Geography of contamination: The location of industrial waste dumps in Catalonia

The handling of the solid industrial waste (SIW) generated in Catalonia is one of the main problems of industrial and territorial policy confronting the public bodies controlling this area of activity. The most recent estimates in this regard indicate that the annual production of SIW is 1,700,000 tons and that only 300,000 tons are treated.In this situation it is usual for a large number of industries to eliminate their SIW furtively, it is common practice to dump waste in various unprepared areas. In this article we present a series of hypotheses which we believe allow us to understand the logic that guides the siting of a large number of these dumps.In the first place we demonstrate the importance of a series of conditions derived from the same industrial logic, to wit, a) the cost of transporting the SIW to the dumps, b) the industrial decentralization process and the metropolitan development of Catalonia, c) vertical integration and the appearance of companies especially dedicated to the elimination of waste and, d) the development of land use through revaluation of the land and greater possibilities for control forces furtive dumps to be sited in more and more distant areas.Secondly, we examine the role of public bodies in this process, concentrating on the characteristics of the legal system and the real effectiveness of urban controls. Finally, in third place, an explanation is given of research carried out in the Barcelona area which shows the importance of the conditions examined above.     

Spatial distribution and temporal variation of reference evapotranspiration in arid and semi‐arid regions of Iran

Analysis of spatial and temporal variations of reference evapotranspiration (ET_o) is important in arid and semi‐arid regions where water resources are limited. The main aim of this study was to analyse the spatial distribution and the annual, seasonal and monthly trends of the Penman–Monteith ET_o for 21 stations in the arid and semi‐arid regions of Iran. Three statistical tests the Mann‐Kendall, Sen's slope estimator and linear regression were used for the analysis. The analysis revealed that ET_o increased from January to July and deceased from July to December at almost all stations. Additionally, higher annual ET_o values were found in the southeast of the study region and lower values in the northwest of the region. Although the results showed both positive and negative trends in annual ET_o series, ET_o generally increased, significantly so in six (～30%) of the stations. Analysis of the impacts of meteorological variables on the temporal trends of ET_o indicated that the increasing trend of ET_o was most likely due to a significant increase in minimum air temperature, while decreasing trend of ET_o was mainly caused by a significant decrease in wind speed. At the sites where increasing ET_o trends were statistically significant, the rate of increase varied from (+)8·36 mm/year at Mashhad station to (+)31·68 mm/year at Iranshahr station. On average, an increasing trend of (+)4·42 mm/year was obtained for the whole study area during the last four decades. Seasonal and monthly ET_o have also tended to increase at the majority of the stations. The greatest numbers of significant trends were observed in winter on the seasonal time‐scale and in September on the monthly time‐scale. Copyright © 2011 John Wiley & Sons, Ltd.     

Soil-Structure Interaction Analysis of Jack-up Platforms Subjected to Monochrome and Irregular Waves

As jack-up platforms have recently been used in deeper and harsher waters, there has been an increasing demand to understand their behaviour more accurately to develop more sophisticated analysis techniques. One of the areas of significant development has been the modelling of spudcan performance, where the load-displacement behaviour of the foundation is required to be included in any numerical model of the structure. In this study, beam on nonlinear winkler foundation (BNWF) modeling—which is based on using nonlinear springs and dampers instead of a continuum soil media—is employed for this purpose. A regular monochrome design wave and an irregular wave representing a design sea state are applied to the platform as lateral loading. By using the BNWF model and assuming a granular soil under spudcans, properties such as soil nonlinear behaviour near the structure, contact phenomena at the interface of soil and spudcan (such as uplifting and rocking), and geometrical nonlinear behaviour of the structure are studied. Results of this study show that inelastic behaviour of the soil causes an increase in the lateral displacement at the hull elevation and permanent unequal settlement in soil below the spudcans, which are increased by decreasing the friction angle of the sandy soil. In fact, spudcans and the underlying soil cause a relative fixity at the platform support, which changes the dynamic response of the structure compared with the case where the structure is assumed to have a fixed support or pinned support. For simulating this behaviour without explicit modelling of soil-structure interaction (SSI), moment-rotation curves at the end of platform legs, which are dependent on foundation dimensions and soil characteristics, are obtained. These curves can be used in a simplified model of the platform for considering the relative fixity at the soil-foundation interface.     

Line-of-Sight Anisotropies in the Cosmic Dawn and Epoch of Reionization 21-cm Power Spectrum

The line-of-sight direction in the redshifted 21-cm signal coming from the cosmic dawn and the epoch of reionization is quite unique in many ways compared to any other cosmological signal. Different unique effects, such as the evolution history of the signal, non-linear peculiar velocities of the matter etc. will imprint their signature along the line-of-sight axis of the observed signal. One of the major goals of the future SKA-LOW radio interferometer is to observe the cosmic dawn and the epoch of reionization through this 21-cm signal. It is thus important to understand how these various effects affect the signal for its actual detection and proper interpretation. For more than one and half decades, various groups in India have been actively trying to understand and quantify the different line-of-sight effects that are present in this signal through analytical models and simulations. In many ways the importance of this sub-field under 21-cm cosmology have been identified, highlighted and pushed forward by the Indian community. In this article, we briefly describe their contribution and implication of these effects in the context of the future surveys of the cosmic dawn and the epoch of reionization that will be conducted by the SKA-LOW.     

