Quantile regression C-vine copula model for spatial extremes

A spatial quantile regression model is proposed to estimate the quantile curve for a given probability of non-exceedance, as function of locations and covariates. Canonical vines copulas are considered to represent the spatial dependence structure. The marginal at each location is an asymmetric Laplace distribution where the parameters are functions of the covariates. The full conditional quantile distribution is given using the Joe–Clayton copula. Simulations show the flexibility of the proposed model to estimate the quantiles with special dependence structures. A case study illustrates its applicability to estimate quantiles for spatial temperature anomalies.     

Phosphorus removal efficiency from wastewater under different loading conditions using sand biofilters augmented with biochar

Treated wastewater is a valuable resource, particularly in countries facing water shortage such as Jordan. Nevertheless, excess nutrients, especially phosphorus, may have detrimental impacts on receiving waterbodies. Treated wastewater in Jordan often exceeds the recommended levels set by the Jordanian Standards for wastewater reuse and discharge. Therefore, it is important to reduce phosphorus loads to acceptable levels before discharge. Biofiltration is a low-cost technology that has shown good potential for wastewater treatment. The performance of biofilters largely depends on the media used. In this study, local sand and sand augmented with biochar prepared from the olive oil processing waste (SBC) were used as filter media for phosphorus removal from clarified secondary treated wastewater. The two media types were tested under different hydraulic and phosphorus loading conditions to simulate shock, flooding, and inundation conditions. The results showed that sand media was more effective in removing phosphorus (90.8 ± 2.6%) than sand amended with biochar (83.3 ± 3.2%). Both media showed resilience under extreme loading conditions. Although phosphorus removal efficiency was negatively affected following the extreme loading events, the observed effects were temporary. The simulated inundation event further showed that the media was able to retain the adsorbed phosphorus. Furthermore, the phosphorus concentration in the effluent remained within the prescribed discharge guidelines at all times.     

Hydrothermal alteration and evolution of Zr-Th-U-REE mineralization in the microgranite of Wadi Ras Abda,North Eastern Desert,Egypt

Ras Abda plutonic suite, North Eastern Desert of Egypt, consists predominantly of Neoproterozoic calc-alkaline older granites. Minor exposures of pink microgranite are occurring along Wadi Ras Abda within the older granites. Previous studies on this area demonstrated that the microgranite is altered in some parts and contains anomalous concentrations of rare metal elements (Zr, Th, and U). These altered and mineralized zones are re-assessed using field observations, chemical analysis, and by the application of various transmitted light and electron microscopic techniques. The rare metals exist as mineral segregation grew freely into open cavities of the microgranite and concordant with the NNE strike-slip fault movement. The mineralized zones contain an assemblage of secondary magnetite, zircon, uranothorite, columbite-(Mn), fergusonite-(Y), and allanite-(Ce). The extreme abundance of zircon in the mineralized zone, along with other evidence, indicates a hydrothermal origin of this zircon together with associated rare metals. The geochemical investigation and mass balance calculations revealed extreme enrichment of Zr, Th, U, Y, Nb, Ta, and REE. Post-magmatic hydrothermal alterations resulted in such pronounced chemical and mineralogical heterogeneity. The hydrothermal fluids are thought to be oxidizing, alkaline and of medium temperature (>?250 °C). The average contents of the elements Zr (1606 ppm), Th (1639 ppm), U (306 ppm), Nb (955 ppm), and REE (1710 ppm) in the mineralized microgranite reach sub-economic levels and could be a potential source of these elements.     

Hydrochemical characterization and geospatial analysis of groundwater quality in Cap Bon region,northeastern Tunisia

The hydrogeochemical characteristics of shallow groundwater in the Grombalia region, northeastern Tunisia, were investigated to evaluate suitability for irrigation and other uses and to determine the main processes that control its chemical composition. A total of 21 groundwater samples were collected from existing wells in January–February 2015 and were analyzed for the major cations and anions concentrations. Conductivity, pH, T°, O₂ and salinity were also measured. Interrelationships between chemical parameters were determined by using the scatter matrix method. The suitability of groundwater for irrigation and other uses was assessed by determining the sodium adsorption ratio, soluble-sodium percentage, total dissolved solids, total hardness, Kelly’s index and permeability index values of water samples. The spatial distribution of key parameters was assessed using a GIS-based spatial gridding technique. This analysis indicated that the chemical composition of groundwater in the study area is of Cl–SO₄–Na–Ca mixed facies with concentrations of many chemical constituents exceeding known guideline values for irrigation. The salinity of groundwater is controlled by most dominant cation and anion (Na–Cl). A correlation analysis shows that Na⁺ is the dominant cation and that reverse ion exchange is a dominant process that controls the hydrogeochemical evolution of groundwater in the area. Geospatial mapping of hydrochemical parameters and indices analyzed with the USSL and Wilcox diagrams show distinctive areas of irrigation suitability. In contrast, 76.2% of samples fall in the highly doubtful to unsuitable category and indicate that the central and north-eastern parts of the study area are unsuitable for irrigation due to a high salinity and alkalinity.     

