Parameterization of iron and manganese cycling in the Black Sea suboxic and anoxic environment

New and published data on the distribution and speciation of manganese and iron in seawater are analyzed to identify and parameterize major biogeochemical processes of their cycling within the suboxic (15.6σ_t16.2) and anoxic layers (σ_t16.2) of the Black Sea. A steady-state transport-reaction model is applied to reveal layering and parameterize kinetics of redox and dissolution/precipitation processes. Previously published data on speciation of these elements in seawater are used to specify the nature of the transformations. Two particulate species of iron (Fe(III) hydroxide and Fe(II) sulfide) are necessary to adequately parameterize the vertical profile of suspended iron, while three particulate species (hydrous Mn(IV) oxide, Mn(II) sulfide, and Mn(II) carbonate) are necessary to describe the profile of suspended manganese. In addition to such processes as mixing and advection, precipitation, sinking, and dissolution of manganese carbonate are found to be essential in maintaining the observed vertical distribution of dissolved Mn(II). These results are used to interpret the observed difference in the form of vertical distribution for dissolved Mn(II) and Fe(II). Redox transformations of iron and manganese are coupled via oxidation of dissolved iron by sinking suspended manganese at σ_t16.2±0.2 kg m⁻³. The particulate manganese, necessary for this reaction, is supplied through oxidation of dissolved Mn(II). The best agreement with observations is achieved when nitrate, rather than oxygen, is set to oxidize dissolved Mn(II) in the lower part of the suboxic layer (15.90σ_t16.2). The results support the idea that, after sulfides of these metals are formed, they sink with particulate organic matter. The sinking rates of the particles and specific rates of individual redox and dissolved-particulate transformations have been estimated by fitting the vertical profile of the net rate.     

Proterozoic mafic magmatism in Siberian craton: An overview and implications for paleocontinental reconstruction

We present a summary of late Paleoproterozoic to Neoproterozoic mafic magmatism in the Siberian craton, including recently published U–Pb and ⁴⁰Ar–³⁹Ar dates. These new precise ages suggest that at least some of the previously published K–Ar ages of Siberian mafic bodies should be ignored. The time–space geochronological chart, or the ‘barcode’ of mafic magmatic events shows significant differences between northern and southern Siberia. Both are characterized by ∼1900–1700 Ma magmatic events, but then there was an almost 1 Ga mafic magmatic ‘pause’ in south Siberia until ∼800 Ma. Meanwhile there are indications of multiple mafic magmatic events in North Siberia (Anabar shield and Olenek uplift) between ∼1600 and 1000 Ma. A series of magmatic events probably related to the breakup of Rodinia occurred in southern Siberia after ∼800 Ma. So far, there are no indications of late Neoproterozoic mafic magmatism in North Siberia. Ca. 1000–950 Ma mafic sills were reported from Meso- to Neo-Proterozoic sedimentary successions in the Sette-Daban area on the east side of the Siberian craton, but their tectonic setting is debated. Recent Ar–Ar dates of ∼1750 Ma for NW-trending dykes in the Aldan and Anabar shields, together with similar-age NNE-trending Baikal uplift dykes in south-eastern Siberia suggest the existence of a giant radial dyke swarm possibly related to a mantle plume centred in the Vilyui River area.     

Composition of the Ordovician lithospheric mantle: Evidence from the study of peridotite xenoliths from camptonite of the Sangilen highland,central Asian fold belt

Doklady Earth Sciences -     

On the radiative and thermodynamic properties of the cosmic radiations using COBE FIRAS instrument data: IV. Sunyaev-Zel’dovich ($\mu$-type) distortion effect

The Sunyaev-Zel’dovich (SZ) effect represents a small spectral distortion to the cosmic microwave background (CMB) radiation, caused by the Compton scattering of CMB photons by the hot gas of galaxy clusters. In an early stage of universe, the SZ effect generates \(\mu\)-type of distortions for the CMB spectrum. A \(\mu\)-type distortion is created between the double Compton scattering decoupling (\(z \sim 10^{6}\)) and the thermalization decoupling by the Compton scattering (\(z \sim 10^{5}\)). In this case, to describe the small spectral distortion of the CMB spectrum, we use the Bose-Einstein (\(\mu\)-type) distribution with a non-zero chemical potential. At present, it is interesting to investigate the effect of this spectral distortion on the integral characteristics of the Bose-Einstein (\(\mu\)-type) spectrum. The thermal radiative and thermodynamic functions are such integral characteristics. These functions are as follows: a) the total radiation power per unit area; b) total energy density; c) number density of photons; d) grand potential density; e) Helmholtz free energy density; f) entropy density; g) heat capacity at constant volume; h) enthalpy density; and i) pressure. Precise analytical expressions are obtained for the temperature dependences of these functions. Using the observational data obtained by the COBE FIRAS, PIXIE, PRISM, and Planck missions, the thermal radiative and thermodynamic functions are calculated. A comparative analysis of the results obtained with the results for the same functions of the CMB spectrum at \(T = 2.72548~\mbox{K}\) is carried out. Very small distortions are observed for the thermal radiative and thermodynamic functions. In the redshift range \(10^{5} < z < 3 \times10^{6}\), these functions are calculated. The expressions are obtained for new astrophysical parameters, such as the entropy density/Boltzmann constant and number density, created by the Bose-Einstein (\(\mu\)-type) spectrum.     