Chemistry of snow and lake water in Antarctic region

Surface snow and lake water samples were collected at different locations around Indian station at Antarctica, Maitri, during December 2004–March 2005 and December 2006–March 2007. Samples were analyzed for major chemical ions. It is found that average pH value of snow is 6.1. Average pH value of lake water with low chemical content is 6.2 and of lake water with high chemical content is 6.5. The Na⁺ and Cl^? are the most abundantly occurring ions at Antarctica. Considerable amount of SO ₄ ^2? is also found in the surface snow and the lake water which is attributed to the oxidation of DMS produced by marine phytoplankton. Neutralization of acidic components of snow is mainly done by NH ₄ ⁺ and Mg²⁺. The Mg²⁺, Ca²⁺ and K⁺ are nearly equally effective in neutralizing the acidic components in lake water. The NH ₄ ⁺ and SO ₄ ^2? occur over the Antarctica region mostly in the form of (NH₄)₂SO₄.     

Development of a Darcy-Brinkman model to simulate water flow and tracer transport in a heterogeneous karstic aquifer (Val d’Orléans, France)

Darcy’s law is the equation of reference widely used to model aquifer flows. However, its use to model karstic aquifers functioning with large pores is problematic. The physics occurring within the karstic conduits requires the use of a more representative macroscopic equation. A hydrodynamic model is presented which is adapted to the karstic aquifer of the Val d’Orléans (France) using two flow equations: (1) Darcy’s law, used to describe water flow within the massive limestone, and (2) the Brinkman equation, used to model water flow within the conduits. The flow equations coupled with the transport equation allow the prediction of the karst transfer properties. The model was tested by using six dye tracer tests and compared to a model that uses Darcy’s law to describe the flow in karstic conduits. The simulations show that the conduit permeability ranges from 5?×?10^?6 to 5.5?×?10^?5?m² and the limestone permeability ranges from 8?×?10^?11 to 6?×?10^?10?m². The dispersivity coefficient ranges from 23 to 53 m in the conduits and from 1 to 5 m in the limestone. The results of the simulations carried out using Darcy’s law in the conduits show that the dispersion towards the fractures is underestimated.     

Leachability of trace elements from two stabilized low lime Indian fly ashes

Fly ash is a waste by-product obtained from the burning of coal by thermal power plants for generating electricity. When bulk quantities are involved, in order to arrest the fugitive dust, it is stored wet rather than dry. Fly ash contains trace concentrations of heavy metals and other substances in sufficient quantities to be able to leach out over a period of time. In this study an attempt was made to study the leachabilities of a few selected trace metals: Cd, Cu, Cr, Mn, Pb and Zn from two different types of class F fly ashes. Emphasis is also laid on developing an alternative in order to arrest the relative leachabilities of heavy metals after amending them with suitable additives. A standard laboratory leaching test for combustion residues has been employed to study the leachabilities of these trace elements as a function of liquid to solid ratio and pH. The leachability tests were conducted on powdered fly ash samples before and after amending them suitably with the matrices lime and gypsum; they were compacted to their respective proctor densities and cured for periods of 28 and 180 days. A marked reduction in the relative leachabilities of the trace elements was observed to be present at the end of 28 days. These relative leachability values further reduced marginally when tests were performed at the end of 180 days.     

Geochemical constraints on the genesis of the volcanic rocks in the southeast of Isfahan area, Iran

Late Miocene–Pliocene to Quaternary calc-alkaline lava flows and domes are exposed in southeast of Isfahan in the Urumieh Dokhtar magmatic belt in the Central Iran structural zone. These volcanic rocks have compositions ranging from basaltic andesites, andesites to dacites. Geochemical studies show these rocks are a medium to high K calc-alkaline suite and meta-aluminous. Major element variations are typical for calc-alkaline rocks. The volcanic rocks have SiO₂ contents ranging between 53.8% and 65.3%. Harker diagrams clearly show that the dacitic rocks did not form from the basaltic andesites by normal differentiation processes. They show large ion lithophile elements- and light rare earth elements (LREE)-enriched normalized multielement patterns and negative Nb, Ti, Ta, and P. Condrite-normalized REE patterns display a steep decrease from LREE to light rare earth elements without any Eu anomaly. These characteristics are consistent with ratios obtained from subduction-related volcanic rocks and in collision setting. The melting of a heterogeneous source is possible mechanism for their magma genesis, which was enriched in incompatible elements situated at the upper continental lithospheric mantle or lower crust. The geochemical characteristics of these volcanic rocks suggested that these volcanic rocks evolved by contamination of a parental magma derived from metasomatized upper lithospheric mantle and crustal melts.     

Valuation of socio-economic indicators for progressing urban sustainability under distinctive rubrics

The key objective of the study is to collect the factors which play an important role in the city's sustainability and implementation advantages for the development of cities in future. This article develops an urban sustainability assessment framework by giving GIS-based decision support tools to guide cities toward sustainability. Multicriteria analysis was used as the decision support system and provides an analytical framework for assessing differences in the level of criteria and ranking decision options. It has the capability for assessment of urban sustainability because it brings sustainability criteria from three pillars of sustainability, environmental, social, and economic, which provide an integrated approach for assessment of urban sustainability. The GIS-based multicriteria analysis serves as a sustainability support system that maps urban sustainability and the underlying environmental, social, and economic conditions. The results from the study show that the four cities - Faisalabad, Lahore, Gujranwala, and Multan - have better economic conditions while only Lahore and Faisalabad showed social progress and the remaining cities showed less suitability. For the environmental index, none of the cities attained high suitability. Lahore, Faisalabad, and Rawalpindi showed better conditions than Gujranwala and Multan. It is demonstrated that Punjab cities have made progress in economic condition and improvement in social condition but have poor environmental condition. In the study, the environmental dimension has indicators which have more impact on the urban sustainability. Environmental degradation is observed in all selected regions and not a single region showed suitability toward its environmental condition and due to this none of the cities gained suitable scores for urban sustainability. Consequently, urban sustainability is a multidimensional and dynamic process that needs regular evaluation and monitoring. Thus, this article contends that the tools help to highlight and emphasize those areas that need guidance in achieving urban sustainability.