Phengite compositions and post-nappe high-pressure metamorphism in the pennine zone of the French Alps

A systematic study of relict highly substituted phengite micas (Si_3.6–3.7) formed in the less deformed and less recrystallized rocks of the internal zone of the French Alps shows that silica content “isograds” for phengites cut across major thrust boundaries. This indicates that a high-pressure metamorphism was post-nappe in the orogenic sequence. Little substituted, secondary phengites and those found in highly recrystallized rocks reflect metamorphic conditions which occurred during the later mountain building phases of the orogeny.Variations of mica phengite content within mineral facies zones indicate rather important differences in pressure along the Pennine zone in going from low- to high-temperature mineral facies.     

Isotopic anomalies of noble gases in meteorites and their origins—IV. C3 (Ornans) carbonaceous chondrites

The C3O chondrites Kainsaz, Lancé and Ornans were studied by an acid dissolution technique, to characterize the noble-gas components in 3 mineral fractions: HF, HCl-solubles (99% of the meteorite), chromite and carbon (0.3–0.9%), and ‘phase Q’, a poorly characterized trace mineral (0.05–0.4%) containing most of the Ar, Kr, Xe. For all fractions, gas contents decline in the order Kainsaz > Lancé > Ornans; this trend parallels volatile contents but not heterogeneity of olivine composition or degree of metamorphism and seems to reflect progressively higher condensation temperatures from the solar nebula.Solubles contain nearly unfractionated Xe, and show ${}^{136}\text{Ar}{}^{132}\text{Xe}$ ratios up to 850. Hence the high $\text{Ar}\text{Xe}$ ratios (200–400) of bulk C3O chondrites must be due to an HF-soluble mineral (possibly magnetite). Phase Q contains ordinary planetary gases and a Ne component of ${}^{20}\text{Ne}{}^{22}\text{Ne}\text{= 10.3 ± 0.4.}$Chromite and carbon contain Ne of ${}^{20}\text{Ne}{}^{22}\text{Ne}\text{= 8.6 ± 0.1}$ and ‘CCF’ xenon (a peculiar component of possibly fissiogenic origin, enriched in the heavy isotopes but accompanied by a component enriched in the light isotopes).In all primitive chondrites, both the amount and the chemical separability of CCFXe parallel the abundance of promordial noble gases and other volatiles, such as C, N, Tl, Bi and In. The close correlation of CCFXe with various properties of undoubtedly local origin (volatile content, petrologic type, presence of ferrichromite and carbon, etc.) is more consistent with a local than with an extrasolar origin of this component. A volatile superheavy element seems to be the most plausible source, but the evidence is not conclusive.     

A study on the fractionation of organic matter in natural water by ultrafiltration techniques

Diaflo ultrafilters have been studied for the fractionation of organic matter in natural water. One method for their use, including pretreatment, is described. The filter retention is not only depending on the weight of the molecule but also on the charge as shown by experiments with dyestuffs and inorganic ions. For pure solutions of phosphate and nitrate the retentions were 77 and 27% respectively. Filter UM 2, with a nominal molecular weight cutoff at 1,000, retained coloured and total organic matter to 94 and 91% respectively. UM 10 (10,000) retained coloured matter to 88%. Through filtrations the binding of calcium to organic in water was found to be 1 to 10%.     

Regional climate model simulations of daily maximum and minimum near-surface temperatures across Europe compared with observed station data 1961–1990

Simulations of the present-day temperature climate in Europe obtained with the dynamic regional climate model HadRM3P from the Hadley Centre are evaluated. Observed daily temperature maxima (T _x) and minima (T_n) for the 1961–1990 period at 185 stations are compared with their nearest corresponding HadRM3P grid-box data. The model generally performs well over the UK and elsewhere between latitudes 50 and 55°N, with biases mostly within ±0.5 K. In other areas coherent regions with seasonal biases up to more than ±5 K exist. In some areas, biases in climatological averages are associated with even larger errors (up to more than ±15 K) in the upper/lower extreme temperature range. Both areas with systematically overestimated and underestimated intra-seasonal daily temperature variances exist, but overestimation dominates. Too hot summer T _x south of about 45°N are associated with drying soils in the model. This problem may occur further north in future integrations with a greenhouse-gas induced warming. Given the existence of errors in the simulations of the present-day climate, we recommend that results from future scenario integrations are treated with care.     

