Field Application of the Combined Membrane‐Interface Probe and Hydraulic Profiling Tool (MiHpt)

The Membrane‐Interface Probe and Hydraulic Profiling Tool (MiHpt) is a direct push probe that includes both the membrane interface probe (MIP) and hydraulic profiling tool (HPT) sensors. These direct push logging tools were previously operated as separate logging systems for subsurface investigation in unconsolidated formations. By combining these two probes into one logging system the field operator obtains useful data about the distribution of both volatile organic contaminants (VOCs) and relative formation permeability in a single boring. MiHpt logging was conducted at a chlorinated VOC contaminated site in Skuldelev, Denmark, to evaluate performance of the system. Formation cores and discrete interval slug tests are used to assess use of the HPT and electrical conductivity (EC) logs for lithologic and hydrostratigraphic interpretation. Results of soil and groundwater sample analyses are compared to the adjacent MiHpt halogen specific detector (XSD) logs to evaluate performance of the system to define contaminant distribution and relative concentrations for the observed VOCs. Groundwater profile results at moderate to highly contaminated locations were found to correlate well with the MiHpt‐XSD detector responses. In general, soil sample results corresponded with detector responses. However, the analyses of saturated coarse‐grained soils at the site proved to be unreliable as demonstrated by high RPDs for duplicate samples. The authors believe that this is due to pore water drainage observed from these cores during sampling. Additionally, a cross section of HPT pressure and MiHpt‐XSD detector logs provides insight into local hydrostratigraphy and formation control on contaminant migration.     

Subgrain-scale decoupling of Re and Os and assessment of laser ablation ICP-MS spot dating in molybdenite

Reproducibility of Re-Os molybdenite ages depends on sample size and homogeneity, suggesting that Re and Os are decoupled within individual molybdenite crystals and do not remain spatially linked over time. In order to investigate the Re-Os systematics of molybdenite at the subgrain (micron) scale, we report LA-ICP-MS Re-Os ages for an Archean molybdenite crystal from Aittojärvi, Finland, analyzed in situ in a white aplite matrix. A related Aittojärvi molybdenite (A996D), in the form of a very fine-grained mineral separate, is used as one of our in-house NTIMS standards, and thus its age of 2760 ± 9 Ma is well established. Measurements of (¹⁸⁷Re + ¹⁸⁷Os)/¹⁸⁵Re on micron scale spots along 200 μm traverses across the crystal yield a wide range of ages demonstrating that, in this case, microsampling of molybdenite does not produce geologically meaningful ages. Experimentation with mineral separations and sample size over a 7-yr period predicted that this would be the outcome. We suggest that ¹⁸⁷Os is more likely to be the mobile species, based on its charge and ionic radius, and that ¹⁸⁷Os becomes decoupled from parent ¹⁸⁷Re with time on the micron and larger scale. Incompatible charge and ionic radius for Os ions formed during reduction of molybdenite-forming fluids may explain the widely observed absence of common (initial) Os in molybdenite. Geologically accurate ages for molybdenite can only be obtained for fully homogenized crystals (or crystal aggregates) so that any post-crystallization ¹⁸⁷Re-¹⁸⁷Os decoupling is overcome.A growing number of geologically accurate ID-NTIMS ¹⁸⁷Re-¹⁸⁷Os ages for homogenized molybdenite suggest that postcrystallization mobility of radiogenic ¹⁸⁷Os must be limited to within the molybdenite mineral phase. We suggest that radiogenic ¹⁸⁷Os may be stored in micron scale dislocations, kink bands, and delamination cracks produced by deformation, and that the unusual structure and deformation response of molybdenite results in an increased chemical stability in this mineral. Migration of ¹⁸⁷Os into adjacent silicate phases is highly unlikely, but other contacting sulfides may take in Os. In an example from a Proterozoic skarn deposit at Pitkäranta (western Russia), we demonstrate minor loss of radiogenic ¹⁸⁷Os from molybdenite and a corresponding gain in adjacent chalcopyrite such that the molybdenite age is not perceptibly disturbed, whereas the resulting chalcopyrite ages are impossibly old. Therefore, it is unadvisable to perform Re-Os analytical work on any sulfide in contact or intimate association with molybdenite. In addition to large errors in the age, if the isochron method is employed, initial ¹⁸⁷Os/¹⁸⁸Os ratios could be erroneously high, leading to seriously errant genetic interpretations.     

