The dissociation constants of carbonic acid in seawater at salinities 5 to 45 and temperatures 0 to 45°C

The pK₁^* and pK₂^* for the dissociation of carbonic acid in seawater have been determined from 0 to 45°C and S = 5 to 45. The values of pK₁^* have been determined from emf measurements for the cell:

Pt](1 − X)H2 + XCO2|NaHCO3, CO2 in synthetic seawater|AgC1; Ag

where X is the mole fraction of CO₂ in the gas. The values of pK₂^* have been determined from emf measurements on the cell:

Pt, H2(g, 1 atm)|Na2CO3, NaHCO3 in synthethic seawater|AgC1; Ag

The results have been fitted to the equations:

lnK^*₁ = 2.83655 − 2307.1266/T − 1.5529413 lnT + (−0.20760841 − 4.0484/T)S^0.5 + 0.08468345S − 0.00654208S¹

InK^*₂ = −9.226508 − 3351.6106/T− 0.2005743 lnT + (−0.106901773 − 23.9722/T)S^0.5 + 0.1130822S − 0.00846934S^1.5

where T is the temperature in K, S is the salinity, and the standard deviations of the fits are σ = 0.0048 in lnK₁^* and σ = 0.0070 in lnK₂^*.Our new results are in good agreement at S = 35 (±0.002 in pK₁^*and ±0.005 in pK₂^*) from 0 to 45°C with the earlier results of Goyet and Poisson (1989). Since our measurements are more precise than the earlier measurements due to the use of the Pt, H₂|AgCl, Ag electrode system, we feel that our equations should be used to calculate the components of the carbonate system in seawater.     

Petroleum prospectivity of the Canada Basin, Arctic Ocean

Reconnaissance seismic reflection data indicate that Canada Basin is a >700,000 sq. km. remnant of the Amerasia Basin of the Arctic Ocean that lies south of the Alpha-Mendeleev Large Igneous Province, which was constructed across the northern part of the Amerasia Basin between about 127 and 89-83.5 Ma. Canada Basin was filled by Early Jurassic to Holocene detritus from the Beaufort-Mackenzie Deltaic System, which drains the northern third of interior North America, with sizable contributions from Alaska and Northwest Canada. The basin contains roughly 5 or 6 million cubic km of sediment. Three fourths or more of this volume generates low amplitude seismic reflections, interpreted to represent hemipelagic deposits, which contain lenses to extensive interbeds of moderate amplitude reflections interpreted to represent unconfined turbidite and amalgamated channel deposits.Extrapolation from Arctic Alaska and Northwest Canada suggests that three fourths of the section in Canada Basin is correlative with stratigraphic sequences in these areas that contain intervals of hydrocarbon source rocks. In addition, worldwide heat flow averages suggest that about two thirds of Canada Basin lies in the oil or gas windows. Structural, stratigraphic and combined structural and stratigraphic features of local to regional occurrence offer exploration targets in Canada Basin, and at least one of these contains bright spots. However, deep water (to almost 4000 m), remoteness from harbors and markets, and thick accumulations of seasonal to permanent sea ice (until its possible removal by global warming later this century) will require the discovery of very large deposits for commercial success in most parts of Canada Basin.     

Spatial variability of the chlorophyll <Emphasis Type="Italic">a</Emphasis> and the specific structure of the phytoplankton in the northwestern part of the Sea of Japan during the winter period

To evaluate the structure and photosynthetic activity of the phytoplankton of the northwestern part of the Sea of Japan, the results of the surveys conducted from February 26 to March 9, 2003, during the 30th cruise of the R/V Akademik Lavrentyev were used. The species composition was considered taking into account the influences of the hydrological conditions. In particular, the studied water area was divided into four zones with various sizes of the mixed layer depth (MLD). An inverse relationship between the MLD and the content of chlorophyll a (Chl a) in various zones was established. The diatom algae were the basic dominants of the composite structure of the phytoplankton everywhere. It is revealed that, at a MLD increase, smaller forms of microalgae receive development. The intrapopulation relations are caused by the adaptation of various species of phytoplankton to the influence of external factors, among which the size of MLD is fundamental.     

Lagrangian measurements in the Kamchatka Current and Oyashio

From 1988 to 1993, 23 satellite-tracked drifting buoys entered the Kamchatka Current. The buoy trajectories showed a well-formed, high-speed current that originated near Shirshov Ridge, and flowed southward through Kamchatka Strait. During some years, the buoys turned eastward at 50°N, while in other years they were transported as far south as Japan (40°N). Only one buoy entered the Sea of Okhotsk. Eddies were evident in many of the buoy trajectories. Greatest maximum daily velocities (>100 cm s^–1) were observed south of Kamchatka Strait, with 50–60 cm s^–1 being more common.     

