PCBs and chlorinated pesticides in the atmosphere and aquatic organisms of Ross Island, Antarctica

PCBs, p,p′-DDT, p,p′-DDE and lindane (γ-hexachlorocyclohexane) were monitored in the lower atmosphere of Ross Island, in Antarctica for 2 yr. Geometrical means were 15.2 pg m⁻³ for PCBs, 2.0 pg m⁻³ for p,p′-DDT, 1.0 pg m⁻³ for p,p′-DDE and 25.8 pg m⁻³ for lindane. Atmospheric levels of lindane were positively correlated with temperature, and a significant difference was found between spring-summer and summer-winter concentrations. No season related differences were found for the other chlorinated hydrocarbons, possibly owing to their lower vapour pressure and the cold climate. Periods with increased atmospheric levels of PCBs and DDT compounds were recorded. Lindane, p,p′-DDE and PCBs were present in fish and zooplankton sampled close to Ross Island. Pollutant levels in the zooplankton (on an extractable fat basis) were highest during the Antarctic spring and autumn and were inversely correlated to their fat content.     

Compositional variations at ultra-structure length scales in coral skeleton

Distributions of Mg and Sr in the skeletons of a deep-sea coral (Caryophyllia ambrosia) and a shallow-water, reef-building coral (Pavona clavus) have been obtained with a spatial resolution of 150 nm, using the NanoSIMS ion microprobe at the Muséum National d’Histoire Naturelle in Paris. These trace element analyses focus on the two primary ultra-structural components in the skeleton: centers of calcification (COC) and fibrous aragonite. In fibrous aragonite, the trace element variations are typically on the order of 10% or more, on length scales on the order of 1-10 μm. Sr/Ca and Mg/Ca variations are not correlated. However, Mg/Ca variations in Pavona are strongly correlated with the layered organization of the skeleton.These data allow for a direct comparison of trace element variations in zooxanthellate and non-zooxanthellate corals. In both corals, all trace elements show variations far beyond what can be attributed to variations in the marine environment. Furthermore, the observed trace element variations in the fibrous (bulk) part of the skeletons are not related to the activity of zooxanthellae, but result from other biological activity in the coral organism. To a large degree, this biological forcing is independent of the ambient marine environment, which is essentially constant on the growth timescales considered here.Finally, we discuss the possible detection of a new high-Mg calcium carbonate phase, which appears to be present in both deep-sea and reef-building corals and is neither aragonite nor calcite.     

The 1995–2002 Long-Term Monitoring of Comet C/1995 O1 (HALE–BOPP) at Radio Wavelength

The bright comet Hale–Bopp provided the first opportunity to follow the outgassing rates of a number of molecular species over a large range of heliocentric distances. We present the results of our observing campaign at radio wavelengths which began in August 1995 and ended in January 2002. The observations were carried out with the telescopes of Nançay, IRAM, JCMT, CSO and, since September 1997, SEST. The lines of nine molecules (OH, CO, HCN, CH₃OH, H₂CO, H₂S, CS, CH₃CN and HNC) were monitored. CS, H₂S, H₂CO, CH₃CN were detected up to r_h= 3–4 AU from the Sun, while HCN and CH₃OH were detected up to 6 AU. CO, which is the main driver of cometary activity at heliocentric distances larger than 3–4 AU, was last detected in August 2001, at r_h= 14 AU. The gas production rates obtained from this programme contain important information on the nature of cometary ices, their thermal properties and sublimation mechanisms.Line shapes allow to measure gas expansion velocities, which, at large heliocentric distances, might be directly connected to the temperature of the nucleus surface. Inferred expansion velocity of the gas varied as r_h ^-0.4 within 7 AU from the Sun, but remained close to 0.4 km s^-1 further away. The CO spectra obtained at large r_hare strongly blueshifted and indicative of an important day-to-night asymmetry in outgassing and expansion velocity. The kinetic temperature of the coma, estimated from the relative intensities of the CH₃OH and CO lines, increased with decreasing r_h, from about 10 K at 7 AU to 110 K around perihelion.     