Disturbance of beach sediment by off-road vehicles

A three-year investigation was undertaken to examine the effects of off-road vehicles (ORVs) on the beach at Fire Island, New York. Within the National Seashore over 45,000 vehicle trips per year are concentrated in the zone seaward of the dune toe. The experimental approach was adopted in order to assess the environmental effects of ORVs. Specially developed instrumentation was used to measure the direct displacement of sand by vehicles traversing the beach. Direct displacement data were reduced graphically and analyzed by stepwise linear regression. The results of 89 field experiments (788 cases) showed that slope, sand compaction, and number of vehicle passes in the same track were the principal factors controlling the measured net seaward displacement of sand. The data suggest that ORV use levels within the National Seashore could be contributing to the overall erosion rate by delivering large quantities of sand to the swash zone (max. of 119,300 m³/yr). However, with proper management downslope movement of sand could be reduced by an order of magnitude. While vehicular passage over the open beach displaces sand seaward, it is not known if such activity actually increases the amount of erosion, measured as net loss to the beach face.     

Postglacial uplift and relative sea level changes in Finnmark,northern Norway

The outer coast of Finnmark in northern Norway is where the former Fennoscandian and Barents Sea ice sheets coalesced. This key area for isostatic modelling and deglaciation history of the ice sheets has abundant raised shorelines, but only a few existing radiocarbon dates constrain their chronology. Here we present three Holocene sea level curves based on radiocarbon dated deposits from isolation basins at the outermost coast of Finnmark; located at the islands Sørøya and Rolvsøya and at the Nordkinn peninsula. We analysed animal and plant remains in the basin deposits to identify the transitions between marine and lacustrine sediments. Terrestrial plant fragments from these transitions were then radiocarbon dated. Radiocarbon dated mollusk shells and marine macroalgae from the lowermost deposits in several basins suggest that the first land at the outer coast became ice free around 14,600 cal yr BP. We find that the gradients of the shorelines are much lower than elsewhere along the Norwegian coast because of substantial uplift of the Barents Sea. Also, the anomalously high elevation of the marine limit in the region can be attributed to uplift of the adjacent seafloor. After the Younger Dryas the coast emerged 1.6–1.0 cm per year until about 9500–9000 cal yr BP. Between 9000 and 7000 cal yr BP relative sea level rose 2–4 m and several of the studied lakes became submerged. At the outermost locality Rolvsøya, relative sea level was stable at the transgression highstand for more than 3000 years, between ca 8000 and 5000 cal yr BP. Deposits in five of the studied lakes were disturbed by the Storegga tsunami ca 8200–8100 cal yr BP.     

A transitioning Arctic surface energy budget: the impacts of solar zenith angle, surface albedo and cloud radiative forcing

Snow surface and sea-ice energy budgets were measured near 87.5°N during the Arctic Summer Cloud Ocean Study (ASCOS), from August to early September 2008. Surface temperature indicated four distinct temperature regimes, characterized by varying cloud, thermodynamic and solar properties. An initial warm, melt-season regime was interrupted by a 3-day cold regime where temperatures dropped from near zero to ?7°C. Subsequently mean energy budget residuals remained small and near zero for 1 week until once again temperatures dropped rapidly and the energy budget residuals became negative. Energy budget transitions were dominated by the net radiative fluxes, largely controlled by the cloudiness. Variable heat, moisture and cloud distributions were associated with changing air-masses. Surface cloud radiative forcing, the net radiative effect of clouds on the surface relative to clear skies, is estimated. Shortwave cloud forcing ranged between ?50 W m^?2 and zero and varied significantly with surface albedo, solar zenith angle and cloud liquid water. Longwave cloud forcing was larger and generally ranged between 65 and 85 W m^?2, except when the cloud fraction was tenuous or contained little liquid water; thus the net effect of the clouds was to warm the surface. Both cold periods occurred under tenuous, or altogether absent, low-level clouds containing little liquid water, effectively reducing the cloud greenhouse effect. Freeze-up progression was enhanced by a combination of increasing solar zenith angles and surface albedo, while inhibited by a large, positive surface cloud forcing until a new air-mass with considerably less cloudiness advected over the experiment area.     

