Isotopic composition of gas hydrates in subsurface sediments from offshore Sakhalin Island, Sea of Okhotsk

Hydrate-bearing sediment cores were retrieved from recently discovered seepage sites located offshore Sakhalin Island in the Sea of Okhotsk. We obtained samples of natural gas hydrates and dissolved gas in pore water using a headspace gas method for determining their molecular and isotopic compositions. Molecular composition ratios C₁/_C2+ from all the seepage sites were in the range of 1,500–50,000, while δ¹³C and δD values of methane ranged from ?66.0 to ?63.2‰ VPDB and ?204.6 to ?196.7‰ VSMOW, respectively. These results indicate that the methane was produced by microbial reduction of CO₂. δ¹³C values of ethane and propane (i.e., ?40.8 to ?27.4‰ VPDB and ?41.3 to ?30.6‰ VPDB, respectively) showed that small amounts of thermogenic gas were mixed with microbial methane. We also analyzed the isotopic difference between hydrate-bound and dissolved gases, and discovered that the magnitude by which the δD hydrate gas was smaller than that of dissolved gas was in the range 4.3–16.6‰, while there were no differences in δ¹³C values. Based on isotopic fractionation of guest gas during the formation of gas hydrate, we conclude that the current gas in the pore water is the source of the gas hydrate at the VNIIOkeangeologia and Giselle Flare sites, but not the source of the gas hydrate at the Hieroglyph and KOPRI sites.     

Implementation of the ground level enhancement alert software at NMDB database

The European Commission is supporting the real-time database for high-resolution neutron monitor measurements (NMDB) as an e-Infrastructures project in the Seventh Framework Programme in the Capacities section. The realization of the NMDB will provide the opportunity for several applications most of which will be implemented in real-time. An important application will be the establishment of an Alert signal when dangerous solar particle events are heading to the Earth, resulting into a ground level enhancement (GLE) registered by neutron monitors (NMs). The cosmic ray community has been occupied with the question of establishing such an Alert for many years and recently several groups succeeded in creating a proper algorithm capable of detecting space weather threats in an off-line mode. A lot of original work has been done to this direction and every group working in this field performed routine runs for all GLE cases, resulting into statistical analyses of GLE events. The next step was to make this algorithm as accurate as possible and most importantly, working in real-time. This was achieved when, during the last GLE observed so far, a real-time GLE Alert signal was produced. In this work, the steps of this procedure as well as the functionality of this algorithm for both the scientific community and users are being discussed. Nevertheless, the transition of the Alert algorithm to the NMDB is also being discussed.     

Fission–track Ages and Magnetic Susceptibility of Cretaceous to Paleogene Volcanic Rocks in Southeastern Sikhote Alin, Far East Russia

Abstract: Seven zircon fission-track ages and 30 magnetic susceptibilities were measured on welded pyroclastic rocks from the Bogopol and Sijanov Groups of the Cretaceous to Paleogene volcanic rocks in the southeastern part of the eastern Sikhote Alin volcano-plutonic belt, Far East Russia. The fission-track ages range from 42. 7 Ma to 64. O Ma which indicate that both the groups are of Early Paleogene time. Two thirds of the samples from the Bogopol Group have high magnetic susceptibility values, more than 3 A- 10^-3 SI unit, which imply that they are of the magnetite–series, whereas the samples from the Sijanov Group show 3 A- 10^-3 to 8 A- 10^-5 SI unit which suggest this group of probably the ilmenite-series.
The Paleogene age and high magnetic susceptibility of the Bogopol Group are quite similar to the Paleogene igneous rocks of the San'in belt, Southwest Japan. This suggests, taking accounts of the opening of the Japan Sea, that the eastern Sikhote Alin volcano-plutonic belt continued to the San'in Belt, and that the Paleogene igneous rocks along the Japan Sea coast of Northeast Japan were situated along the volcanic front of the eastern Sikhote Alin volcano-plutonic belt.     

Biostratigraphy of the Late Middle Pleistocene (Middle Neopleistocene) of the Southern Urals region

A summary of published and unpublished materials on the stratigraphy of the Late Middle Pleistocene (Middle Neopleistocene according to the Russian stratigraphic scheme) of the Southern Urals region is given. Deposits of different origin in the regional stratigraphic units are characterized. The results of mammalian investigations provide the basis for the stratigraphical subdivision. Mollusca and palynology are used for the reconstruction of the palaeoenvironments. The stratigraphical positions of the main Middle Neopleistocene localities and precise definitions of the stratigraphical scheme of the Southern Urals region are discussed. The Southern Urals subdivisions are correlated with the Western European stratigraphical schemes (Holsteinian–Saalian interval).     