Wide-band high linearity active dipole for low frequency radio astronomy

We have developed an active dipole that is intended for use in new generation low frequency array applications. The preamplifier of the active dipole has very high linearity (input IP2 = 70 dBm, input IP3 = 31 dBm) and low noise temperature (100?C360 K). The frequency dependence of the dipole impedance and the match between the dipole and preamplifier have been optimized to achieve Galactic noise limited operation. The ratio between the antenna temperature due to Galactic noise and the noise temperature of the preamplifier is 10 ± 1.5 dB over the whole 10 to 70 MHz range. The total cost of the active cross-dipole is 220 euro.     

Modelling of thermochemical plumes and implications for the origin of the Siberian traps

Thermochemical plumes form at the base of the lower mantle as a consequence of heat flow from the outer core and the presence of local chemical doping that decreases the melting temperature. Theoretical and experimental modelling of thermochemical plumes show that the diameter of a plume conduit remains practically constant during plume ascent. However, when the top of a plume reaches a refractory layer, whose melting temperature is higher than the melt temperature in the plume conduit, a mushroom-shaped plume head develops. Main parameters (melt viscosity, ascent time, ascent velocity, temperature differences in the plume conduit, and thermal power) are presented for a thermochemical plume ascending from the core–mantle boundary. In addition, the following relationships are developed: the pressure distribution in the plume conduit during the ascent of a plume, conditions for eruption-conduit formation, the effect of the P–T conditions and controls on the shape and size of a plume top, heat transfer between a thermochemical plume and the lithosphere (when the plume reaches the bottom of a refractory layer in the lithosphere), and eruption volume versus the time interval t₁ between plume formation and eruption. These relationships are used to determine thermal power and time t₁ for the Tunguska syneclise and the Siberian traps as a whole.

The Siberian and other trap provinces are characterized by giant volumes of lavas and sills formed a very short time period. Data permit a model for superplumes with three stages of formation: early (variable picrites and alkali basalts), main (tholeiite plateau basalts), and final (ultrabasic and alkaline lavas and intrusions). These stages reflect the evolution of a superplume from the ascent of one or several independent plumes, through the formation of thick lenses of mantle melts underplating the lithosphere and, finally, intrusion and extrusion of differentiated mantle melts. Synchronous syenite–granite intrusions and bimodal volcanism abundant in the margins of the Siberian traps are the result of melting of the lower crust at depths of 65–70 km under the effect of plume melts.     

The age of camptonite dikes of the Agardag alkali-basalt complex (western Sangilen): results of Ar/Ar and U/Pb dating

A camptonite dike swarm (Agardag alkali-basalt complex) in the western part of the Sangilen Upland abounds in mantle xenoliths. Mineralogical, petrographic, and petrochemical studies show that the dikes are composed of lamprophyres of two groups, basic and ultrabasic. Ar/Ar dating of amphibole and phlogopite megacrysts gives an intrusion age for the dikes of 443.0 ± 1.3 Ma. ²⁰⁶Pb/²³⁸U dating of zircon from a glomeroporphyritic intergrowth in camptonite from one of the dikes yielded a core age of 489.0 ± 5.4 Ma. This corresponds to the time of formation of the Chzhargalanta granite–leucogranite complex (489.4 ± 2.6 Ma). The ²⁰⁶Pb/²³⁸U age of the zircon rim is 444.0 ± 7.5 Ma. The ages obtained by Ar/Ar dating of amphibole and biotite megacrysts and by U/Pb dating of the magmatic rim of zircon crystal from the camptonite coincide within the dating error, which indicates that the camptonite dikes formed in the Late Ordovician. These dikes are the oldest-known example of mantle-derived xenoliths in mafic volcanic rocks from an off-craton setting. These are samples of the Upper Ordovician lithospheric mantle.