Estimates of changes in design rainfall values for Canada

Annual maximum rainfall data from 51 stations in Canada were analyzed for trends and changes by using the Mann–Kendall trend test and a bootstrap resampling approach, respectively. Rainfall data were analyzed for nine durations ranging from 5 min to 24 h. The data analyzed are typically used in the development of intensity‐duration‐frequency (IDF) curves, which are used for estimating design rainfall values that form an input for the design of critical water infrastructure. The results reveal more increasing than decreasing trends and changes in the data with more increasing changes and larger changes, noted for the longer rainfall durations. The results also indicate that a traditional trend test may not be sufficient when the interest is in identifying changes in design rainfall quantiles. Copyright © 2012 John Wiley & Sons, Ltd.     

Green and Eco‐Friendly Removal of Mycotoxins with Organo‐Bentonites; Isothermal,Kinetic, and Thermodynamic Studies

In the current study the application of organo‐modified bentonite for the adsorption of mycotoxins (aflatoxin B1, citrinin, patulin, and zearalenone) is presented. The modification of clays is carried out using benzyl‐tri‐n‐butyl ammonium bromide (BTB), benzethonium chloride (BTC), and dioctyl sodium sulfosuccinate (DSS). Various experimental parameters such as pH, time, adsorbent dose, and mycotoxins concentration are thoroughly studied. The modified clays (B‐BTB, B‐BTC and B‐DSS) are characterized by X‐ray fluorescence, X‐ray diffraction, and Fourier transform infrared spectroscopy. The results depicted the high detoxification efficiency (≈99%) of modified clays for the removal of mycotoxins under optimized conditions (pH 5, time: 30 min, adsorbent amount: 50 mg). The adsorption capacities of modified clays are found in the order of: B‐BTC (AFB1: 18.02, CIT: 18.35, PAT: 18.21, ZEA: 18.09 mg g^?1) > B‐BTB (AFB1: 17.7, CIT: 18.11, PAT: 17.95, ZEA: 17.90 mg g^?1) > B‐DSS (AFB1: 17.5, CIT: 18.02, PAT: 17.86, ZEA: 17.80 mg g^?1). The obtained results fitted well with thermodynamic, isothermal (Langmuir) and pseudo‐second order kinetics. Low cost organo‐modified bentonite shows the promise in mitigating mycotoxin contamination, which could improve food safety and reduce environmental contamination.     

Estimating wave crest distributions using the method of L-moments

The design of fixed or floating offshore structures requires accurate information of the met-ocean data at the intended offshore site. In the design process it is recognized that this environmental data is modified in the near-field by the interaction with the particular geometrical configuration of the offshore structure. This transformation of the incident wave field around and beneath an offshore structure presents a challenge for ocean engineers when specifying the wave gap elevation to avoid impact loads on the underside of the deck and inundation of the topsides. Thus, the accurate estimation of the wave crest distributions from measurements at various locations near and under the offshore structure during model test studies is essential. A semi-empirical approach is presented herein that builds upon the findings of previous studies and introduces the Method of L-moments. A three parameter model for a wave crest probability distribution function is presented and explicit relationships between the parameters of the distribution and its’ first three L-Moments are established. Furthermore, three narrow-band models from earlier research studies are reviewed and compared with the new model. Wave measurements from a mini-TLP model test program are used as the basis for comparison of the four distributions. The root-mean-square error is used as a metric to quantify the overall fit of the data and its accuracy in the high end tail of the data. The L-Moment model is shown to be more robust in representing the data in both the far-field and beneath the deck of the mini-TLP where the wave field demonstrates increased non-linear behavior.     

Stability of rubble-mound breakwater using H50 wave height parameter

The prediction of rubble mound breakwaters' stability is one of the most important issues in coastal and maritime engineering. The stability of breakwaters strongly depends on the wave height. Therefore, selection of an appropriate wave height parameter is very vital in the prediction of stability number. In this study, H₅₀, the average of the 50 highest waves that reach the breakwater in its useful life, was used to predict the stability of the armor layer. First, H₅₀ was used instead of the significant wave height in the most recent stability formulas. It was found that this modification yields more accurate results. Then, for further improvement of the results, two formulas were developed using model tree.To develop the new formulas, two experimental data sets of irregular waves were used. Results indicated that the proposed formulas are more accurate than the previous ones for the prediction of the stability parameter. Finally, the proposed formulas were applied to regular waves and a wide range of damage levels and it was seen that the developed formulas are applicable in these cases as well.     