Impact of Two "El Niño" Events of Different Intensity on the Hypoxic Soft Bottom Macrobenthos off the Central Peruvian wast

Abstract. Monthly changes in the community structure of hypoxic soft-bottom macrobenthos have been studied at a station at 34 m depth in Ancón Bay (Peru) before and during two El Niño (EN) events. Of these events, 1982-83 is considered the strongest, and 1991–93 one of the most prolonged in the 20th century. On the oceanographic scale, EN 1982–83 ranges as "very strong", whereas EN 1991–93 ranges as "moderate".
The thermal anomalies at the station during EN 1982–83 (+ 7.8 °C) were almost twice those of EN 1991–93 (+ 4.1 °C). However, the community changes were not in all cases proportional to the extent of warming. Species numbers increased in a similar way (up to 24 species from near zero in each of the two events), but maximum faunal density was five times higher, and mean biomass was twice as high in 1982–83 compared with the event a decade later. Species diversity was slightly higher during EN 1982–83, whereas successional and trophic changes occurred on a broader scale during EN 1991–93. On the whole, the impact of the long-lasting event on the small soft-bottom macrofauna was not much weaker than that of the exceptionally strong event.
The authors discuss the mechanisms which may be responsible for the differences and similarities encountered in the benthic community dynamics during these two events. Both in the unusually strong and the unusually long EN, the community revealed a pattern of early biological response several months ahead of the onset of local warming which marks the official begin of EN. The question is addressed to what extent the increase of certain parameters in the benthic community could be used for predictive purposes.     

Transverse vibrations of a rectangular cantilever plate with thickness varying in a discontinuous fashion

A numerical solution is obtained for the title problem by means of the popular finite element method. An experimental investigation of the problem is also presented for plates of square planform. The agreement between theoretical and experimental values is very good in the case of the fundamental frequency, and reasonably good when the second and third normal modes of transverse vibration are considered. It is concluded that beneficial effects are obtained in the sense that one generates a lighter structural element with higher fundamental frequency of transverse vibration. Hence, dynamic stiffening is achieved.     

Spatial and temporal variability of particulate matter in the benthic boundary layer at the N.W. European Continental Margin (Goban Spur)

Near bottom water samples and sediments were taken during five cruises to 6 stations forming a transect across the N.W. European Continental Margin at Goban Spur. Flow velocity spot measurements in the benthic boundary layer (BBL) always increased from the shelf to the upper slope (1470 m) from 5 to 9 cm s⁻¹ in spring/summer and from 15 to 37 cm s⁻¹ in autumn/winter. Decreasing values were detected at the lower slope (2000 m) and the lowest values of ca. 2 cm s⁻¹ at the continental rise at 4500 m water depth. Long term measurements with a benthic lander at 1470 m show that currents have a tidal component and reach maximum velocities up to 20 cm s⁻¹, sufficiently high periodically to resuspend and transport phytodetritus. During these long-term observations, currents were always weaker in spring/summer than in autumn/winter. Critical shear velocities of shelf/slope sediments increased with depth from 0.5 to 1.7 cm s⁻¹ and major resuspension events and Intermediate Nepheloid Layers (INLs) should occur around 1000 m. Chloroplastic Pigment Equivalents (CPE) ranged from 0.0 to 0.21 μg dm⁻³, Particulate Organic Carbon (POC) from 12 to 141 μg dm⁻³ and Total Particulate Matter (TPM) from 0.2 to 10.0 mg dm⁻³. Aggregates in the BBL occurred with a median diameter of 152 to 468 μm. Data on suspended particulate matter in the near-bottom waters showed that hydrodynamic sorting within the particulate organic fraction occurred. Phytodetritus was packaged in relatively large aggregates and contributed little to the total organic carbon pool in nearbottom waters (CPE/POC ca.0.2%). The main organic fraction has low settling velocities and high residence times within the benthic boundary layer. As POC was not concentrated in the near bed region the degree to which carbon is accessible to the benthic community depends on aggregate formation, subsequent settling and/or biodeposition of the POC. Close to the sea bed downslope transport may dominate. Under flow conditions high enough to resuspend fresh phythodetritus from sediments at the productive shelf edge, this could be transported to 1500 m (Goban Spur) or abyssal depth (Canyon site between Meriadzek and Goban Spur) within 21 days.     

Gonadal development in Japanese medaka (Oryzias latipes) exposed to 17 β-estradiol

The purpose of this research was to evaluate the Japanese medaka (Oryzias latipes) as an ecotoxicological model for the rapid evaluation of environmental estrogens. A novel short-term (48-h) exposure to 17 β-estradiol is proposed in development of a positive control for disruption of gonadal development. Recently hatched medaka fry (30 fry per dose group) with undifferentiated gonads were exposed to 4.0, 29.4, and 115.6 μg/liter of 17 β-estradiol (acetone carrier) for 48 h in a water bath at 25 °C. The fry were then grown-out in spring water for 2 weeks, killed, and processed for histological evaluation. High lethality was encountered during the grow-out period in the 115.6 μg/liter dose group. Fry in the spring water and acetone (carrier) control groups developed into females or males. Fry exposed to 17 β-estradiol developed primarily into females or had testis-ova.