Assessing the impacts of climate and land use change on streamflow,water quality and suspended sediment in the Kor River Basin,Southwest of Iran

This research addressed the separate and combined impacts of climate and land use change on streamflow, suspended sediment and water quality in the Kor River Basin, Southwest of Iran, using (BASINS–WinHSPF) model. The model was calibrated and validated for hydrology, sediment and water quality for the period 2003–2012. The model was run under two climate changes, two land use changes and four combined change scenarios for near-future period (2020–2049). The results revealed that projected climate change impacts include an increase in streamflow (maximum increases of 52% under RCP 2.6 in December and 170% under RCP 8.5). Projected sediment concentrations under climate change scenarios showed a monthly average decrease of 10%. For land use change scenarios, agricultural development scenario indicated an opposite direction of changes in orthophosphate (increases in all months with an average increase of 6% under agricultural development scenario), leading to the conclusion that land use change is the dominant factor in nutrient concentration changes. Combined impacts results indicated that streamflows in late fall and winter months increased while in summer and early fall decreased. Suspended sediment and orthophosphate concentrations were decreased in all months except for increases in suspended sediment concentrations in September and October and orthophosphate concentrations in late winter and early spring due to the impact of land use change scenarios.     

Effect of $$\hbox {CO}_2$$ solubility on dissolution rate of calcite in saline aquifers for temperature range of 50–100 $$^{\circ } \hbox {C}$$∘C and pressures up to 600 bar: alterations of fractures geometry in carbonate rocks by $$\hbox {CO}_2$$-acidified brines

An empirical model is developed to predict the dissolution rate of calcite in saline solutions that are saturated with respect to dissolved \(\hbox {CO}_2\) over a broad range of both subcritical and supercritical conditions. The focus is on determining the rate of calcite dissolution within a temperature range of 50–100 \(^\circ \hbox {C}\) and pressures up to 600 bar, relevant for \(\hbox {CO}_2\) sequestration in saline aquifers. A general reaction kinetic model is used that is based on the extension of the standard Arrhenius equation with an added, solubility-dependent, pH term to account for the saturated concentration of dissolved \(\hbox {CO}_2\). On the basis of this kinetic model, a new rate equation is obtained using multi-parameter, nonlinear regression of experimental data to determine the dissolution of calcite as a function of temperature, pressure and salinity. Different models for the activity coefficient of \(\hbox {CO}_2\) dissolved in saline solutions are accounted for. The new rate equation helps us obtain good agreement with experimental data, and it is applied to study the geochemically induced alterations of fracture geometry due to calcite dissolution.     

Impact of tailings dam failure on spatial features of copper contamination (Mazraeh mine area,Iran)

Mining activities pose a potential risk of metal contamination around mining sites. On May 6, 2010, a tailings dam failure of the Mazraeh copper mine near Ahar in East Azerbaijan province, Iran, released vast amounts of mine wastes. To better understand the magnitude of copper contamination in the waste-affected soils, it is important to assess the spatial distribution of soil copper content at unsampled points. A total of 30 soil samples and their surficial sediments together with the 6 uncontaminated control samples (0–10 and 10–30 cm) were collected along the stream flow that joined Ahar-Chai River. Some of soil properties as well as total copper concentration were determined in all samples. The mean value of the latter in the surface contaminated soils was found to be approximately two times more than controls. Furthermore, the mean concentration of copper in the surface loaded material was 10 times more than the soils. High copper concentrations were observed in surficial sediments of the soils near the broken tailings dam. The Inverse Distance Weighting (IDW) method was employed in data analysis. The spherical and Gaussian semivariogram models were properly fitted to the data of copper contents in soils and surficial sediments.     

Study on the improving method for gas production prediction in tight clastic reservoir

Relative permeability and resistivity index are important parameters for the exploration and development in a tight sandstone gas field. In the splitting method which uses permeability (K), reservoir thickness (H), and relative permeability (K), briefly referred to as the KHK splitting method, the accuracy of the relative permeability is crucial. According to the relationship between resistivity index and relative permeability of the Mesozoic Lower Safa Formation at Obaiyed Field in the Western Desert of Egypt, we improved the split method and made it more in line with the real situation by adopting Pairoys’ model which is more suitable to our study area. In this paper, we use a radial basis function (RBF) to establish the relationship between logging data and the gas production split point to point in tight sandstone gas reservoirs. To compare with the result by support vector regression (SVR), our method is better as indicated by mean absolute error values. In order to solve the problem that the relative permeability is difficult to obtain in the well logging evaluation, we also provide a convenient method and application example.     

Seasonal variation of the double diffusion processes at the Strait of Hormuz

Profiles of salinity and temperature were measured in the strait of Hormuz (SH) during the winter of 2012, spring and summer of 2013. To investigate the double diffusion (DD) processes, Turner (TU) angle values are calculated in all the stations in the SH. Different TU angle values correspond to salt fingering (SF), diffusive convection (DC) and stable stratification. The distributions of the two forms of DD were plotted vertically along transects in the eastern, central and western part of the SH, and corresponding DD processes were described. The results show that both SF and DC occurred in most part of the study area. Two different water masses (the Indian Ocean surface water and the Persian Gulf water) were evident at the SH, and SF and DC were evident at the interface of two water masses. Due to evaporation, SF occurred in the surface layer of most Stations throughout the year. In the eastern part of the SH, occurrences of DC were more feasible in wintertime. SF was the main phenomenon at the end of hot season. For central part, SF occurred throughout the year in water column. In the western part, water column was stable in summer and DC happened in most part of water column in winter.     