Fluorite Deposits at Voznesenka in the Khanka Massif, Russia: Geology and Age of Mineralization

Abstract. A huge fluorite deposit at Voznesenka in the Khanka massif, Far East Russia is concluded to have formed at ca. 450 Ma in Late Ordovician time based on the K‐Ar ages for Li‐micas in the fluorite ore and greisenized leucogranite within the deposit. This conclusion is inconsistent with the current view of Devonian mineralization that stemmed from widely scattered whole‐rock Rb‐Sr isotope data for the heterogeneous leucogranite stocks influenced by strong alteration. The Voznesenka and neighboring fluorite deposits may have formed in Cambrian limestone in relation to the intrusion of the Li‐F‐rich felsic magma which has a similar chemistry to representative Li‐F‐rich felsic rocks including topaz granite and ongonite or topaz rhyolite; these rocks may be classified as a specific group of highly fractionated felsic magmas. Biotite granite plutons exposed in the Voznesenka district are divided in age into two groups based on the CHIME age data for zircon, monazite and xenotime: Ordovician and Permian. The Ordovician plutons seem to be coeval to the fluorite deposits and are characterized by F‐rich chemistry, reduced nature and association of tin mineralization with the deposition of fluorite and tourmaline. The biotite granite magmas of initially enhanced F contents could have been highly fractionated to form Li‐F‐rich leucogranite cupolas that provided fluorite deposits within the host limestone. Future prospecting for similar fluorite deposits is to be focused on areas of intersection between Ordovician Li‐F‐rich granite and Cambrian carbonate sequences. The Permian granite of southeastern margin of the Grodekovo batholith is characterized by lesser F content, oxidized nature and the lack of tin and fluorite mineralization in contrast to the Ordovician granite. The result of Permian age does not support the current view of Silurian age for the batholith and requires overall chronological reinvestigation in connection with the tectonic history of the Khanka massif because the Grodekovo is a representative of Paleozoic batholiths in Primorie.     

Biostratigraphy of the Upper Pleistocene (Upper Neopleistocene)–Holocene deposits of the Lemeza River valley of the Southern Urals region (Russia)

Numerous caves and terraces with late Late Pleistocene (Upper Neopleistocene according to the Russian stratigraphic scale)–Holocene deposits are located in the Lemeza River valley in the surroundings of the Atysh waterfall, the native reserve territory of the Bashkortostan Republic. Lemeza River runs in the southern part of the western slope of the Urals and belongs to the Belaya River valley system (Russian Federation). A summary of the biostratigraphical investigations between 1992 and 2007 in this area is given. Deposits of cave and fluvial origin are characterized in the framework of the regional stratigraphy. The results of mammalian investigations and radiocarbon dating provide the basis for the stratigraphical subdivision. Palynology, mollusca, fishes, amphibian and reptiles are used for the reconstruction the palaeoenvironments. The Southern Urals stratigraphic subdivisions are correlated with Western European (Weichselian-Holocene), Eastern European (Russia) (Leningrad–Ostashkov–Shuvalov) and Uralian (Nevyansk–Polar Urals–Gorbunovsky) stratigraphic schemes.     

On the effects of resolution in dissipationless cosmological simulations

We present a study of numerical effects in dissipationless cosmological simulations. The numerical effects are evaluated and studied by comparing the results of a series of 64³-particle simulations of varying force resolution and number of time-steps, performed using three of the N -body techniques currently used for cosmological simulations: the Particle–Mesh (PM), the Adaptive Particle–Particle–Particle–Mesh (AP³M) and the newer Adaptive Refinement Tree (ART) codes. This study can therefore be interesting both as an analysis of numerical effects and as a systematic comparison of different codes.
We find that the AP³M and the ART codes produce similar results given that convergence is reached within the code type. We also find that numerical effects may affect the high-resolution simulations in ways that have not been discussed before. In particular, our study revealed the presence of two-body scattering, the effects of which can be greatly amplified by inaccuracies in time integration. This process appears to affect the correlation function of matter, the mass function, the inner density of dark matter haloes and other statistics at scales much larger than the force resolution, although different statistics may be affected in a different fashion. We discuss the conditions for which strong two-body scattering is possible and discuss the choice of the force resolution and integration time-step. Furthermore, we discuss recent claims that simulations with force softening smaller than the mean interparticle separation are not trustworthy and argue that this claim is incorrect in general, and applies only to the phase-sensitive statistics. Our conclusion is that, depending on the choice of mass and force resolution and the integration time-step, a force resolution as small as 0.01 of the mean interparticle separation can be justified.     

Kamenetsk—A new impact structure in the Ukrainian Shield

The Kamenetsk impact structure is a deeply eroded simple crater that formed in crystalline rocks of the Ukrainian Shield. This study presents structural, lithologic, and shock metamorphic evidence for an impact origin of the Kamenetsk structure, which was previously described as a paleovolcano. The Kamenetsk structure is an oval depression that is 1.0–1.2 km in diameter and 130 m deep. The structure is deeply eroded, and only the lower part of the sequence of lithic breccia has been preserved in the deepest part of the crater to recent time, while the predominant part of impact rocks and postimpact sediments was eroded. Manifestations of shock metamorphism of minerals, especially planar deformation features in quartz and feldspars, were determined by petrographic investigations of lithic breccia that allowed us to determine the impact origin of the Kamenetsk structure. The erosion of the crater and surrounding target to a minimal depth of 220 m preceded the deposition of the postimpact sediments. The time of the formation of the Kamenetsk structure is bracketed within a wide interval from 2.0 to 2.1 Ga, the age of the crystalline target rocks, to the Late Miocene age of the sediments overlaying the crater. The deep erosion of the structure suggests it is probably Paleozoic in age.