Tropical versus high latitude freshwater influence on the Atlantic circulation

We investigate the model sensitivity of the Atlantic meridional overturning circulation (AMOC) to anomalous freshwater flux in the tropical and northern Atlantic. Forcing in both locations leads to the same qualitative response: a positive freshwater anomaly induces a weakening of the AMOC and a negative freshwater anomaly strengthens the AMOC. Strong differences arise in the temporal characteristics and amplitude of the response. The advection of the tropical anomaly up to the deep water formation area leads to a time delayed response compared to a northern forcing. Thus, in its transient response, the AMOC is less sensitive to a constant anomalous freshwater flux in the tropics than in the north. This difference decreases with time and practically vanishes in equilibrium with constant freshwater forcing. The equilibrium response of the AMOC shows a non-linear dependence on freshwater forcing in both locations, with a stronger sensitivity to positive freshwater forcing. As a consequence, competitive forcing in both regions is balanced when the negative forcing is about 1.5 times larger than the positive forcing. The relaxation time of the AMOC after termination of a freshwater perturbation depends significantly on the AMOC strength itself. A strong overturning exhibits a faster relaxation to its unperturbed state. By means of a set of complementary experiments (pulse-perturbations, constant and stochastic forcing) we quantify these effects and discuss the corresponding time scales and physical processes.     

Five centuries of Stockholm winter/spring temperatures reconstructed from documentary evidence and instrumental observations

Historical documentary sources, reflecting different port activities in Stockholm, are utilised to derive a 500-year winter/spring temperature reconstruction for the region. These documentary sources reflect sea ice conditions in the harbour inlet and those series that overlap with the instrumental data correlate well with winter/spring temperatures. By refining dendroclimatological methods, the time-series were composited to a mean series and calibrated (1756–1841; r ²?=?66%) against Stockholm January–April temperatures. Strong verification was confirmed (1842–1892; r ²?=?60%; RE/CE?=?0.55). By including the instrumental data, the quantified (QUAN) reconstruction indicates that recent two decades have been the warmest period for the last 500 years. Coldest conditions occurred during the 16th/17th and early 19th centuries. An independent qualitative (QUAL) historical index was also derived for the Stockholm region. Comparison between QUAN and QUAL shows good coherence at inter-annual time-scales, but QUAL distinctly appears to lack low frequency information. Comparison is also made to other winter temperature based annually resolved records for the Baltic region. Between proxy coherence is generally good although it decreases going back in time with the 1500–1550 period being the weakest period—possibly reflecting data quality issues in the different reconstructions.     

European climate of the past 500 years: new challenges for historical climatology

Temperature reconstructions from Europe for the past 500 years based on documentary and instrumental data are analysed. First, the basic documentary data sources, including information about climate and weather-related extremes, are described. Then, the standard palaeoclimatological reconstruction method adopted here is discussed with a particular application to temperature reconstructions from documentary-based proxy data. The focus is on two new reconstructions; January–April mean temperatures for Stockholm (1502–2008), based on a combination of data for the sailing season in the Stockholm harbour and instrumental temperature measurements, and monthly Central European temperature (CEuT) series (1500–2007) based on documentary-derived temperature indices of the Czech Republic, Germany and Switzerland combined with instrumental records from the same countries. The two series, both of which are individually discussed in greater detail in subsequent papers in this special edition, are here compared and analysed using running correlations and wavelet analysis. While the Stockholm series shows a pronounced low-frequency component, the CEuT series indicates much weaker low-frequency variations. Both series are analysed with respect to three different long-period reconstructions of the North Atlantic Oscillation (NAO) and are compared with other European temperature reconstructions based on tree-rings, wine-harvest data and various climate multiproxies. Correlation coefficients between individual proxy-based series show weaker correlations compared to the instrumental data. There are also indications of temporally varying temperature cross-correlations between different areas of Europe. The two temperature reconstructions have also been compared to geographically corresponding temperature output from simulations with global and regional climate models for the past few centuries. The findings are twofold: on the one hand, the analysis reinforces the hypothesis that the index-data based CEuT reconstruction may not appropriately reflect the centennial scale variations. On the other hand, it is possible that climate models may underestimate regional decadal variability. By way of a conclusion, the results are discussed from a broader point of view and attention is drawn to some new challenges for future investigations in the historical climatology in Europe.     

