, which enhanced microbial denitrification, causing the observed ¹⁵N‐enrichment. Copyright © 2012 John Wiley & Sons, Ltd.     

Observations of magnetic anomaly signatures in Mars Express ASPERA-3 ELS data

Mars Express (MEX) Analyser of Space Plasmas and Energetic Atoms (ASPERA-3) data is providing insights into atmospheric loss on Mars via the solar wind interaction. This process is influenced by both the interplanetary magnetic field (IMF) in the solar wind and by the magnetic ‘anomaly’ regions of the martian crust. We analyse observations from the ASPERA-3 Electron Spectrometer near to such crustal anomalies. We find that the electrons near remanent magnetic fields either increase in flux to form intensified signatures or significantly reduce in flux to form plasma voids. We suggest that cusps intervening neighbouring magnetic anomalies may provide a location for enhanced escape of planetary plasma. Initial statistical analysis shows that intensified signatures are mainly a dayside phenomenon whereas voids are a feature of the night hemisphere.     

Thallium isotope composition of the upper continental crust and rivers—An investigation of the continental sources of dissolved marine thallium

The thallium (Tl) concentrations and isotope compositions of various river and estuarine waters, suspended riverine particulates and loess have been determined. These data are used to evaluate whether weathering reactions are associated with significant Tl isotope fractionation and to estimate the average Tl isotope composition of the upper continental crust as well as the mean Tl concentration and isotope composition of river water. Such parameters provide key constraints on the dissolved Tl fluxes to the oceans from rivers and mineral aerosols.The Tl isotope data for loess and suspended riverine detritus are relatively uniform with a mean of ε²⁰⁵Tl = −2.0 ± 0.3 (ε²⁰⁵Tl represents the deviation of the ²⁰⁵Tl/²⁰³Tl isotope ratio of a sample from NIST SRM 997 Tl in parts per 10⁴). For waters from four major and eight smaller rivers, the majority were found to have Tl concentrations between 1 and 7 ng/kg. Most have Tl isotope compositions very similar (within ±1.5 ε²⁰⁵Tl) to that deduced for the upper continental crust, which indicates that no significant Tl isotope fractionation occurs during weathering. Based on these results, it is estimated that rivers have a mean natural Tl concentration and isotope composition of 6 ± 4 ng/kg and ε²⁰⁵Tl = −2.5 ± 1.0, respectively.In the Amazon estuary, both additions and losses of Tl were observed, and these correlate with variations in Fe and Mn contents. The changes in Tl concentrations have much lower amplitudes, however, and are not associated with significant Tl isotope effects. In the Kalix estuary, the Tl concentrations and isotope compositions can be explained by two-component mixing between river water and a high-salinity end member that is enriched in Tl relative to seawater. These results indicate that Tl can display variable behavior in estuarine systems but large additions and losses of Tl were not observed in the present study.     

A search for millimeter-wave emission from HCN and other molecules in Comet Bradfield (1979l)

Millimeter-wave emission from HCN, CS, CH₃OH, and two unidentified lines (previously observed in Comet Kohoutek (1973 XII)) was sought and not detected from Comet Bradfield (1979l) after perihelion passage. Limits on column densities and production rates are derived. In the case of HCN, the production rate is less than that reported for Comet Kohoutek, even after scaling relative to the observed OH emission from each comet.     

Ultra-high-resolution observations of CH in Southern Molecular Cloud envelopes

We present a mini-survey of ultrahigh-resolution spectroscopy (UHRS) of CH towards three southern molecular cloud envelopes. The sightlines are selected to probe physically similar gas in different Galactic environments. With a velocity resolution of ∼0.5 km s⁻¹  ( R =575 000)  these observations resolve most kinematic components of the absorption lines. We do, however, detect one line component in the Lupus region, which is not resolved and for which an upper limit of   b <0.3 km s^-1  is found. We find a correlation between distance of the absorbing gas from the Galactic mid-plane and the fractional abundance of CH. We show that this correlation can be explained as being a result of a fall-off in the ultraviolet radiation field intensity and propose that CH observations in carefully selected sightlines might allow a mapping of the variations in the interstellar radiation field.     

Fish assemblages in Tanzanian mangrove creek systems influenced by solar salt farm constructions

Deforestation of mangrove forests is common occurrence worldwide. We examined fish assemblage composition in three mangrove creek systems in Tanzania (East Africa), including two creeks where the upper parts were partly clear-cut of mangrove forest due to the construction of solar salt farms, and one creek with undisturbed mangrove forest. Fish were caught monthly for one year using a seine net (each haul covering 170 m²) within three locations in each creek, i.e. at the upper, intermediate and lower reaches. Density, biomass and species number of fish were lower in the upper deforested sites compared to the mangrove-fringed sites at the intermediate and lower parts in the two creeks affected by deforestation, whereas there were no differences among the three sites in the undisturbed mangrove creek system. In addition, multivariate analyses showed that the structure of fish assemblages varied between forested and clear-cut sites within the two disturbed creeks, but not within the undisturbed creek. Across the season, we found no significant differences except for a tendency of a minor increase in fish densities during the rainy season. At least 75% of the fishes were juveniles and of commercial interest for coastal fisheries and/or aquaculture. Mugil cephalus, Gerres oyena and Chanos chanos were the most abundant species in the forested sites. The dominant species in the clear-cut areas were M. cephalus and Elops machnata, which were both found in relatively low abundances compared to the undisturbed areas. The conversion of mangrove forests into solar salt farms not only altered fish assemblage composition, but also water and sediment conditions. In comparison with undisturbed areas, the clear-cut sites showed higher salinity, water temperature as well as organic matter and chlorophyll a in the sediments. Our results suggest that mangrove habitat loss and changes in environmental conditions caused by salt farm developments will decrease fish densities, biomass and species numbers as well as alter the overall fish assemblage composition in the salt farm area but not downstream in the creek.