Temporal trends in dioxins (polychlorinated dibenzo-p-dioxin and dibenzofurans) and dioxin-like polychlorinated biphenyls in Baltic herring (Clupea harengus)

Polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) and dioxin-like polychlorinated biphenyl (dl-PCBs) concentrations in Baltic herring (Clupea harengus) have been relatively stable since the mid to late 1990s. It is unclear why concentrations in Baltic herring are not following the observed decreases in other environmental matrices. Here, changes in long-term temporal trends in Baltic herring were examined. A number of biological variables were examined alongside the temporal trends to investigate whether fish biology e.g., growth (length, weight, age), lipid content, reproductive phase or fishing date may provide an explanation for the temporal trends observed.     

Origin and extent of fresh groundwater, salty paleowaters and recent saltwater intrusions in Red River flood plain aquifers, Vietnam

A model has been established on the origin and extent of fresh groundwater, salty paleowaters and saltwater from recent seawater intrusions in the Red River flood plain in Vietnam. This was done with geological observations, geophysical borehole logging and transient electromagnetic methods. Salt paleowater is present up to 50–75?km from the coastline, with occurrence controlled by the Holocene transgression. A density-driven leaching of salty porewater has occurred from high-permeability Holocene sediments into underlying Pleistocene deposits, whereas diffusion has dominated in low-permeability layers. In the Pleistocene aquifer, the highest content of dissolved solids is found below two intrinsic valleys with Holocene marine sediments and along the coastline. Recent intrusion of saltwater from the South China Sea is observed in shallow groundwater 35?km inland, probably a result of transport of salty water inland in rivers or leaching of paleowaters from very young near-coast marine sediments. The observed inverted salinity profile, with high saline water overlying fresher groundwater, has been formed due to the global eustatic sea-level changes during the last 8,000–9,000?years. The proposed model may therefore be applicable to other coastal aquifers, with a proper incorporation of the local geological environments.     

Experimental study of strain localization in sensitive clays

For evaluation of slope stability in materials displaying strain-softening behavior, knowledge concerning the failed state material response is of importance. Here, soft sensitive clay is studied. Such clays behave contractant at failure, which for undrained conditions yields a strain-softening behavior governed by the generation of excess pore water pressure. Strain softening is further linked with material instability and the phenomenon of strain localization. In the case of shear band formation, internal pore pressure gradients are then expected to be present for globally undrained conditions in the sensitive clay due to its low permeability. In the present study, this hypothesis and its implications on the global response and shear band properties are investigated. Utilizing an experimental setup with a modified triaxial cell allowing for shear band formation, the effect of varying the displacement rate is studied. Onset of strain localization is interpreted to occur just before or at the peak shear strength. A strong rate dependency of the softening response is observed. Increasing displacement rates give raised brittleness in terms of the slope of the global softening curve due to accumulating pore pressure. Also, reduced shear band thickness and a shear band inclination approaching 45° are obtained for increasing rates. In the context of slope failure in such materials, the rate dependency in the post-peak state opens up for a large variation in behavior, all depending on time as an important factor.     

Finiteness of spatial central configurations in the five-body problem

We strengthen a generic finiteness result due to Moeckel by showing that the number of spatial central configurations of the Newtonian five-body problem with positive masses is finite, apart from some explicitly given special cases of mass values.     

Precise U–Pb baddeleyite ages of mafic dykes and intrusions in southern West Greenland and implications for a possible reconstruction with the Superior craton

The Archaean block of southern Greenland constitutes the core of the North Atlantic craton (NAC) and is host to a large number of Precambrian mafic intrusions and dyke swarms, many of which are regionally extensive but poorly dated. For southern West Greenland, we present a U–Pb zircon age of 2990 ± 13 Ma for the Amikoq mafic–ultramafic layered intrusion (Fiskefjord area) and four baddeleyite U–Pb ages of Precambrian dolerite dykes. Specifically, a dyke located SE of Ameralik Fjord is dated at 2499 ± 2 Ma, similar to a previously reported ⁴⁰Ar/³⁹Ar age of a dyke in the Kangâmiut area. For these and related intrusions of ca. 2.5 Ga age in southern West Greenland, we propose the name Kilaarsarfik dykes. Three WNW-trending dykes of the MD3 swarm yield ages of 2050 ± 2 Ma, 2041 ± 3 Ma and 2029 ± 3 Ma. A similar U–Pb baddeleyite age of 2045 ± 2 Ma is also presented for a SE-trending dolerite (Iglusuataliksuak dyke) in the Nain Province, the rifted western block of the NAC in Labrador. We speculate that the MD3 dykes and age-equivalent NNE-trending Kangâmiut dykes of southern West Greenland, together with the Iglusuataliksuak dyke (after closure of the Labrador Sea) represent components of a single, areally extensive, radiating swarm that signaled the arrival of a mantle plume centred on what is presently the western margin of the North Atlantic craton. Comparison of the magmatic ‘barcodes’ from the Nain and Greenland portions of the North Atlantic craton with the established record from the north-eastern Superior craton shows matches at 2500 Ma, 2214 Ma, 2050–2030 Ma and 1960–1950 Ma. We use these new age constraints, together with orientations of the dyke swarms, to offer a preliminary reconstruction of the North Atlantic craton near the north-eastern margin of the Superior craton during the latest Archaean and early Palaeoproterozoic, possibly with the Core Zone craton of eastern Canada intervening.     

Expert judgements on the response of the Atlantic meridional overturning circulation to climate change

We present results from detailed interviews with 12 leading climate scientists about the possible effects of global climate change on the Atlantic Meridional Overturning Circulation (AMOC). The elicitation sought to examine the range of opinions within the climatic research community about the physical processes that determine the current strength of the AMOC, its future evolution in a changing climate and the consequences of potential AMOC changes. Experts assign different relative importance to physical processes which determine the present-day strength of the AMOC as well as to forcing factors which determine its future evolution under climate change. Many processes and factors deemed important are assessed as poorly known and insufficiently represented in state-of-the-art climate models. All experts anticipate a weakening of the AMOC under scenarios of increase of greenhouse gas concentrations. Two experts expect a permanent collapse of the AMOC as the most likely response under a 4×CO₂ scenario. Assuming a global mean temperature increase in the year 2100 of 4 K, eight experts assess the probability of triggering an AMOC collapse as significantly different from zero, three of them as larger than 40%. Elicited consequences of AMOC reduction include strong changes in temperature, precipitation distribution and sea level in the North Atlantic area. It is expected that an appropriately designed research program, with emphasis on long-term observations and coupled climate modeling, would contribute to substantially reduce uncertainty about the future evolution of the AMOC.     

Grain boundary energy as a clue to mineral segregations — A preliminary study

Dihedral angles between two grains of quartz and one of pyrrhotite, sphalerite resp. hematite are measured at triple junctions. An approach to equilibrium is noted. The sulphides have dihedral angles greater than 120 ° and the oxide less than 120 °. No significant influence of sphalerite composition on dihedral angle can be proved. It is concluded that the average grain boundary energy between two grains of quartz is smaller than that between quartz and a sulphide but greater than that between quartz and hematite. Sulphide — biotite interfaces are found to be parallel to the biotite cleavage. Parallelism is concluded to meet a requirement of minimum grain boundary energy. Assuming random distribution of grains, the interfacial area between sulphides and transparent minerals is found to be too small in comparison with that between sulphides. The sulphide clustering, observed and inferred, is suggested to depend on a combination of grain boundary energy and epitaxial growth, but may to some extent be inherited from the ore-generation stage.