Aquatic hydrocarbon distributions in the Seine estuary: Biogenic polyaromatics and n-alkanes

Dissolved and particulate hydrocarbons of biogenic origin were investigated for the first time in surface waters along the Seine River and its estuary. They comprise n-alkanes (n-ALKs) and diagenetic polycyclic aromatic hydrocarbons (PAHs). Samples were collected in three different sections of the estuary: the riverine zone, the mixing zone, and the marine zone. At the river mouth, two mooring stations were used for the collection of samples over tidal cycles. Total particulate n-ALK concentrations ranged from 31 ng 1^?1 to 2,918 ng 1^?1, or 5 μg g^?1 dry ng 1^?1, or 2 μg g^?1 of SM. Concentrations varied with the SM load and could be related to sedimentation and estuarine mixing. The sources of the n-ALKs were different in each zone of the estuary. The dissolved n-ALKs displayed lower concentrations than the particulate phase, varying from 136 ng 1^?1 to 344 ng 1^?1, while biogenic dissolved PAHs were almost absent.     

Accumulation of sediment,organic matter and trace metals with space and time,in a creek along Mumbai coast,India

Two core sediment samples; one from inner part (ManI) and the other closer to the mouth (ManII); were collected from the intertidal regions of Manori, a tidally influenced creek near Mumbai, India. Both the cores were subjected to various geochemical analyses to determine parameters such as pH, sediment components, total organic carbon, total nitrogen, total phosphorus and selected metals viz., Fe, Mn, Cu, Pb, Co, Ni, Zn, Cr, Al, Ca and V. Analysis of ²¹⁰Pb activity was employed to assess the sediment deposition trend of the area. The data was further processed using factor and cluster analyses. The results indicate that the sediments from site ManI, had finer sediment composition, higher porosity, organic matter and metal contents but exhibited an erratic decline in ²¹⁰Pb activity downcore. Also ManI showed higher C:N ratio and enrichment factor values as compared to site ManII. The inner area (ManI) probably received a greater input of organic matter from the erosion of terrestrial matter as well as domestic and industrial discharge. Sediments from site ManII had typical marine organic matter composition (lower C:N ratio). The concentration of metals at this site was also low indicating the contents were getting diluted by freshwater and seawater mixing.     

Throughfall patterns in sugarcane and riparian forest: understanding the effect of sugarcane age and land use conversion

Sugarcane is an annual crop with a dynamic canopy that changes over time mainly because of genetic adaptation. There is uncertainty about the temporal trends of throughfall (TF) in this important commercial crop. In the present paper, we used troughs to measure TF in a third and fourth ratoon and subsequently in a fourth and fifth ratoon. Additional measurements were carried out in an adjacent riparian forest. There were no significant differences between cycles of sugarcane, growth phases and riparian forest. The TF results for ratoon crop and riparian forest in 2011/2012 were 76% and 79.5% of gross rainfall, respectively, while in 2012/2013, they were 79% and 78%, respectively. However, TF was remarkably lower in the riparian forest relative to ratoon from the second half of the culm formation and elongation phase (280 days after harvest) until harvest. Copyright © 2016 John Wiley & Sons, Ltd.     

Mid and late Holocene forest fires and deforestation in the subalpine belt of the Iberian range,northern Spain

The conversion of subalpine forests into grasslands for pastoral use is a well-knownphenomenon, although for most mountain areas the timing of deforestation has not been determined. The presence of charcoal fragments in soil profiles affected by shallow landsliding enabled us to date the occurrence of fires and the periods of conversion ofsubalpine forest into grasslands in the Urbión Mountains, Iberian Range, Spain. We found that the treeline in the highest parts of the northwestern massifs of the Iberian Range(the Urbión, Demanda, Neila, and Cebollera massifs) is currently between 1500 and 1600 m a.s.l., probably because of pastoral use of the subalpine belt, whereas in the past it would have reached almost the highest divides(at approximately 2100–2200 m a.s.l.). The radiocarbon dates obtained indicate that the transformation of the subalpine belt occurred during the Late Neolithic, Chalcolithic, Bronze Age, Iron Age, and Middle Ages. Forest clearing was probably moderate during fires prior to the Middle Ages, as the small size of the sheep herds and the local character of the markets only required small clearings, and therefore more limited fires. Thus, it is likely that the forest recovered burnt areas in a few decades; this suggests the management of the forest and grasslands following a slash-andburn system. During the Middle and Modern Ages deforestation and grassland expansion affected most of the subalpine belt and coincided with the increasing prevalence of transhumance, as occurred in other mountains in the Iberian Peninsula(particularly the Pyrenees). Although the occurrence of shallow landslides following deforestation between the Neolithic and the Roman Period cannot be ruled out, the most extensive shallow landsliding processes would have occurred from the Middle Ages until recent times.     