Biostratigraphy of Asmari Formation in Ghare Agha seyed of Farsan region,Chaharmahale Bakhtiari Province,Iran

The Asmari Formation consists of shallow marine sedimentary rocks deposited on ramp setting .Lar-ger benthic foraminifera collected from Asmri Formation are dominated by hyaline and porcelanouse forms , in-cluding Amphistegina, Nummulites, Archaias, Astrotrillina, Miogypsinella, Miogypsinoides, Lepidocyclina, Operculina, Spiroclypeous and Miliolids.The presence of Nummulites cf.vascus in the lower part of the forma-tion allows the age to be determined as Rupelian .The occurrence of Borelis pygmae is an index taxon of the Ru-pelian-Chattian and indicates Early Chattian of SBZ 21-22 in the study section .The first appearance of Mio-gypsinella akadagensis shows Late Chattian ( SBZ 23) and defines the upper boundary of the SBZ 21-22.The new data are the first evidences showing that the shallow marine Asmari Formation is attributed to Oligocene (Rupelian-Chattian) age for this region.     

Preservation of organic matter in soils of a climo-biosequence in the Main Range of Peninsular Malaysia

Limited information is available about factors of soil organic carbon(SOC) preservation in soils along a climo-biosequence. The objective of this study was to evaluate the role of soil texture and mineralogy on preservation of SOC in the topsoil and subsoil along a climo-biosequence in the Main Range of Peninsular Malaysia. Soil samples from the A and B-horizons of four representative soil profiles were subjected to particle-size fractionation and mineralogical analyses including X-ray diffraction and selective dissolution. The proportion of SOC in the 250-2000 μm fraction(SOC associated with coarse sand) decreased while the proportion of SOC in the 53 μm fraction(SOC associated with clay and silt)increased with depth. This reflected the importance of the fine mineral fractions of the soil matrix for SOC storage in the subsoil. Close relationships between the content of SOC in the 53 μm fraction and the content of poorly crystalline Fe oxides [oxalate-extractable Fe(Fe_o) – pyrophosphate-extractable Fe(Fe_p)] and poorly crystalline inorganic forms of Al [oxalateextractable Al(Al_o) – pyrophosphate-extractable Al(Al_p)] in the B-horizon indicated the importance of poorly crystalline Fe oxides and poorly crystalline aluminosilicates for the preservation of SOC in the Bhorizon. The increasing trend of Fe_o-Fe_p and Al_o-Al_p over elevation suggest that the importance of poorly crystalline Fe oxides and poorly crystalline aluminosilicates for the preservation of SOC in the Bhorizon increased with increasing elevation. This study demonstrates that regardless of differences in climate and vegetation along the studied climobiosequence, preservation of SOC in the subsoil depends on clay mineralogy.     

The nonlinear association between the Arctic Oscillation and North American winter climate

Nonlinear projections of the Arctic Oscillation (AO) index onto North American winter (December–March) 500-mb geopotential height (Z500) and surface air temperature (SAT) anomalies reveal a pronounced asymmetry in the atmospheric patterns associated with positive and negative phases of the AO. In a linear view, the Z500 anomaly field associated with positive AO resembles a positive North Atlantic Oscillation pattern with statistically significant positive and negative anomalies stretching zonally into central-eastern USA and Canada, respectively, resulting in a cold climate anomaly over northeastern and eastern Canada, Alaska and the west coast of USA, and a warm climate anomaly over the rest of the continent. By contrast, the nonlinear behavior, mainly a quadratic association with AO, which is most apparent when the amplitude of the AO index is large, has the same spatial pattern and sign for both positive and negative values of the index. The nonlinear pattern reveals negative Z500 anomalies over the west coast of USA and the North Atlantic and positive Z500 anomalies at higher latitudes centered over the Gulf of Alaska and northeastern Canada accompanied by cooler than normal climate over the USA and southwestern Canada and warmer than normal climate over other regions of the continent. A similar analysis is conducted on the data from the Canadian Center for Climate Modelling and Analysis second generation coupled general circulation model. The nonlinear patterns of North American Z500 and SAT anomalies associated with the AO in the model simulation are generally consistent with the observational results, thereby confirming the robustness of the nonlinear behavior of North American winter climate with respect to the AO in a climate simulation that is completely independent of the observations.     

Textural relations,P-T path,polymetamorphism and also geodynamic significance of metamorphic rocks of the Aligudarz-Khonsar region,Sanandaj-Sirjan zone,Iran

The metamorphic rocks of the Aligudarz-Khonsar region can be divided into nine groups: slate, phyllite, sericite schist, biotite-muscovite schist, garnet schist, garnet-staurolite schist, staurolite schist, mylonitic granite, and marble. In this metamorphic region, four phases of metamorphism can be identified (dynamothermal, thermal, dynamic and retrograde metamorphism) and there are three deformation phases (D1, D2 and D3). Paleozoic pelagic shales experienced prograde metamorphism and polymetamorphism from the greenschist to amphibolite facies along the kyanite geotherm. The metapelites show prograde dynamothermal metamorphism from the greenschist to amphibolite facies. Maximum degree of dynamothermal metamorphism is seen in the Nughan bridge area. Also development of the mylonitic granites in the Nughan bridge area shows that dynamic metamorphism in this area was more intense than in other parts of the AligudarzKhonsar metapelitic zone. The chemical zoning of garnets shows three stages of growth and syn-tectonic formation. With ongoing metamorphism, staurolite appeared, and the rocks reached amphibolite facies, but the degree of metamorphism did not increase past the kyanite zone. Thus, metamorphism of the pelitic sediments occurred at the greenschist to amphibolite facies (kyanite zone). Thermodynamic studies of these rocks indicate that the metapelites in the Aligudarz-Khonsar region formed at 490–550°C and 0.47–5.6 kbar.