First discovery of stishovite in an iron meteorite

Abstract— The first occurrence of stishovite in an iron meteorite, Muonionalusta (group IVA), is reported. The mineral occurs intimately mixed with amorphous silica, forming tabular grains up to ?3 mm wide, with a hexagonal outline. It was identified using X‐ray diffraction and Raman microspectroscopy. The unit‐cell parameters of stishovite are a = 4.165(3) Å and c = 2.661(6) Å, and its chemical composition is nearly pure SiO₂. Raman spectra show relatively sharp bands at 231 and 754 cm^?1 and a broad band with an asymmetric shape and a maximum around 500 cm^?1. The rare grains are found within troilite nodules together with chromite, daubreelite, and schreibersite. From their composition and morphology, and by comparisons with silica inclusions in, e.g., the Gibeon IVA iron, we conclude that these rare grains represent pseudomorphs after tridymite. The presence of stishovite in Muonionalusta is suggested to reflect shock metamorphic conditions in the IVA parent asteroid during a cosmic impact event.     

Long-Term Seasonal Trends in the Prey Community of Delta Smelt (<Emphasis Type="Italic">Hypomesus transpacificus</Emphasis>) Within the Sacramento-San Joaquin Delta,California

Abiotic factors and species introductions can alter food web timing, disrupt life cycles, and change life history expressions and the temporal scale of population dynamics in zooplankton communities. We examined physical, trophic, and zooplankton community dynamics in the San Francisco Estuary, California, a highly altered Mediterranean climate waterway, across a 43-year dataset (1972–2014). Before invasion by the suspension-feeding overbite clam (Potamocorbula amurensis) in the mid-1980s, the estuary demonstrated monomictic thermal mixing in which winter turbidity and cool temperatures contributed to seasonally low productivity, followed by a late-spring-summer clearing phase with warm water and peak phytoplankton blooms that continued into early winter. Following the clam invasion, we observed a shift in peak phytoplankton bloom timing, with peak productivity now occurring in May compared to June prior to the invasion. Peak abundance of several zooplankton taxa (Eurytemora affinis, Pseudodiaptomus, other calanoids, and non-copepods) also shifted to earlier in the season. We present the first evidence of a shift in the timing of peak abundance for zooplankton species that are key prey items of delta smelt (Hypomesus transpacificus), a federally threatened pelagic fish species. These timing shifts may have exacerbated well-documented food limitations of delta smelt due to declines in primary productivity since the invasion of the overbite clam. Future conservation efforts in the estuary should consider measures designed to restore the timing and magnitude of pre-invasion phytoplankton blooms.     

An Early Pleistocene interglacial deposit at Pingorsuit,North-West Greenland

At the Pingorsuit Glacier in North-West Greenland, an organic-rich deposit that had recently emerged from the retreating ice cap was discovered at an elevation of 480 m above sea level. This paper reports on macrofossil analyses of a coarse detritus gyttja and peaty soil, which occurred beneath a thin cover of till and glacifluvial deposits. The sediments contained remains of vascular plants, mosses, beetles, caddisflies, midges, bryozoans, sponges and other invertebrates. The flora includes black spruce, tree birch, boreal shrubs and wetland and aquatic taxa, which shows that mires, lakes and ponds were present in the area. We describe a new extinct waterwort species Elatine odgaardii. The fossils were deposited in a boreal environment with a mean July air temperature that was at least 9 °C higher than at present. The fossil assemblages show strong similarities with others from Greenland that have been assigned an Early Pleistocene age, and we suggest a similar age for the sediments found at the margin of the Pingorsuit Glacier. At the Pingorsuit Glacier in North-West Greenland, an organic-rich deposit was discovered at an elevation of 480 m above sea level. The sediments contained remains of vascular plants, mosses, beetles, caddisflies, midges, bryozoans, sponges and other invertebrates. The fossils were deposited in a boreal environment with a mean July air temperature that was at least 9 °C higher than at present.     

