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31.
Response surface methodology (RSM) was applied to study the combined effects of the various parameters namely, pH, biosorbent dosage, cadmium concentration and temperature, and to optimize the process conditions for the maximum removal of cadmium using Psidium guvajava L. leaf powder. In order to obtain the mutual interactions between the variables and to optimize these variables, a 24 full factorial central composite design using RSM was employed. The analysis of variance (ANOVA) of the quadratic model demonstrates that the model was highly significant. The model was statistically tested and verified by experimentation. A maximum cadmium removal of 93.2% was obtained under the following optimum conditions: aqueous cadmium concentration 40.15 mg/L, adsorbent dosage 0.5 g/50 mL solution, pH 5.0, and temperature (35°C). The value of desirability factor obtained was 1. 相似文献
32.
Hydrogeochemistry of the Koyna River basin,India 总被引:1,自引:1,他引:0
Pradeep Kumar Naik A. K. Awasthi A. V. S. S. Anand P. N. Behera 《Environmental Earth Sciences》2009,59(3):613-629
Hydrogeochemistry of the Koyna River basin, famous for the Koyna earthquake (magnitude 7) of 1967, has been studied. Basalt
is the primary aquifer; laterites, alluvium, and talus deposits form aquifers of secondary importance. Groundwater generally
occurs under water table conditions in shallow aquifers. Deeper aquifers are associated only with basalts. One hundred and
87 water samples were collected from various sources, such as dugwells, borewells, springs, and surface water, including 40
samples for analysis of iron. Only major constituents were analyzed. Analyses show that the concentrations of Ca2+ exceed that of Mg2+ in almost all water samples; the concentrations of Na+ are generally next to Ca2+ and are always higher than that of K+; and CO3
2– and SO4
2– are very low and are often negligible. Groundwater in borewells tapping deeper aquifers has higher mineralization compared
to that in dugwells representing shallow aquifers. Majority of the water samples are dominated by alkaline earths (Ca2+, Mg2+) and weak acids (HCO3
−, CO3
2–). Groundwater from shallow aquifers is generally calcium-bicarbonate type (53%) and calcium-magnesium-bicarbonate type (27%).
In case of deeper aquifer, it is mostly calcium-magnesium-bicarbonate type (29%), sodium-bicarbonate type (24%), calcium-bicarbonate
type (19%), calcium-magnesium-sodium-bicarbonate type (19%) and sodium-calcium-bicarbonate type (9%). Groundwater water is
generally fit for drinking and irrigation purposes, except in the lower reaches of the Koyna River basin, which is affected
by near water logging conditions. 相似文献
33.
T. L. Krylova M. S. Pandian N. S. Bortnikov Vijay Anand S N. V. Gorelikova V. G. Gonevchuk P. G. Korostelev 《Geology of Ore Deposits》2012,54(4):276-294
Formation conditions of orebodies and conditions of wolframite deposition at the Degana tungsten deposits in Rajasthan, India and the Tigrinoe tin-tungsten deposit in the Russian Far East were studied. Differences in the composition and state of fluid systems were established by microthermometric study of fluid inclusions (FI) and thorough petrographic examination of FI. At the Degana deposit, the ore veins in granite were formed from K-Na-Ca-(Mg, Fe, etc.) chloride solutions with a salinity up to 36 wt % NaCl equiv at a temperature of >420 to 120°C and under a pressure reaching 1550 bar. The formation temperature of the orebodies hosted in breccia reached 450°C and pressure was below 400 bar. The salinity of mainly Nachloride aqueous solutions was no higher than 18 wt % NaCl equiv. At the Tigrinoe deposit, the temperature during formation of quartz-wolframite-cassiterite veins varied from 420 to 240°C and the pressure was no higher than 300 bar. The salt concentration of Na-chloride solutions was 7-3 wt %. Wolframite crystallized at the very beginning of ore deposition. Probable sources of fluids are discussed. It is suggested that the factors controlling wolframite deposition could have been different even at the same deposit. 相似文献
34.
F. A. J. Abernethy A. B. Verchovsky N. A. Starkey M. Anand I. A. Franchi Monica M. Grady 《Meteoritics & planetary science》2013,48(9):1590-1606
Angrites are a small group of ancient basaltic achondrites, notable for their unusual chemistry and extreme volatile depletion. No comprehensive study of indigenous light elements currently exists for the group. Measurement of the abundances and isotopic composition of carbon and nitrogen could provide information pertaining to the evolution of the angrite parent body. Bulk‐sample stepped combustion analyses of five angrites and a glass separate from D'Orbigny were combined with earlier data and acid dissolution experiments of carbonates found in D'Orbigny to compile an inventory of indigenous carbon and nitrogen. Indigenous carbon combusted between 700 °C and 1200 °C, with abundances of 10–140 ppm and a mass‐weighted δ13C of ?25 to ?20‰ with the exception of D'Orbigny (δ13C approximately ?5‰). Nitrogen was released at 850–1200 ºC, 1–20 ppm with a δ15N ?3‰ to +4‰; again, D'Orbigny (δ15N approximately +20 to +25‰) was an exception. We interpret these components as largely indigenous and decoupled; the carbon in graphitic or amorphous form, while the nitrogen is present as a dissolved component in the silicates. No relationship with the textural sub‐classification of angrites is apparent. We suggest that the angrite parent body contains a reservoir of reduced carbon and thus may have undergone a change in redox conditions, although the timing and mechanism for this remain unclear. 相似文献
35.
