Soil water residence times and solute uptake on a dolomite bedrock—preliminary results

Calcium and magnesium levels have been monitored in slope foot drainage waters on a dolomite bedrock. Both calcium and magnesium rich pulses occur. Short term dissolution experiments demonstrate high calcium levels in solution while other authors have suggested that long residence time groundwater has relatively high levels of magnesium due to calcite precipitation. Patterns of field fluctuations in Ca: Mg ratios can thus be tentatively interpreted in terms of short residence time water of high calcium content mixing with long residence time water of high magnesium content. Fluorometric dye tracing has been used to indicate the orders of magnitude of soil water residence times, suggesting that quickflow components are resident in the system for a few hours to a few days. Further work is in progress.     

A moving grid finite-element model of the bulk properties of the atmospheric boundary layer

A moving-grid finite-element model has been developed to model numerically the vertically integrated properties of the atmospheric boundary layer (ABL) in one dimension. The model equations for mean wind velocity and potential temperature are combined with a surface energy budget and predictive equations for boundary-layer height to simulate both stable and unstable ABLs. The nodal position defining the top of the boundary layer is one of the model unknowns and is determined by boundary-layer dynamics. The finite-element method, being an integral method, has advantages of accurate representation of both bulk values and their vertical derivatives, the latter being essential properties of the nocturnal boundary layer. Compared with observations and results of other models, the present model predicts bulk properties very well while retaining a simple and economical form.Journal Paper No. J-12996 of the Iowa Agriculture and Home Economics Experiment Station, Ames, Iowa, Project No. 2779.     

Carbon fluxes from eroding peatlands – the carbon benefit of revegetation following wildfire

Peatlands are among the largest long‐term soil carbon stores, but their degradation can lead to significant carbon losses. This study considers the carbon budget of peat‐covered sites after restoration, following degradation by past wildfires. The study measured the carbon budget of eight sites: four restored‐revegetated sites, two unrestored bare soil control sites, and two intact vegetated controls over two years (2006–2008). The study considered the following flux pathways: dissolved organic carbon (DOC); particulate organic carbon (POC); dissolved carbon dioxide (CO₂); primary productivity; net ecosystem respiration, and methane (CH₄). The study shows that unrestored, bare peat sites can have significant carbon losses as high as 522 ± 3 tonnes C/km²/yr. Most sites showed improved carbon budgets (decreased source and/or increased sink of carbon) after restoration; this improvement was mainly in the form of a reduction in the size of the net carbon source, but for one restored site the measured carbon budget after four years of restoration was greater than observed for vegetated controls. The carbon sequestration benefit of peatland restoration would range between 122 and 833 tonnes C/km²/yr. Copyright © 2011 John Wiley & Sons, Ltd.     

A laboratory study of the turbulent ekman layer

Abstract

Comparing characteristics of a turbulent Ekman boundary layer in a rotating apparatus with atmospheric observations and theories, we find that the similarity relations derived by Kazanski and Monin, and others, scale both laboratory and field data quite well, especially considering that the Coriolis parameter is larger by a factor of 10⁵ in the experiment than it is in the atmosphere. Eddy viscosity models and Deardorff's numerical model predict the properties of both with varying degrees of success. High frequency spectra of velocity fluctuations scale with the Kolmogoroff length and time scales. Both magnitude and direction of the surface shear stress were measured directly, with a heated film stress gauge.     

ANISOTROPIC TRAVELTIME TOMOGRAPHY

Velocity estimation technique using seismic data is often based on time/distance equations which are independent of direction, and even though we now know that many rocks are quite anisotropic, useful results have been obtained over the years from these isotropic estimates. Nevertheless, if velocities are significantly direction-dependent, then the isotropic assumption may lead to serious structural interpretation errors. Additionally, information on angle-dependence may lead to a better understanding of the lithology of the rocks under measurement. VSP and cross-well data may each lack the necessary aperture to estimate more than two velocity parameters for each wave type, and if the data straddle a symmetry axis, then these may be usefully chosen to be the direct velocities (from time-and-distance measurements along the axis) and NMO velocities (from differential time-offset measurements). These sets of two parameters define ellipses, and provide intermediate models for the variation of velocity with angle which can later be assembled and translated into estimates of the elastic moduli of the rocks under scrutiny. If the aperture of the measurements is large enough e.g. we have access to both VSP and cross-well data, we divide the procedure into two independent steps, first fitting best ellipses around one symmetry axis and then fitting another set around the orthogonal axis. These sets of four elliptical parameters are then combined into a new, double elliptical approximation. This approximation keeps the useful properties of elliptical anisotropy, in particular the simple relation between group and phase velocities which simplifies the route from the traveltimes measurements to the elastic constants of the medium. The inversion proposed in this paper is a simple extension of well-known isotropic schemes and it is conceptually identical for all wave types. Examples are shown to illustrate the application of the technique to cross-well synthetic and field P-wave data. The examples demonstrate three important points: (a) When velocity anisotropy is estimated by iterative techniques such as conjugate gradients, early termination of the iterations may produce artificial anisotropy. (b) Different components of the velocity are subject to different type of artifacts because of differences in ray coverage, (c) Even though most rocks do not have elliptical dispersion relations, our elliptical schemes represent a useful intermediate step in the full characterization of the elastic properties.     