Timing and maximum flood level of the Early Holocene glacial lake Nedre Glomsjø outburst flood,Norway

This study discusses the timing and maximum flood level of the Nedre Glomsjø outburst flood, Norway, based on sediment records retrieved from 15 bog and lake basins located close to the purported maximum flooded level. The sediment records in 12 of the basins consist of a distinct light-coloured silty bed that is correlated to the outburst-flood-deposited ‘Romerike Silt Bed’ identified elsewhere in the region. The silt bed is recorded in basins up to a certain elevation and is absent above this level. The new maximum flood level inferred from the basin sediment records exceeds the established landform-induced palaeostage indicators by 5–10 m. The data indicate a higher maximum flood level and larger inundation area than previously suggested and highlight the importance of acquiring a wide range of geological data when reconstructing palaeofloods. Radiocarbon dates of terrestrial macrofossils found stratigraphically above and below the Romerike Silt Bed suggest that the glacial lake Nedre Glomsjø outburst flood occurred between 10.5 and 10.3 cal. ka BP. The new and well-constrained timing of the outburst flood is beneficial for reconstructing regional deglaciation and provides a precise age for the Romerike Silt Bed chronostratigraphical marker, which is of value for studies in SE Norway and adjacent regions.     

Managing Bay and Estuarine Ecosystems for Multiple Services

Managers are moving from a model of managing individual sectors, human activities, or ecosystem services to an ecosystem-based management (EBM) approach which attempts to balance the range of services provided by ecosystems. Applying EBM is often difficult due to inherent tradeoffs in managing for different services. This challenge particularly holds for estuarine systems, which have been heavily altered in most regions and are often subject to intense management interventions. Estuarine managers can often choose among a range of management tactics to enhance a particular service; although some management actions will result in strong tradeoffs, others may enhance multiple services simultaneously. Management of estuarine ecosystems could be improved by distinguishing between optimal management actions for enhancing multiple services and those that have severe tradeoffs. This requires a framework that evaluates tradeoff scenarios and identifies management actions likely to benefit multiple services. We created a management action-services matrix as a first step towards assessing tradeoffs and providing managers with a decision support tool. We found that management actions that restored or enhanced natural vegetation (e.g., salt marsh and mangroves) and some shellfish (particularly oysters and oyster reef habitat) benefited multiple services. In contrast, management actions such as desalination, salt pond creation, sand mining, and large container shipping had large net negative effects on several of the other services considered in the matrix. Our framework provides resource managers a simple way to inform EBM decisions and can also be used as a first step in more sophisticated approaches that model service delivery.     

Geochemical constraints on the Laurentide Ice Sheet contribution to Meltwater Pulse 1A

Planktonic and benthic δ¹⁸O records adjacent to the runoff outlets of the Laurentide Ice Sheet (LIS) indicate that the LIS contributed to the abrupt ～20 m rise in sea level ～14.6 ka, Meltwater Pulse 1A (MWP-1A). However, the magnitude of the LIS contribution still remains unresolved. Here, I use a freshwater runoff–ocean mixing model to calculate the LIS meltwater required to explain the decreases in planktonic and benthic δ¹⁸O observed during MWP-1A at the southern, eastern and northern runoff outlets of the LIS. Maximum LIS contributions in equivalent sea level rise for a 500-year long MWP-1A are 2.7 m discharged into the Gulf of Mexico as a combined hyperpycnal and hypopycnal flow, 2.1 m discharged into the North Atlantic, and 0.5 m into the Arctic Ocean, for a total LIS contribution of ≤5.3 m. A LIS contribution of <30% to MWP-1A supports the hypothesis that a significant component of this MWP was sourced from the Antarctic Ice Sheet.     

Were last glacial climate events simultaneous between Greenland and France? A quantitative comparison using non‐tuned chronologies

Several large abrupt climate fluctuations during the last glacial have been recorded in Greenland ice cores and archives from other regions. Often these Dansgaard–Oeschger events are assumed to have been synchronous over wide areas, and then used as tie‐points to link chronologies between the proxy archives. However, it has not yet been tested independently whether or not these events were indeed synchronous over large areas. Here, we compare Dansgaard–Oeschger‐type events in a well‐dated record from southeastern France with those in Greenland ice cores. Instead of assuming simultaneous climate events between both archives, we keep their age models independent. Even these well‐dated archives possess large chronological uncertainties that prevent us from inferring synchronous climate events at decadal to multi‐centennial time scales. If possible, comparisons between proxy archives should be based on independent, non‐tuned time‐scales. Copyright © 2009 John Wiley & Sons, Ltd.