The impacts of climate change on agricultural production systems in China

Climate change can bring positive and negative effects on Chinese agriculture, but negative impacts tend to dominate. The annual mean surface temperature has risen about 0.5–0.8 °C. The precipitation trends have not been identified during the past 100 years in China, although the frequency and intensity of extreme weather/climate events have increased, especially of drought. Water scarcity, more frequent and serious outbreaks of insects and diseases, and soil degradation caused by climate change have impacted agro-environmental conditions. However, temperature rise prolonged the crop growth seasons and cold damages have reduced in Northeast China. The projection of climate change indicates that the surface temperature will continue to increase with about 3.9 to 6.0 °C and precipitation is expected to increase by 9 to 11 % at the end of 21st century in China. Climate warming will provide more heat and as a consequence, the boundary of the triple-cropping system (TCS) will extend northwards by as much as 200 to 300 km, from the Yangtze River Valley to the Yellow River Basin, and the current double-cropping system (DCS) will move to the central part of China, into the current single cropping system (SCS) area which will decrease in SCS surface area of 23.1 % by 2050. Climate warming will also affect the optimum location for the cultivation of China’s main crop varieties. If no measures are taken to adapt to climate changes, compared with the potential yield in 1961–1990, yields of irrigated wheat, corn and rice are projected to decrease by 2.2–6.7 %, 0.4 %–11.9 % and 4.3–12.4 % respectively in the 2050s. Climate warming will enhance potential evaporation and reduce the availability of soil moisture, thus causing a greater need for agricultural irrigation, intensifying the conflict between water supply and demand, especially in arid and semi-arid areas of China. With adequate irrigation, the extent of the reduction in yield of China’s corn and wheat can be improved by 5 % to 15 %, and rice by 5 % or so than the potential yield in 1961–1990. Adaptive measures can reduce the agricultural loss under climate change. If effective measures are taken in a timely way, then climate change in the next 30–50 years will not have a significant influence on China’s food security.     

Analysis of thunderstorm and lightning activity associated with sprites observed during the EuroSprite campaigns: Two case studies

During the summers of 2003 to 2006 sprites were observed over thunderstorms in France by cameras on mountain tops in Southern France. The observations were part of a larger coordinated effort, the EuroSprite campaigns, with data collected simultaneously from other sources including the French radar network for precipitation structure, Meteosat with images of cloud top temperature and the Météorage network for detection of cloud-to-ground (CG) flash activity. In this paper two storms are analyzed, each producing 27 sprite events. Both storms were identified as Mesoscale Convective Systems (MCS) with a trailing stratiform configuration (ST) and reaching a maximum cloud area of ~ 120,000 km². Most of the sprites were produced while the stratiform area was clearly developed and during periods of substantial increase of rainfall in regions with radar reflectivity between 30 and 40 dBZ. The sprite-producing periods followed a maximum in the CG lightning activity and were characterized by a low CG flash rate with a high proportion of + CG flashes, typically around 50%. All sprites were associated with + CGs except one which was observed after a − CG as detected by the Météorage network. This − CG was estimated to have − 800 C km charge moment change. The peak current of sprite-producing + CG (SP + CG) flashes was twice the average value of + CGs and close to 60 kA with little variation between the periods of sprite activity. The SP + CG flashes were further characterized by short time intervals before a subsequent CG flash (median value < 0.5 s) and with clusters of several CG flashes which suggest that SP + CG flashes often are part of multi-CG flash processes. One case of a lightning process associated with a sprite consisted of 7 CG flashes.