Biostratigraphy and seismic data analysis to detect the sequence stratigraphic depositional environment of the Miocene succession: Gulf of Suez (Egypt)

This work comprises a study of the sequence stratigraphy, seismic-facies analysis, biostratigraphy and depositional environments of the northern part of the Gulf of Suez, Egypt, using a set of 24 3D seismic profiles, composite logs and sonic logs from ten wells. The syn-rift formations in the studied ten wells are described lithologically and interpreted based on investigating two seismic profiles. Biostratigraphically, the Miocene fossils are identified to correlate the five planktonic foraminiferal biozones in the examined boreholes (RB-A1, RB-B1, RB-B3, EE85-2 and RB-C1). The sequence stratigraphic analysis suggests that the Miocene succession can be subdivided into two major third order depositional sequences (S1 and S2) separated by the three major sequence boundaries (DSB1, DSB2 and DSB3).     

Flow dynamics at the origin of thin clayey sand lacustrine turbidites: Examples from Lake Hazar,Turkey

Turbidity currents and their deposits can be investigated using several methods, i.e. direct monitoring, physical and numerical modelling, sediment cores and outcrops. The present study focused on thin clayey sand turbidites found in Lake Hazar (Turkey) occurring in eleven clusters of closely spaced thin beds. Depositional processes and sources for three of those eleven clusters are studied at three coring sites. Bathymetrical data and seismic reflection profiles are used to understand the specific geomorphology of each site. X‐ray, thin sections and CT scan imagery combined with grain‐size, geochemical and mineralogical measurements on the cores allow characterization of the turbidites. Turbidites included in each cluster were produced by remobilization of surficial slope sediment, a process identified in very few studies worldwide. Three types of turbidites are distinguished and compared with deposits obtained in flume studies published in the literature. Type 1 is made of an ungraded clayey silt layer issued from a cohesive flow. Type 2 is composed of a partially graded clayey sand layer overlain by a mud cap, attributed to a transitional flow. Type 3 corresponds to a graded clayey sand layer overlain by a mud cap issued from a turbulence‐dominated flow. While the published experimental studies show that turbulence is damped by cohesion for low clay content, type 3 deposits of this study show evidence for a turbulence‐dominated mechanism despite their high clay content. This divergence may in part relate to input variables, such as water chemistry and clay mineralogy, that are not routinely considered in experimental studies. Furthermore, the large sedimentological variety observed in the turbidites from one coring site to another is related to the evolution of a sediment flow within a field‐scale basin made of a complex physiography that cannot be tackled by flume experiments.     

Tunisian landfill leachate treatment using <Emphasis Type="Italic">Chlorella</Emphasis> sp.: effective factors and microalgae strain performance

The potential of the autoclaved Tunisian landfill leachate treatment using microalgae (Chlorella sp.) cultivation was investigated in this study. Landfill leachate was collected from Borj Chakir landfill, Tunisia. A full factorial experimental design 2² was proposed to study the effects of the incubation time and leachate ratio factors on the organic matter removal expressed in chemical oxygen demand (COD) and ammoniacal nitrogen (NH₄─N) and on the biological response of Chlorella sp. expressed by the cell density and chlorophyll content. All experiments were batch runs at ambient temperature (25 ± 2 °C). The Chlorella sp. biomass and chlorophyll a concentrations of 1.2 and 5.32 mg L^?1, respectively, were obtained with 10% leachate spike ratio. The obtained results showed that up to 90% of the ammoniacal nitrogen in landfill leachate was removed in 10% leachate ratio spiked medium with a residual concentration of 40 mg L^?1. The maximum COD removal rate reached 60% within 13 days of incubation time indicating that microalgae consortium was quite effective for treating landfill leachate organic contaminants. Furthermore, with the 10% leachate ratio spiked medium, the maximum lipid productivity was 4.74 mg L^?1 d^?1. The present study provides valuable information for potential adaptation of microalgae culture and its contribution for the treatment of Tunisian landfill leachate.     

An original semi‐discrete approach to assess gas conductivity of concrete structures

For civil engineering structures with a tightness role, structural permeability is a key issue. In this context, this paper presents a new proposition of a numerical modelling of leakage rate through a cracked concrete structure undergoing mode I cracking. The mechanical state of the material, considered in the framework of continuum mechanics based on finite element modelling, is described by means of the stress‐based nonlocal damage model which takes into account the stress state and provides realistic local mechanical fields. A semi‐discrete method based on the strong discontinuity approach to estimate crack opening is then considered in the post‐treatment phase. Using a Poiseuille's like relation, the coupling between the mechanical state of the material and its dry gas conductivity is performed. For validation purposes, an original experimental campaign is conducted on a dry concrete disc loaded in a splitting setup. During the loading, gas conductivity and digital image correlation analysis are performed. The comparison with the 3D experimental mechanical global response highlights the performance of the mechanical model. The comparison between crack openings measured by digital image correlation and estimated by the strong discontinuity method shows a good agreement. Finally, the results of the semi‐discrete approach coupled with the gas conductivity compared with experimental data show a good estimation of the structural conductivity. Consequently, if the mechanical problem is well modelled at the global scale, then the proposed approach provides good estimation of gas conductivity. Copyright © 2016 John Wiley & Sons, Ltd.     

