Testing polymineral post-IR IRSL and quartz SAR-OSL protocols on Middle to Late Pleistocene loess at Batajnica,Serbia

The loess–palaeosol sequence of Batajnica (Vojvodina region, Serbia) is considered as one of the most complete and thickest terrestrial palaeoclimate archives for the Middle and Late Pleistocene. In order to achieve a numerical chronology for this profile, four sets of ages were obtained on 18 individual samples. Equivalent doses were determined using the SAR protocol on fine (4–11 μm) and coarse (63–90 μm) quartz fractions, as well as on polymineral fine grains by using two elevated temperature infrared stimulation methods, pIRIR₂₉₀ and pIRIR₂₂₅. We show that the upper age limit of coarse quartz OSL and polymineral pIRIR₂₉₀ and pIRIR₂₂₅ techniques is restricted to the Last Glacial/Interglacial cycle due to the field saturation of the natural signals. Luminescence ages on coarse quartz, pIRIR₂₂₅ and pIRIR₂₉₀ polymineral fine grains are in general agreement. Fine quartz ages are systematically lower than the coarse quartz and pIRIR ages, the degree of underestimation increasing with age. Comparison between natural and laboratory dose response curves indicate the age range over which each protocol provides reliable ages. For fine and coarse quartz, the natural and laboratory dose response curves overlap up to ~150 and ~250 Gy, respectively, suggesting that the SAR protocol provides reliable ages up to c. 50 ka on fine quartz and c. 100 ka on coarse quartz. Using the pIRIR₂₂₅ and pIRIR₂₉₀ protocols, equivalent doses up to ~400 Gy can be determined, beyond which in the case of the former the natural dose response curve slightly overestimates the laboratory dose response curve. Our results suggest that the choice of the mineral and luminescence technique to be used for dating loess sediments should take into consideration the reported limited reliability.     

Thallium (I) distribution in the Dubossari Reservoir of the Dniester River

Thallium (I) distribution in the Dubossari Reservoir of the Dniester River is studied. The method of inverse voltammetry is used to measure thallium (I) concentration in the water, bottom sediments, and some higher aquatic plants. In the central part of the reservoir, (where a large the Rezina-Rybnitsa Industrial Complex, producing cement and steel, is located), the concentration of thallium (I) in the investigated objects is maximum. The input of thallium (I) from the atmosphere and contaminated soil is assessed by means of measuring its concentration in Xanthoria parietina lichen and in the phytosuspension settled onto clasping-leaved pondweed (Potamogeton perfoliatus).     

Optical properties of long-range transported volcanic ash over Romania and Poland during Eyjafjallajökull eruption in 2010

After Eyjafjallajökull volcano eruption on 14 April 2010, due to a complex air mass circulation, Romania was exposed to volcanic ash and its mixture with continental aerosols. Ash particles with an average Ångström (UV-VIS) exponent of 1.4 ± 0.2 and (VIS-IR) of 1.2 ± 0.3, a color ratio (VIS-UV) of 0.54 and (IR-VIS) of 0.49, an average particle depolarization value ～9.4%, and a lidar ratio of 50 sr were retrieved on 18 April from multiwavelength Raman lidar measurements in Bucharest. Mixed volcanic ash with mineral dust particles advected from Sahara, depolarization ～12%, Ångström (UV-VIS) exponent of 1.25 ± 0.25 and (VIS-IR) of 1.45 ± 0.25, an increased color ratio (VIS-UV) of 0.61, (IRVIS) of 0.39 and lidar ratio of 53 sr were identified on 28 April. From observations in Poland conducted by an elastic lidar at 532 nm and a ceilometer at 1064 nm we retrieved an average backscatter related Ångström (VIS-IR) exponent of 1.25 ± 0.35, and a color ratio (IR-VIS) of 0.53 in the layer at about 5.5 km during the night of 16/17 April, indicating fresh ash over Warsaw.     

Bioindication of Mercury Pollution of the Dubossary Reservoir

Mercury pollution of the Dubossary Reservoir in the Dniester River was studied with the use of bioindicators (higher aquatic plants, epiphyte suspension, Xanthoria parietina lichen). The maximum mercury concentration in bioindicators is recorded in the zone near the Rezinsko-Rybnitskii Complex, which incorporates two large cement works and a metallurgical plant.__________Translated from Vodnye Resursy, Vol. 32, No. 4, 2005, pp. 464–469.Original Russian Text Copyright © 2005 by G. Munteanu, V. Munteanu.