Incorporation of chitosan and glass substrate for improvement in adsorption,separation, and stability of TiO<Subscript>2</Subscript> photodegradation

It is demonstrated that single titanium dioxide (TiO₂) has high potential for photodegradation of pollutants. However, it is still far from becoming an effective photocatalyst system, due to issues of adsorption process, separation, as well as dissolution. Therefore, this study highlights the high adsorption capacity, simplified separation, and the promising stability of TiO_2(SY) (synthesized via sol–gel method) photocatalyst, fabricated using chitosan–TiO_2(SY) and supported by glass substrate (Cs–TiO_2(SY)/glass substrate) photocatalysts. Chitosan (Cs), with abundant –R–NH and NH₂ groups, promotes the adsorption sites of methyl orange (MO) and OH groups for major attachment to TiO_2(SY). Meanwhile, the glass substrate increases stability and assists separation of the photocatalysts. Initially, nano-TiO_2(SY) has been characterized using high-resolution transmission electron microscope. Cs–TiO_2(SY)/glass substrate was fabricated via dip-coating. The distribution and interface between the photocatalytic components were characterized by Fourier transform infrared absorption spectroscopy, UV–Vis diffuse reflectance spectroscopy, field emission scanning electron microscopy, and energy-dispersive spectrometer. UV–Vis analysis of the multilayer photocatalyst (2, 4, 6, and 8 layers) was further carried out by the adsorption–photodegradation, with MO as model of pollutant. Seventy percent of the total removal of MO via optimized eight layers of photocatalyst was achieved within 1 h of UV irradiation. The adsorption photocatalyst achieved 50 % with no exposure to UV light for 15 min of irradiation. It is concluded that suitable photocatalytic conditions and sample parameters possessing the multilayer photocatalyst of Cs–TiO_2(SY) are beneficial toward the adsorption–photodegradation process in wastewater treatment.     

An Assessment of Changes in Winter Cold and Warm Spells over Canada

The recent Third Assessment Report (TAR) of the Intergovernmental Panel onClimate Change (IPCC) indicated that observed 20th century changes in severalclimatic extremes are qualitatively consistent with those expected due to increasedgreenhouse gases. However, a lack of adequate data and analyses make conclusiveevidence of changing extremes somewhat difficult, particularly, in a global sense.In Canada, extreme temperature events, especially those during winter, can havemany adverse environmental and economic impacts. In light of the aforementionedIPCC report, the main focus of this analysis is to examine observed trends andvariability in the frequency, duration, and intensity of winter (Jan–Feb–Mar) cold and warm spells over Canada during the second half of the 20th century.Cold spell trends display substantial spatial variability across the country. From1950–1998, western Canada has experienced decreases in the frequency, duration, and intensity of cold spells, while in the east, distinct increases in the frequency and duration have occurred. These increases are likely associated with morefrequent occurrences of the positive phase of the North Atlantic Oscillation (NAO)during the last several decades. With regard to winter warm spells, significantincreases in both the frequency and duration of these episodes were observedacross most of Canada. One exception was found in the extreme northeasternregions, where warm spells are becoming shorter and less frequent. The resultsof this study are discussed within the context of climate warming expectations.     

Deriving snow‐cover depletion curves for different spatial scales from remote sensing and snow telemetry data

During the melting of a snowpack, snow water equivalent (SWE) can be correlated to snow‐covered area (SCA) once snow‐free areas appear, which is when SCA begins to decrease below 100%. This amount of SWE is called the threshold SWE. Daily SWE data from snow telemetry stations were related to SCA derived from moderate‐resolution imaging spectroradiometer images to produce snow‐cover depletion curves. The snow depletion curves were created for an 80 000 km² domain across southern Wyoming and northern Colorado encompassing 54 snow telemetry stations. Eight yearly snow depletion curves were compared, and it is shown that the slope of each is a function of the amount of snow received. Snow‐cover depletion curves were also derived for all the individual stations, for which the threshold SWE could be estimated from peak SWE and the topography around each station. A station's peak SWE was much more important than the main topographic variables that included location, elevation, slope, and modelled clear sky solar radiation. The threshold SWE mostly illustrated inter‐annual consistency. Copyright © 2015 John Wiley & Sons, Ltd.     

Geophysical surveys to investigate the relation between the Quaternary Nile channels and the Messinian Nile canyon at East Nile Delta, Egypt

This paper compares the pattern of historical Eastern Nile Delta branches, delineated by geoelectric resistivity investigation, with the path of the Nile canyon of Messinian time revealed in seismic reflection. A close correlation is evident between the Late Quaternary Nile River channels and the Messinian canyons (wadies) in the eastern Nile Delta. This indicates that the Messinian canyons were a persistent topographic (or geomorphic) feature until historical branches. The results may also have implications for long-term patterns of subsidence in the delta area.