Wrench structural deformation in Ras Al Hilal-Al Athrun area, NE Libya: a new contribution in Northern Al Jabal Al Akhdar Belt

Al Jabal Al Akhdar is a NE/SW- to ENE/WSW-trending mobile part in Northern Cyrenaica province and is considered a large sedimentary belt in northeast Libya. Ras Al Hilal-Al Athrun area is situated in the northern part of this belt and is covered by Upper Cretaceous–Tertiary sedimentary successions with small outcrops of Quaternary deposits. Unmappable and very restricted thin layers of Palaeocene rocks are also encountered, but still under debate whether they are formed in situ or represent allochthonous remnants of Palaeocene age. The Upper Cretaceous rocks form low-lying to unmappable exposures and occupy the core of a major WSW-plunging anticline. To the west, south, and southeast, they are flanked by high-relief Eocene, Oligocene, and Lower Miocene rocks. Detailed structural analyses indicated structural inversion during Late Cretaceous–Miocene times in response to a right lateral compressional shear. The structural pattern is themed by the development of an E–W major shear zone that confines inside a system of wrench tectonics proceeded elsewhere by transpression. The deformation within this system revealed three phases of consistent ductile and brittle structures (D₁, D₂, and D₃) conformable with three main tectonic stages during Late Cretaceous, Eocene, and Oligocene–Early Miocene times. Quaternary deposits, however, showed at a local scale some of brittle structures accommodated with such deformation and thus reflect the continuity of wrenching post-the Miocene. D₁ deformation is manifested, in Late Cretaceous, via pure wrenching to convergent wrenching and formation of common E- to ENE-plunging folds. These folds are minor, tight, overturned, upright, and recumbent. They are accompanied with WNW–ESE to E–W dextral and N–S sinistral strike-slip faults, reverse to thrust faults and pop-up or flower structures. D₂ deformation initiated at the end of Lutetian (Middle Eocene) by wrenching and elsewhere transpression then enhanced by the development of minor ENE–WSW to E–W asymmetric, close, and, rarely, recumbent folds as well as rejuvenation of the Late Cretaceous strike-slip faults and formation of minor NNW–SSE normal faults. At the end of Eocene, D₂ led to localization of the movement within E–W major shear zone, formation of the early stage of the WSW-plunging Ras Al Hilal major anticline, preservation of the contemporaneity (at a major scale) between the synthetic WNW–ESE to E–W and ENE–WSW strike-slip faults and antithetic N–S strike-slip faults, and continuity of the NW–SE normal faults. D₃ deformation is continued, during the Oligocene-Early Miocene, with the appearance of a spectacular feature of the major anticline and reactivation along the E–W shear zone and the preexisting faults. Estimating stress directions assumed an acted principal horizontal stress from the NNW (N33°W) direction.     

Multivariate statistical analyses of the groundwater system in Darb El-Arbaein, Southwestern Desert, Egypt

In Darb El-Arbaein, the groundwater is the only water resource. The aquifer system starts from Paleozoic–Mesozoic to Upper Cretaceous sandstone rocks. They overlay the basement rocks and the aquifer is confined. In the present research, the performance of the statistical analyses to classify groundwater samples depending on their chemical characters has been tested. The hydrogeological and hydrogeochemical data of 92 groundwater samples were obtained from the General Authority for Rehabilitation Projects and Agricultural Development authority in northern, central, and southern Darb El-Arbaein. A robust classification scheme for partitioning groundwater chemistry into homogeneous groups was an important tool for the characterization of Nubian sandstone aquifer. We test the performance of the many available graphical and statistical methodologies used to classify water samples. R-mode, Q-mode, correlation analysis, and principal component analysis were investigated. All the methods were discussed and compared as to their ability to cluster, ease of use, and ease of interpretation. The correlation investigation clarifies the relationship among the lithologic, hydrogeologic, and anthropogenic factors. Factor investigation revealed three factors, namely, the evaporation process–agricultural impact–lithogenic dissolution, the hydrogeological characteristics of the aquifer system, and the surface meteoric water that recharge the aquifer system. Two main clusters that subdivided into four subclusters were identified in the groundwater system based on hydrogeological and hydrogeochemical data. They reflect the impact of geomedia, hydrogeology, geographic position, and agricultural wastewater. The groundwater is undersaturated with respect to most selected minerals. The groundwater was supersaturated with respect to iron minerals in northern and southern Darb El-Arbaein. The partial pressure of the groundwater versus saturation index of calcite shows the gradual change in PCO₂ from atmospheric to the present aquifer pressures.