The Late Cretaceous (Cenomanian to Coniacian) marine sediments of central India prevalently known as ‘Bagh Beds,’ have been deposited in the E-W extending Narmada Basin. The stratigraphy of these Cenomanian — Coniacian sediments has been reviewed and summarized. The Bagh Beds have been found to consist of three formations: Nimar Sandstone, Nodular Limestone and Corallian Limestone in ascending order. Main emphasis has been given to Nodular Limestone Formation (Turonian), which is the most fossiliferous horizon of the Bagh Beds. Nodular Limestone Formation has more or less alternating bands of varying thickness of nodular limestone and marl. It yielded numerous ammonoid specimens, which have been found to belong to a morphologically highly variable ammoniod taxon Placenticeras mintoi Vredenburg. 相似文献
36.
Thick, commonly lateritic, regoliths are widespread in inter-tropical regions of the world and present particular challenges in exploration. These are best tackled through a sound understanding of the evolution of the landscapes in which they occur. The regoliths formed under humid, warm to tropical conditions and, although they may have been modified by later climatic changes, i.e., to more humid or more arid conditions, many chemical and mineralogical characteristics are retained. These include the geochemical expressions of concealed mineralization. Erosional and depositional processes control the preservation and occurrence of specific regolith units that may be used as sample media and, in turn, target size, element associations and contrast, thereby influencing sampling procedures, analysis and data interpretation. These parameters are best summarized in terms geochemical dispersion models based on the degree of preservation of the pre-existing lateritic regolith. Regolith–landform mapping permits an assessment of the terrain in terms of such models. In relict regolith–landform regimes, in which the lateritic regolith is largely preserved, broad multi-element anomalies in the upper ferruginous horizons (lateritic residuum) can be detected using sample intervals of 1 km or more. In contrast, in erosional regimes, where this material is absent, anomalies in upper saprolite, and the soil and lag derived from it, are more restricted in area and closer sampling intervals, (200×40 m or less) may be necessary. Lag and soil are, generally, ineffective in depositional areas, except where the sediments are very thin (e.g.,<2 m) or overburden provenance can be established. Stratigraphic drilling is necessary to establish whether the overburden overlies a buried lateritic horizon or an erosion surface cut in saprolite. Lateritic residuum remains an excellent sample medium if present, again with widespread haloes, but where it is absent, leaching and the restricted haloes in upper saprolite present formidable problems. Ferruginous saprolite or composites across the unconformity may be effective, but otherwise carefully targeted drilling and sampling through saprolite and saprock may be necessary. Partial extraction analyses have yet to demonstrate significant results except in very specific environments. In arid regions, pedogenic carbonate (calcrete, caliche) may be a valuable sample medium for Au exploration, principally in erosional regimes, and in depositional areas where the overburden is shallow. Sample intervals range from 1 km for regional surveys, through to 100×20 m in prospect evaluation. Saprolite is an essential sample medium in all landform environments, but the restricted halos and possibility of leaching requires that drilling and sampling should be at close intervals. 相似文献
37.
The characteristics of directional spread parameters at intermediate water depth are investigated based on a cosine power ‘2s' directional spreading model. This is based on wave measurements carried out using a Datawell directional waverider buoy in 23 m water depth. An empirical equation for the frequency dependent directional spreading parameter is presented. Directional spreading function estimated based on the Maximum Entropy Method is compared with those obtained using a cosine power ‘2s' parameter model. A set of empirical equations relating the directional spreading parameter corresponding to the peak of wave spectrum to other wave parameters like significant wave height and period are obtained. It shows that the wave directional spreading at peak wave frequency can be related to the non-linearity parameter, which allows estimation of directional spreading without reference to wind information. 相似文献
38.
39.
Yizhao Gao Anand Padmanabhan Junjun Yin Guofeng Cao 《International journal of geographical information science》2018,32(3):425-449
Tracking spatial and temporal trends of events (e.g. disease outbreaks and natural disasters) is important for situation awareness and timely response. Social media, with increasing popularity, provide an effective way to collect event-related data from massive populations and thus a significant opportunity to dynamically monitor events as they emerge and evolve. While existing research has demonstrated the value of social media as sensors in event detection, estimating potential time spans and influenced areas of an event from social media remains challenging. Challenges include the unstable volumes of available data, the spatial heterogeneity of event activities and social media data, and the data sparsity. This paper describes a systematic approach to detecting potential spatiotemporal patterns of events by resolving these challenges through several interrelated strategies: using kernel density estimation for smoothed social media intensity surfaces; utilizing event-unrelated social media posts to help map relative event prevalence; and normalizing event indicators based on historical fluctuation. This approach generates event indicator maps and significance maps explaining spatiotemporal variations of event prevalence to identify space-time regions with potentially abnormal event activities. The approach has been applied to detect influenza activity patterns in the conterminous US using Twitter data. A set of experiments demonstrated that our approach produces high-resolution influenza activity maps that could be explained by available ground truth data. 相似文献
40.