Strong, localised country-rock contamination and partial homogenisation of a mafic magma: An example from west central Sweden

A dolerite sill cutting slightly older basalt in west-central Sweden shows a strong chemical variation (54% < SiO₂ < 73%) within a restricted area (< 100 × 100 m²). The linear correlation among almost all elements is extremely high; in addition, _NdT is strongly correlated with the SiO₂ content. Least-square hyperbolic-ratio and three-element ratio modelling (common denominator) suggests that most of the chemical variation is explained by mixing and/or micro-mingling. In all, we test 407 hyperbolas, of which 402 are fitted. The five ratio pairs, which could not be fitted to a hyperbola using a least-square fitting procedure, have the ratio Th / Eu in common. Testing the goodness of fit is problematic for hyperbolic distributions; for comparing purposes we sum the distances to chords approximating the hyperbola. Mobile and immobile elements behave similarly, suggesting that no elements are lost or added from outside the system. The data suggests that already the most mafic of the analysed rocks is a mixture of the ‘normal’ dolerite and a siliceous crustal rock. A mafic magma intruded into the base of the crust, where it fractionated resulting in a decreased Mg number. The magma was then contaminated with country rocks in an intermediate magma chamber due to country rock melting; during mixing/mingling almost no fractionation took place. The contaminated rock suggests the presence of a fluid phase. This was probably a prerequisite for country-rock melting. Enrichment in some incompatible elements suggests that besides major mixing/mingling a thermochemical separation process has affected the most felsic rock enriching it in light rare earths and Zr.     

The Greenland Ice Core Chronology 2005, 15–42 ka. Part 1: constructing the time scale

The Greenland Ice Core Chronology 2005, GICC05, is extended back to 42 ka b2k (before 2000 AD), i.e. to the end of Greenland Stadial 11. The chronology is based on independent multi-parameter counting of annual layers using comprehensive high-resolution measurements available from the North Greenland Ice Core Project, NGRIP. These are measurements of visual stratigraphy, conductivity of the solid ice, electrolytical melt water conductivity and the concentration of Na⁺, Ca²⁺, SO₄²⁻, NO₃⁻, NH₄⁺. An uncertainty estimate of the time scale is obtained from identification of ‘uncertain’ annual layers, which are counted as 0.5±0.5 years. The sum of the uncertain annual layers, the so-called maximum counting error of the presented chronology ranges from 4% in the warm interstadial periods to 7% in the cold stadials. The annual accumulation rates of the stadials and interstadials are on average one-third and half of the present day values, respectively, and the onset of the Greenland Interstadials 2, 3, and 8, based on 20 year averaged δ¹⁸O values, are determined as 23,340, 27,780, and 38,220 yr b2k in GICC05.     

Approach to chemical equilibrium in diagenetic chlorites

Electron microprobe analyses were made on diagenetic chlorites in sandstones and mudstones from two deep wells according to the petrographic character of the chlorite occurrence: as pseudomorphic phases, rims on quartz or glauconite or as distinct phases in the clay matrix. Chlorite compositions do not depend upon crystallization site (reacting phases) making it apparent that new chlorites can form in an approach to chemical equilibrium at or near the surface (40° C, 1 km depth). Comparison of this data with that for late diagenetic and early metamorphic chlorites indicates that the compositional range for different grains in the same thin section is similar for the samples throughout the 40°–270° C temperature span. Compositional range decreases upon further metamorphism.Al content appears to be a more reliable indicator of temperature variations than other substitutions in the chlorite structure. The clay mineral assemblage which indicates sedimentary facies affects the trends in composition (Al increase or decrease) as a function of temperature. The octahedral site occupancy show a general increase in going from diagenesis to metamorphic conditions in pelitic rocks. The range of Fe-Mg ratios seems to depend more on the chemistry of each sample than the temperature of formation of the minerals.     

Sector-zoned phlogopites in igneous rocks

Sector-zoned micas are described in three occurrences of igneous rocks. Basal sectors (001) and lateral sectors (010) are well defined. Analyses of probably isochronous growth points indicate that there are consistent chemical composition differences between the sectors, the (010) sector being richer in Si and poorer in Ti, Fe, Al and Ba relative to the (001) sector. Within each sector type Fe/ (Fe + Mg) increases from core to rim. These differences vary in amplitude from one occurrence to the other, but are systematic for micas with extremely different tetrahedral cations. Possible factors influencing this type of crystallization are briefly reviewed: growth rate, geometry of protosites and bulk composition of the liquid.     

Turbulent exchange above a pine forest,I: Fluxes and gradients

Measurements of gradients of wind, temperature and humidity and of the corresponding turbulent fluxes have been carried out over a sparse pine forest at Jädra»s in Sweden. In order to ascertain that correct gradient estimates were obtained, two independent measuring systems were employed: one system with sensors at 10 fixed levels on a 51 m tower and another with reversing sensors for temperature and humidity, covering the height interval 23 to 32 m. Turbulent fluxes were measured at three levels simultaneously. Data from three field campaigns: in June 1985, June 1987 and September 1987 have been analyzed. The momentum flux is found on the average to be virtually constant from tree top level, at 20 to 50 m. The average fluxes of sensible and latent heat are not so well behaved. The ratio of the non-dimensional gradients of wind and temperature to their corresponding values under ideal conditions (low vegetation) are both found to be small immediately above the canopy (about 0.3 for temperature and 0.4 for wind). With increasing height, the ratios increase, but the values vary substantially with wind direction. The ratios are not found to vary systematically with stability (unstable stratification only studied). The ratio of the non-dimensional humidity gradient to the corresponding non-dimensional potential temperature gradient (equivalent to k _h /k _w ) is found to be unity for (z – d)/L _v less than about –0.1 and about 1.4 for near neutral stratification, but the scatter of the data is very large.