Assessing shallow landslide hazards using the TRIGRS and SHALSTAB models,Serra do Mar,Brazil

The hillslopes of the Serra do Mar, a system of escarpments and mountains that extend more than 1500 km along the southern and southeastern Brazilian coast, are regularly affected by heavy rainfall that generates widespread mass movements, causing large numbers of casualties and economic losses. This paper evaluates the efficiency of susceptibility mapping for shallow translational landslides in one basin in the Serra do Mar, using the physically based landslide susceptibility models SHALSTAB and TRIGRS. Two groups of scenarios were simulated using different geotechnical and hydrological soil parameters, and for each group of scenarios (A and B), three subgroups were created using soil thickness values of 1, 2, and 3 m. Simulation results were compared to the locations of 356 landslide scars from the 1985 event. The susceptibility maps for scenarios A1, A2, and A3 were similar between the models regarding the spatial distribution of susceptibility classes. Changes in soil cohesion and specific weight parameters caused changes in the area of predicted instability in the B scenarios. Both models were effective in predicting areas susceptible to shallow landslides through comparison of areas predicted to be unstable and locations of mapped landslides. Such models can be used to reduce costs or to define potentially unstable areas in regions like the Serra do Mar where field data are costly and difficult to obtain.     

Gentrification in Porto: floating city users and internationally-driven urban change

The heightening scale of urban tourism and the fast-growing number of “floating” city users raise new challenges to understand contemporary urban change – namely for internationally open, heritage-rich medium-sized cities. Discussing the case of Porto at a time when the contested notion of gentrification infuses local politics, we highlight the transnational drivers of this process in Portugal´s second city. While acknowledging perils and benefits, we argue that more than simply leaving a footprint to be solved with taxation, internationally-driven gentrification may endanger city diversity and identity, raising implications for urban policy and for our understanding of local development as a whole.     

Anoxia over the western continental shelf of India: bacterial indications of intrinsic nitrification feeding denitrification

Studies on the Arabian Sea coastal anoxia have been of immense interest, but despite its ecological significance there is sparse understanding of the microbes involved. Hence, observations were carried out off Goa (15 degrees 30'N, 72 degrees 40'E to 15 degrees 30'N, 72 degrees 59'E) to understand the processes that mediate the changes in various inorganic nitrogen species in the water column during anoxia. Water column chemistry showed a clear distinct oxic environment in the month of April and anoxic condition in October. Our study based on microbial signatures indicated that oxygen deficit appeared as a well-defined nucleus almost 40 km away from the coast during the oxic period (April) and spreads there after to the entire water column synchronizing with the water chemistry. Striking results of net changes in inorganic nitrogen species in nitrification blocked and unblocked experimental systems show that denitrification is the predominant process in the water column consuming available nitrate ( approximately 0.5 microM) to near zero levels within approximately 72 h of incubation. These observations have been supported by concomitant increase in nitrite concentration ( approximately 4 microM). Similar studies on denitrification-blocked incubations, demonstrate the potential of nitrification to feed denitrification. Nitrification could contribute almost 4.5 microM to the total nitrate pool. It was found that the relation between ammonium and total dissolved inorganic nitrogen (DIN) pool (r=0.98, p<0.001, n=122) was significant compared to the latter with nitrite and nitrate. The occurrence of high ammonium under low phosphate conditions corroborates our observations that ammonium does not appear to be locked under low oxygen regimes. It is suggested that ammonium actively produced by detrital breakdown (ammonification) is efficiently consumed through nitrification process. The three processes in concert viz. ammonification, nitrification and denitrification appear to operate in more temporal and spatial proximity than hitherto appreciated in these systems and this gives additional cues on the absence of measurable nitrate at surface waters, which was earlier attributed only to efficient algal uptake. Hence we hypothesize that the alarming nitrous oxide input into the atmosphere could be due to high productivity driven tighter nitrification-denitrification coupling, rather than denitrification driven by extraneous nitrate.     

Perceptive of the pyroxene-bearing micrometeorites and their relation to chondrites

We studied 149 pyroxenes from 69 pyroxene-bearing micrometeorites collected from deep-sea sediments of the Indian Ocean and South Pole Water Well at Antarctica, Amundsen-Scott South Pole station. The minor elements in pyroxenes from micrometeorites are present in the ranges as follows: MnO ~0.0–0.4 wt%, Al₂O₃ ~0.0–1.5 wt%, CaO ~0.0–1.0 wt%, Cr₂O₃ ~0.3–0.9 wt%, and FeO ~0.5–4 wt%. Their chemical compositions suggest that pyroxene-bearing micrometeorites are mostly related to precursors from carbonaceous chondrites rather than ordinary chondrites. The Fe/(Fe+Mg) ratio of the pyroxenes and olivines in micrometeorites shows similarities to carbonaceous chondrites with values lying between 0 and 0.2, and those with values beyond this range are dominated by ordinary chondrites. Atmospheric entry of the pyroxene-bearing micrometeorites is expected to have a relatively low entry velocity of <16 km s⁻¹ and high zenith angle (70–90°) to preserve their chemical compositions. In addition, similarities in the pyroxene and olivine mineralogical compositions between carbonaceous chondrites and cometary particles suggest that dust in the solar system is populated by materials from different sources that are chemically similar to each other. Our results on pyroxene chemical compositions reveal significant differences with those from ordinary chondrites. The narrow range in olivine and pyroxene chemical compositions are similar to those from carbonaceous chondrites, and a small proportion to ordinary chondrites indicates that dust is largely sourced from carbonaceous chondrite-type bodies.