Late Cainozoic geology,soils, and landscape evolution of the Torrens Creek area,North Queensland

The major features of the geology and geomorphology of the semi‐arid, tropical Torrens Creek area of North Queensland are described. The evolution of the landscape through the late Cainozoic is discussed with reference to three phases of landscape instability and erosion, each separated by phases of stability during which weathering and soil formation proceeded. These erosional periods were probably initiated by episodic uplift of the Great Divide region. Tentative correlations with landscape events in the nearby Nulla Basalt Province suggest that soil profile development probably occurred during late Pliocene (2.3–2.0 m.y. ago), mid‐Pleistocene (1.3–1.1 m.y. ago), and in Quaternary (less than 0.1 m.y. ago) times.     

A mathematical model of concentrate solids content for the wet drum magnetic separator

Low concentrate density from wet drum magnetic separators in dense medium circuits can cause operating difficulties due to inability to obtain the required circulating medium density and, indirectly, high medium solids losses. The literature is almost silent on the processes controlling concentrate density. However, the common name for the region through which concentrate is discharged—the squeeze pan gap—implies that some extrusion process is thought to be at work. There is no model of magnetics recovery in a wet drum magnetic separator, which includes as inputs all significant machine and operating variables.A series of trials, in both factorial experiments and in single variable experiments, was done using a purpose built rig which featured a small industrial scale (700 mm lip length, 900 mm diameter) wet drum magnetic separator. A substantial data set of 191 trials was generated in this work. The results of the factorial experiments were used to identify the variables having a significant effect on magnetics recovery.It is proposed, based both on the experimental observations of the present work and on observations reported in the literature, that the process controlling magnetic separator concentrate density is one of drainage. Such a process should be able to be defined by an initial moisture, a drainage rate and a drainage time, the latter being defined by the volumetric flowrate and the volume within the drainage zone. The magnetics can be characterised by an experimentally derived ultimate drainage moisture. A model based on these concepts and containing adjustable parameters was developed. This model was then fitted to a randomly chosen 80% of the data, and validated by application to the remaining 20%. The model is shown to be a good fit to data over concentrate solids content values from 40% solids to 80% solids and for both magnetite and ferrosilicon feeds.     

Isotopic constraints on growth conditions of multiphase calcite–pyrite–barite concretions in Carboniferous mudstones

Carbonate concretions in the Lower Carboniferous Caton Shale Formation contain diagenetic pyrite, calcite and barite in the concretion matrix or in different generations of septarian fissures. Pyrite was formed by sulphate reduction throughout the sediment before concretionary growth, then continued to form mainly in the concretion centres. The septarian calcites show a continuous isotopic trend from δ¹³C=?28·7‰ PDB and δ¹⁸O=?1·6‰ PDB through to δ¹³C=?6·9‰ PDB and δ¹⁸O=?14·6‰ PDB. This trend arises from (1) a carbonate source initially from sulphate reduction, to which was added increasing contributions of methanogenic carbonate; and (2) burial/temperature effects or the addition of isotopically light oxygen from meteoric water. The concretionary matrix carbonates must have at least partially predated the earliest septarian cements, and thus used the same carbonate sources. Consequently, their isotopic composition (δ¹³C=?12·0 to ?10·1‰ PDB and δ¹⁸O=?5·7 to ?5·6‰ PDB) can only result from mixing a carbonate cement derived from sulphate reduction with cements containing increasing proportions of carbonate from methanogenesis and, directly or indirectly, also from skeletal carbonate. Concretionary growth was therefore pervasive, with cements being added progressively throughout the concretion body during growth. The concretions contain barite in the concretion matrix and in septarian fissures. Barite in the earlier matrix phase has an isotopic composition (δ³⁴S=+24·8‰ CDT and δ¹⁸O=+16·4‰ SMOW), indicating formation from near‐surface, sulphate‐depleted porewaters. Barites in the later septarian phase have unusual isotopic compositions (δ³⁴S=+6 to +11‰ CDT and δ¹⁸O=+8 to +11‰ SMOW), which require the late addition of isotopically light sulphate to the porewaters, either from anoxic sulphide oxidation (using ferric iron) or from sulphate dissolved in meteoric water. Carbon isotope and biomarker data indicate that oil trapped within septarian fissures was derived from the maturation of kerogen in the enclosing sediments.     

Cenozoic tectonic events at the border of the Paraná Basin, São Paulo, Brazil

In the last decade, even in areas that had been considered tectonically stable, a great amount of Cenozoic, including the Quaternary period, structural data have been collected throughout Brazil. The main goal of this study is to describe the Cenozoic structures and tectonic evolution of an area that is located at the border of the Paraná Basin in the state of São Paulo.The research methods consisted of the analysis of: (1) brittle structure data, mainly conjugate fractures and fault slip data; (2) lineaments traced on air photos and TM Landsat and radar images; and (3) a second-order base surface map.The study area, during the Cenozoic, has been affected by five strike–slip tectonic events, which generated mainly strike–slip faults, and secondarily normal and reverse ones. The events were named, from the oldest to the youngest, E1-NE, E2-EW, E3-NW, E4-NS, and E5-NNE; and the maximum principal stresses σ1 strike approximately NE–SW, E–W, NW–SE, N–S, and NNE–SSW, respectively. Event E2-EW seems to have been contemporaneous with the deposition of the Rio Claro Formation, the most important Cenozoic deposit of probable Neogenic age, and also to have controlled the distribution of its deposits. Event E3-NW was the strongest one in the area, as is pointed out by structural data, and the maximum principal stress σ1 of event E5-NNE is partially concordant with the orientation of σH-max of well break-out data in the Paraná Basin, suggesting a Neotectonic activity for this event. Finally, discontinuities parallel and correlated to the directions of strike–slip faults of the Cenozoic events seem to have actively controlled the sculpturing of the relief in the study area.